Synthesis of Mesoporous Silica Particles by Polymerization Induced Colloid Aggregation and Its Application for High-Performance Liquid Chromatography

B.B. Zhao; F.Y. Wang; T. Li

doi:10.14233/ajchem.2015.18296

Issue

Vol. 27 No. 3 (2015): Vol 27 Issue 3

Issue Published : January 19, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis of Mesoporous Silica Particles by Polymerization Induced Colloid Aggregation and Its Application for High-Performance Liquid Chromatography

https://doi.org/10.14233/ajchem.2015.18296

B.B. Zhao

College of food science and technology, Henan University of Technology, Zhengzhou, P.R. China

F.Y. Wang

Chemical Engineering Institute, Nanjing University of Science and Technology, Nanjing, P.R. China

T. Li

Dalian Elite Analytical Instruments Co., Ltd., Dalian, P.R. China

Corresponding Author(s) : B.B. Zhao

gentlebeibei@163.com

Asian Journal of Chemistry, Vol. 27 No. 3 (2015): Vol 27 Issue 3
Article Published : January 18, 2015

Abstract

Micrometer-sized mesoporous silica particles have been synthesized by a modified polymerization induced colloid aggregation method. Silica particles with particle size in the range of 2-5 μm could be obtained by controlling the reaction conditions. The obtained silica particles were characterized by scanning electron microscopy (SEM), N₂ physisorption technique and inductively coupled plasma emission spectroscopy (ICP-AES). The C18-modified silica particles were explored as stationary phase in reversed phase liquid chromatography and its chromatographic characteristics for separation of some small molecules have been studied.

Keywords

Polymerization induced colloid aggregation Silica particles High performance liquid chromatography Stationary phase

Zhao, B., Wang, F., & Li, T. (2015). Synthesis of Mesoporous Silica Particles by Polymerization Induced Colloid Aggregation and Its Application for High-Performance Liquid Chromatography. Asian Journal of Chemistry, 27(3), 1097–1101. https://doi.org/10.14233/ajchem.2015.18296

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References

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References

H.D. Qiu, X.J. Liang, M. Sun and S.X. Jiang, Anal. Biochem. Chem., 399, 3307 (2011); doi:10.1007/s00216-010-4611-x.

B.B. Zhao, C.H. Tian, Y. Zhang, T. Tang and F.Y. Wang, Particuology, 9, 314 (2011); doi:10.1016/j.partic.2010.07.028.

B.B. Zhao, Y. Zhang, T. Tang, F.Y. Wang, W.B. Zhang and T. Li, Prog. Chem., 24, 122 (2012).

Z.T. Jiang and Y.M. Zuo, Anal. Chem., 73, 686 (2001); doi:10.1021/ac001008u.

A.N. Sathyagal, P.W. Carr and A.V. McCormick, J. Colloid Interf. Sci., 219, 20 (1999); doi:10.1006/jcis.1999.6447.

W. Li, D. Chen, Z. Li, Y. Shi, Y. Wan, J. Huang, J. Yang, D. Zhao and Z. Jiang, Electrochem. Commun.,9, 569 (2007); doi:10.1016/j.elecom.2006.10.027.

M.K. Seo, S. Yang, I.J. Kim and S.J. Park, Mater. Res. Bull., 45, 10 (2010); doi:10.1016/j.materresbull.2009.09.006.

L. Han, Z. Shan, D.H. Chen, X.J. Yu, P.Y. Yang, B. Tu and D.Y. Zhao, J. Colloid Interf. Sci., 318, 315 (2008); doi:10.1016/j.jcis.2007.10.026.

K.K. Unger, R. Skudas and M.M. Schulte, J. Chromatogr. A, 1184, 393 (2008); doi:10.1016/j.chroma.2007.11.118.

C.A. Clayton, J.W. Hines and P.D. Elkins, Anal. Chem., 59, 2506 (1987); doi:10.1021/ac00147a014.

D.A. Barrett, V.A. Brown, R.C. Watson, M.C. Davies, P.N. Shaw, H.J. Ritchie and P. Ross, J. Chromatogr. A, 905, 69 (2001); doi:10.1016/S0021-9673(00)01000-1.

L. Zhao, J.G. Yu, R. Guo and B. Cheng, Key Eng. Mater., 280-283, 1153 (2005); doi:10.4028/www.scientific.net/KEM.280-283.1153.

J.J. Kirkland and J. Kohler, Porous Silica Microspheres having Silanol-enriched and Silanized Surfaces. US Patent 5108595 (1992).

C.I. Lee, S.W. Lee, Y. Lee, Y.H. Chang and Y.M. Hahm, Stud. Surf. Sci. Catal., 146, 193 (2003); doi:10.1016/S0167-2991(03)80360-9.

Issue

Vol. 27 No. 3 (2015): Vol 27 Issue 3

Synthesis of Mesoporous Silica Particles by Polymerization Induced Colloid Aggregation and Its Application for High-Performance Liquid Chromatography

Corresponding Author(s) : B.B. Zhao

Abstract

Keywords

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