Copyright (c) 2015 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Assessment of Roadside Soil Pollution by Heavy Metal Ions and Correlation to Traffic Activities in Madina City, Saudi Arabia: Part I
Corresponding Author(s) : E. Assirey
Asian Journal of Chemistry,
Vol. 27 No. 3 (2015): Vol 27 Issue 3
Abstract
Traffic activities are considered as one major sources of heavy metal pollution in roadside soil. Therefore, this study was carried out to investigate the impact of traffic on the characteristics of heavy metals in roadside soil of Madina city, Saudi Arabia. Soil samples from the surface and 20 cm under surface in 12 different sites were collected and analyzed for As, Co, Pb, V and Zn. The traffic density was monitored in roads near the sampling sites and correlated with heavy metal concentration to investigate the impact of traffic density on heavy metal ions concentration. The results revealed great dependence of Pb and Zn on traffic density with correlation coefficients of 0.991 and 0.987, respectively. The other metals, As, Co and V showed no dependence on traffic density and no dependence between the surface and under surface concentration. The values of pollution indices such as contamination factor, degree of contamination and geo-accumulation index (Igeo) indicated various levels of contamination in the roadside soil in some study sites. The degree of contamination values in the more polluted site were 32.192, 28.872 and 23.902 in the airport road (1), Taibah University street (2) and Orwah valley street (3). These results ensure that traffic emissions, automobiles and other anthropogenic activities are major sources of the metal contamination.
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- L.C. Mello, A. Claudino, I. Rizzatti, R.L. Bortoluzzi and D.R. Zanette, J. Braz. Chem. Soc., 16(3a), 308 (2005); doi:10.1590/S0103-50532005000300003.
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Z. Al-Qodah, Desalination, 196, 164 (2006); doi:10.1016/j.desal.2005.12.012.
L. de Oliveria Franco, R. de Cussia C. Maia, A.L.F. Porto, A.S. Messias, K. Fukushima and G.M. de Campos-Takaki, J. Microbiol., 35, 243 (2004).
T.R. Crompton, Toxicants in the Aqueous Echosystem, Wiley, Chichester, pp. 91-135 (1997).
X. Yan, D. Gao, F. Zhang, C. Zeng, W. Xiang and M. Zhang, J. Environ. Res. Public Health, 10, 762 (2013); doi:10.3390/ijerph10030762.
S. P. Raj, Res. J. Chem. Sci., 3, 18, (2013).
C. Pagotto, N. Remy, M. Legret and P. Le Cloirec, J. Environ. Technol., 22, 307 (2001); doi:10.1080/09593332208618280.
L.M.J. Dolan, H. Van Bohemen, P. Whelan, K.F. Akbar and V. O'mally, in eds.: J. Davenport and J.L. Davenport, Towards the Sustainable Development of Modern Road Ecosystem. In: The Ecology of Transportation: Managing Mobility for the Environment, Springer, Netherlands, pp. 275-331 (2006).
E.S. Abechl, O.J. Okunola, S.M.J. Zubairu, A.A. Usman and E. Apene, Nigeria J. Environ. Chem. Ecotoxicol., 2, 98 (2010).
K.I. Sakagami, R. Eamada and T. Kurobe, J. Mitteeilungen der Deutschen Bodenkundlichen Gessellscaft., 33, 59 (1982).
C.W. Gray, R.G. Mclaren and A.H.C. Roberts, J. Sci. Total Environ., 305, 105 (2003); doi:10.1016/S0048-9697(02)00404-7.
X. Li, C.- Poon and P.S. Liu, J. Geochem, 16, 1361 (2001); doi:10.1016/S0883-2927(01)00045-2.
L. Poggio, B. Vrscaj, R. Schulin, E. Hepperle and F.A. Marsan, J. Environ. Poll., 157, 680 (2009); doi:10.1016/j.envpol.2008.08.009.
M. Soylak, I. Narin, L. Elci and M. Dogan, Fresenius Environ. Bul., 9, 36 (2000).
I. Narin, M. Soylak and M. Dogan, Fresenius Environ. Bull., 6, 749 (1997).
G. Shi, Z. Chen, S. Xu, J. Zhang, L. Wang, C. Bi and J. Teng, Environ. Pollut., 156, 251 (2008); doi:10.1016/j.envpol.2008.02.027.
K.F. Akrari, W.H.G. Hallei, A.D. Headley and M. Athar, Soil Water Res., 1, 158 (2006).
G. Cekstere and A. Osvalde, Urban For. Urban Green., 12, 69 (2013); doi:10.1016/j.ufug.2012.09.004.
T. Duong and B. Lee, Environ. Manage., 92, 554 (2011); doi:10.1016/j.jenvman.2010.09.010.
J. Carrero, I. Arrizabalaga, J. Bustamante, N. Goienaga, G. Arana and J.M. Madariaga, Sci. Total Environ., 458-460, 427 (2013); doi:10.1016/j.scitotenv.2013.04.047.
C.S. Tamrakar and P.R. Shakya, Pak. J. Anal. Environ. Chem., 12, 32 (2011).
M. Aslam, D.K. Verma and R. Dhakerya, Res. J. Environ. Earth Sci., 4, 1060 (2012).
M.S. El-Shahawi, A. Hamza, A.S. Bashammakh and W.T. Al-Saggaf, Talanta, 80, 1587 (2010); doi:10.1016/j.talanta.2009.09.055.
S.M. Al-Shayeb and M. Seaward, Asian J. Chem., 13, 407 (2001).
M.S. Akhter and I.M. Madany, Water Air Soil Pollut., 66, 111 (1993); doi:10.1007/BF00477063.
I. Narin, M. Soylak and M. Dogan, Environ. Bull., 6, 749 (1997).
D.E. Guven and G. Akinci, GU J. Sci., 24, 29 (2011).
L. Hakanson, Water Res., 14, 975 (1980); doi:10.1016/0043-1354(80)90143-8.
K.B. Mmolawa, A.S. Likuku and G.K. Gaboutleeloe, Afr. J. Environ. Sci. Technol., 5, 186 (2011); doi:10.5897/AJEST10.246.
G. Muller, Geol. J., 2, 108 (1969).
S. Budavari, M.J. O'Neil and A. Smith, the Merck Index, Merck & Co. Inc., USA, edn 13, pp. 440-462 (2001).
K.H. Wedepohl, Geol. Rundschau., 80, 207 (1991); doi:10.1007/BF01829361.
S.A. Abbasi, P.C. Nipaney and R. Soni, Anal. Lett., 22, 225 (1989); doi:10.1080/00032718908051196.
M.W. Kadi, J. Hazard. Mater., 168, 1280 (2009); doi:10.1016/j.jhazmat.2009.03.015.
J.J. Clark and A.C. Knudsen, J. Environ. Qual., 42, 1498 (2013); doi:10.2134/jeq2013.03.0100.
R.A. Goyer and M.A. Mehlman, Advances in Modern Toxicology, In: Toxicology of Trace Elements, New York, Wiley, vol. 2 (1977).
S. Bengtsson and G. Tyler, Vanadium in the Environment, University of London, Monitoring and Assessment Research Centre, (MARC Report No. 2), London (1976).
M.W. Paschke, E.F. Redente and D.B. Levy, Environ. Toxicol. Chem., 19, 2751 (2000); doi:10.1002/etc.5620191120.
R.L. Chaney and J.A. Ryan, in eds.: H.A.J. Hoitink and H.M. Keener, Heavy Metals and Toxic Organic Pollutants in MSW-Composts: Research Results on Phytoavailability, Bioavailability, Fate etc. In: Science and Engineering of Composting: Design, Environmental, Microbiological and Utilization Aspects, Ohio State University, Ohio, pp. 451-506 (1993).
NEQS (National Environmental Quality Standards), Pakistan Environmental Legislation, Ministry of Environment (1997).