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Vol. 27 No. 3 (2015): Vol 27 Issue 3

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Sol-Gel Method for Preparation of Nanosize NiFe2-xCoxO4 Using Egg White

https://doi.org/10.14233/ajchem.2015.18641
Rudy Situmeang
Department of Chemistry, FMIPA University of Lampung, Jl. S. Brodjonegoro No. 1 Bandar Lampung 35415, Indonesia
Posman Manurung
Department of Physics, FMIPA University of Lampung, Jl. S. Brodjonegoro No. 1 Bandar Lampung 35415, Indonesia
Septhian Try Sulistiyo
Department of Chemistry, FMIPA University of Lampung, Jl. S. Brodjonegoro No. 1 Bandar Lampung 35415, Indonesia
Sutopo Hadi
Department of Chemistry, FMIPA University of Lampung, Jl. S. Brodjonegoro No. 1 Bandar Lampung 35415, Indonesia
Wasinton Simanjuntak
Department of Chemistry, FMIPA University of Lampung, Jl. S. Brodjonegoro No. 1 Bandar Lampung 35415, Indonesia
Simon Sembiring
Department of Physics, FMIPA University of Lampung, Jl. S. Brodjonegoro No. 1 Bandar Lampung 35415, Indonesia

Corresponding Author(s) : Rudy Situmeang

situmeang@unila.ac.id

Asian Journal of Chemistry, Vol. 27 No. 3 (2015): Vol 27 Issue 3

Abstract

NiCoxFe2-xO4 nanomaterials (with x = 0.1-0.3) have been prepared using a combination method of sol-gel and freeze-drying. Preparation of material was carried out by dissolving nitrate salts of iron, nickel and cobalt in egg white solution and then the sample was stirred throughly using magnetic stirrer. The sample was subjected to calcination treatment and subsequently characterized using the techniques of X-ray diffraction for both qualitative and quantitative analysis such as Rietveld and Debye-Scherrer methods, infrared spectroscopy and scanning electron microscopy. The results of X-ray diffraction characterization indicated that the catalysts consist of various crystalline phases, with NiFe2O4 superimposed to CoFe2O4 is a major phase. FTIR analysis confirmed the existence of both Lewis acid and Brønsted-Lowry acid sites. The sample was found to display relatively surface morphology and according to the scanning electron microscopy data and Scherrer equation, the particle size of the material is in nano scale, 15-46 nm.

Keywords

Nanomaterial Sol-gel and freeze-drying BrØnsted-Lowry and Lewis acid sites
Situmeang, R., Manurung, P., Try Sulistiyo, S., Hadi, S., Simanjuntak, W., & Sembiring, S. (2015). Sol-Gel Method for Preparation of Nanosize NiFe2-xCoxO4 Using Egg White. Asian Journal of Chemistry, 27(3), 1138–1142. https://doi.org/10.14233/ajchem.2015.18641
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