Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Morphology and Properties of Polypeptide-block-poly(ethylene glycol)/Poly(tetramethylene glycol) Blend Film
Corresponding Author(s) : Fa-Gang Wang
Asian Journal of Chemistry,
Vol. 26 No. 1 (2014): Vol 26 Issue 1
Abstract
A series of poly(g-benzyl L-glutamate)-block-poly(ethylene glycol)/poly(tetramethylene glycol) (PBLG-block-PEG/PTMG) blend films were prepared by casting the polymer blend solution in dichloroethane. Surface morphologies of the PBLG-block-PEG/PTMG blend films were investigated by scanning electron microscopy and atomic force microscopy. Mechanical and chemical properties of the polymer blend films were studied by tensile tests and surface contact angle tests. It was shown that the introduction of poly(tetramethylene glycol) could greatly affect the properties of the polypeptide block copolymer films.
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- Y. Nishio and R. Manley, Macromolecules, 21, 1270 (1988); doi:10.1021/ma00183a016.
- J.S. Park, J.W. Park and E. Ruckenstein, Polymer, 42, 4271 (2001); doi:10.1016/S0032-3861(00)00768-0.
- T. Kondo, C. Sawatari, R. Manley and D.G. Gray, Macromolecules, 27, 210 (1994); doi:10.1021/ma00079a031.
- C. Sawatari and T. Kondo, Macromolecules, 32, 1949 (1999); doi:10.1021/ma980900o.
- K. Lio, N. Minoura and M. Nagura, Polymer, 36, 2579 (1995); doi:10.1016/0032-3861(95)91204-K.
- G.Q. Zhu, G.C. Li and P. Wang, Polym.- Plast. Technol. Eng., 50, 1470 (2011); doi:10.1080/03602559.2011.593080.
- G.Q. Zhu, Y.Y. Liu and F.G. Wang, Int. J. Polym. Mater., 61, 737 (2012); doi:10.1080/00914037.2011.610044.
- K. Jokei, M. Oka, T. Hayashi and Y. Miyachi, Eur. Polym. J., 35, 945 (1999); doi:10.1016/S0014-3057(98)00051-2.
- D.M. Tang, J.P. Lin, S.L. Lin, S.N. Zhang, T. Chen and X.H. Tian, Macromol. Rapid Commun., 25, 1241 (2004); doi:10.1002/marc.200400100.
- L.Q. Bai, L.J. Zhu, S.J. Min, L. Liu, Y.R. Cai and J.M. Yao, Appl. Surf. Sci., 254, 2988 (2008); doi:10.1016/j.apsusc.2007.10.049.
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- G.Q. Zhu, L. Feng and S.N. Zhang, J. Macromol. Sci. A, 46, 694 (2009); doi:10.1080/10601320902939002.
- N. Higashi, J. Kawahara and M. Niwa, J. Colloid Interf. Sci., 288, 83 (2005); doi:10.1016/j.jcis.2005.02.086.
- G.Q. Zhu, Chem. Pap., 64, 34 (2010); doi:10.2478/s11696-009-0090-y.
- Z. Gao, A. Desjardins and A. Eisenberg, Macromolecules, 25, 1300 (1992); doi:10.1021/ma00030a015.
- X.F. Zhong, S.K. Varshney and A. Eisenberg, Macromolecules, 25, 7160 (1992); doi:10.1021/ma00052a014.
- T. Li, J.P. Lin, T. Chen and S.N. Zhang, Polymer, 47, 4485 (2006); doi:10.1016/j.polymer.2006.04.011.
- J.P. Lin, A. Abe, H. Furuya and S. Okamoto, Macromolecules, 29, 2584 (1996); doi:10.1021/ma951026r.
- G.Q. Zhu, F.G. Wang, Y.Y. Liu and Q.C. Gao, Fibers Polym., 11, 819 (2010); doi:10.1007/s12221-010-0819-9.
- J.P. Lin, G.Q. Zhu, X.M. Zhu, S.L. Lin, T. Nose and W.W. Ding, Polymer, 49, 1132 (2008); doi:10.1016/j.polymer.2008.01.021.
- M. Moffitt and A. Eisenberg, Macromolecules, 30, 4363 (1997); doi:10.1021/ma961577x.
- Y. Miyachi, K. Jokei, M. Oka and T. Hayashi, Eur. Polym. J., 35, 767 (1999); doi:10.1016/S0014-3057(98)00059-7.
- H.-Y. Tsi, C.-C. Chen, W.-C. Tsen, Y.-C. Shu and F.-S. Chuang, Polym. Test., 30, 50 (2011); doi:10.1016/j.polymertesting.2010.10.005.
- S.C. Roh, M.J. Park, S.H. Yoo and C.K. Kim, J. Membr. Sci., 411-412, 201 (2012); doi:10.1016/j.memsci.2012.04.032.
- G.Q. Zhu, Q.C. Gao, Z.H. Li and F.G. Wang, Int. J. Polym. Mater., 60, 290 (2011); doi:10.1080/00914037.2010.504179.
- M.Y. Lee, S.H. Kim, H.S. Ganapathy, S.W. Kim and K.T. Lim, Ultramicroscopy, 108, 1210 (2008); doi:10.1016/j.ultramic.2008.04.017.
- M.J. Fasolka, A.M. Mayes and S.N. Magonov, Ultramicroscopy, 90, 21 (2001); doi:10.1016/S0304-3991(01)00129-2.
- S. Yamamoto, Y. Tsujii and T. Fukuda, Polymer, 42, 2007 (2001); doi:10.1016/S0032-3861(00)00525-5.
References
Y. Nishio and R. Manley, Macromolecules, 21, 1270 (1988); doi:10.1021/ma00183a016.
J.S. Park, J.W. Park and E. Ruckenstein, Polymer, 42, 4271 (2001); doi:10.1016/S0032-3861(00)00768-0.
T. Kondo, C. Sawatari, R. Manley and D.G. Gray, Macromolecules, 27, 210 (1994); doi:10.1021/ma00079a031.
C. Sawatari and T. Kondo, Macromolecules, 32, 1949 (1999); doi:10.1021/ma980900o.
K. Lio, N. Minoura and M. Nagura, Polymer, 36, 2579 (1995); doi:10.1016/0032-3861(95)91204-K.
G.Q. Zhu, G.C. Li and P. Wang, Polym.- Plast. Technol. Eng., 50, 1470 (2011); doi:10.1080/03602559.2011.593080.
G.Q. Zhu, Y.Y. Liu and F.G. Wang, Int. J. Polym. Mater., 61, 737 (2012); doi:10.1080/00914037.2011.610044.
K. Jokei, M. Oka, T. Hayashi and Y. Miyachi, Eur. Polym. J., 35, 945 (1999); doi:10.1016/S0014-3057(98)00051-2.
D.M. Tang, J.P. Lin, S.L. Lin, S.N. Zhang, T. Chen and X.H. Tian, Macromol. Rapid Commun., 25, 1241 (2004); doi:10.1002/marc.200400100.
L.Q. Bai, L.J. Zhu, S.J. Min, L. Liu, Y.R. Cai and J.M. Yao, Appl. Surf. Sci., 254, 2988 (2008); doi:10.1016/j.apsusc.2007.10.049.
I. Oh, K. Lee, H.-Y. Kwon, Y.-B. Lee, S.-C. Shin, C.-S. Cho and C.-K. Kim, Int. J. Pharm., 181, 107 (1999); doi:10.1016/S0378-5173(99)00012-5.
G.Q. Zhu, L. Feng and S.N. Zhang, J. Macromol. Sci. A, 46, 694 (2009); doi:10.1080/10601320902939002.
N. Higashi, J. Kawahara and M. Niwa, J. Colloid Interf. Sci., 288, 83 (2005); doi:10.1016/j.jcis.2005.02.086.
G.Q. Zhu, Chem. Pap., 64, 34 (2010); doi:10.2478/s11696-009-0090-y.
Z. Gao, A. Desjardins and A. Eisenberg, Macromolecules, 25, 1300 (1992); doi:10.1021/ma00030a015.
X.F. Zhong, S.K. Varshney and A. Eisenberg, Macromolecules, 25, 7160 (1992); doi:10.1021/ma00052a014.
T. Li, J.P. Lin, T. Chen and S.N. Zhang, Polymer, 47, 4485 (2006); doi:10.1016/j.polymer.2006.04.011.
J.P. Lin, A. Abe, H. Furuya and S. Okamoto, Macromolecules, 29, 2584 (1996); doi:10.1021/ma951026r.
G.Q. Zhu, F.G. Wang, Y.Y. Liu and Q.C. Gao, Fibers Polym., 11, 819 (2010); doi:10.1007/s12221-010-0819-9.
J.P. Lin, G.Q. Zhu, X.M. Zhu, S.L. Lin, T. Nose and W.W. Ding, Polymer, 49, 1132 (2008); doi:10.1016/j.polymer.2008.01.021.
M. Moffitt and A. Eisenberg, Macromolecules, 30, 4363 (1997); doi:10.1021/ma961577x.
Y. Miyachi, K. Jokei, M. Oka and T. Hayashi, Eur. Polym. J., 35, 767 (1999); doi:10.1016/S0014-3057(98)00059-7.
H.-Y. Tsi, C.-C. Chen, W.-C. Tsen, Y.-C. Shu and F.-S. Chuang, Polym. Test., 30, 50 (2011); doi:10.1016/j.polymertesting.2010.10.005.
S.C. Roh, M.J. Park, S.H. Yoo and C.K. Kim, J. Membr. Sci., 411-412, 201 (2012); doi:10.1016/j.memsci.2012.04.032.
G.Q. Zhu, Q.C. Gao, Z.H. Li and F.G. Wang, Int. J. Polym. Mater., 60, 290 (2011); doi:10.1080/00914037.2010.504179.
M.Y. Lee, S.H. Kim, H.S. Ganapathy, S.W. Kim and K.T. Lim, Ultramicroscopy, 108, 1210 (2008); doi:10.1016/j.ultramic.2008.04.017.
M.J. Fasolka, A.M. Mayes and S.N. Magonov, Ultramicroscopy, 90, 21 (2001); doi:10.1016/S0304-3991(01)00129-2.
S. Yamamoto, Y. Tsujii and T. Fukuda, Polymer, 42, 2007 (2001); doi:10.1016/S0032-3861(00)00525-5.