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Vol. 26 No. 1 (2014): Vol 26 Issue 1

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Synthesis and Characterisation of μ-Oxy-bis[triphenylbismuth(V)] Dicarboxylates and Halo-Carboxylates

https://doi.org/10.14233/ajchem.2014.15517
Kiran Singhal
Department of Chemistry, University of Lucknow, Lucknow-226 007, India
Subhas Kumar Chaudhary
Department of Chemistry, University of Lucknow, Lucknow-226 007, India
Vishnu Kumar Sahu
Department of Chemistry, Maharani Lal Kunwari Post Graduate College, Balrampur-271 201, India
Prem Raj
Department of Chemistry, University of Lucknow, Lucknow-226 007, India

Corresponding Author(s) : Kiran Singhal

kiran.singhal@gmail.com

Asian Journal of Chemistry, Vol. 26 No. 1 (2014): Vol 26 Issue 1

Abstract

Several unknown μ-oxybis[triphenylbismuth]dicarboxylates and μ-oxy-bis[triphenylbismuth]chloro-carboxylates of the general formula Ph3Bi(L)-O-Bi(L)Ph3 and Ph3Bi(Cl)-O-Bi(L)Ph3, respectively have been synthesised by the metathetical reactions of μ-oxybis-[triphenylbismuth]dichloride reactions and silver salts of corresponding carboxylic acids in 1:2 and 1:1 ratio [where L= 2-pyrazine carboxylic acid, p-methoxy mandelic acid, salicylic acid, benzillic acid and p-(trifluoromethyl)mandelic acid)]. The newly synthesized bismuth derivatives have been characterized on the basis of melting point, elemental analysis, IR 1H and 13C NMR spectra. The molecular weight and conductivity data indicate the monomeric and non electrolytic behaviour in solution.

Keywords

µ-Oxybis(triphenylbismuth)dicarboxylates
Singhal, K., Kumar Chaudhary, S., Kumar Sahu, V., & Raj, P. (2013). Synthesis and Characterisation of μ-Oxy-bis[triphenylbismuth(V)] Dicarboxylates and Halo-Carboxylates. Asian Journal of Chemistry, 26(1), 196–200. https://doi.org/10.14233/ajchem.2014.15517
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