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Vol. 26 No. 1 (2014): Vol 26 Issue 1

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Synthesis, Characterization and Crystal Structure of Nickel Complex (dppv)Ni(C7H4NS2)2

https://doi.org/10.14233/ajchem.2014.15478
Yu-Long Li
Key Laboratory of Green Catalysis of Higher Education Institutes of Sichuan, Sichuan University of Science & Engineering, Zigong 643000, P.R. China; Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, P.R. China
Bin Xie
Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, P.R. China
Li-Ke Zou
Key Laboratory of Green Catalysis of Higher Education Institutes of Sichuan, Sichuan University of Science & Engineering, Zigong 643000, P.R. China
Xiao Lin
Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, P.R. China
Sha-Sha Zhu
Institute of Functional Materials, Sichuan University of Science & Engineering, Zigong 643000, P.R. China

Corresponding Author(s) : Yu-Long Li

yu_longli@yahoo.cn

Asian Journal of Chemistry, Vol. 26 No. 1 (2014): Vol 26 Issue 1

Abstract

Reaction of 2-mercaptobenzothiazole with (dppv)NiCl2 (dppv: Ph2PCH=CHPPh2) in the presence of Et3N affords the title complex (dppv)Ni(C7H4NS2)2 in 92 % yield. The new complex was fully characterized by elemental analysis, TGA, IR and 1H (13C, 31P) NMR spectroscopies. In addition, the molecular structure of the title complex was established by X-ray crystallography. The crystal of (dppv)Ni(C7H4NS2)2·CH2Cl2 crystallizes in monoclinic, space group P2/n with a = 15.927(9), b = 8.3553(5), c = 16.3728(8) Å, a = 90.00, b = 112.417(4), g = 90.00°, V = 2014.22(19) Å3, Z = 2, C40H30N2NiP2S4·CH2Cl2, Mr = 872.48, Dc = 1.439 g/cm3, F(000) = 896 and μ(MoKa) = 0.934 mm-1. The final R = 0.0920 and wR = 0.2220 for 2572 observed reflections with I > 2s(I) and R = 0.1171 and wR = 0.2434 for all data. The geometry at the Ni centre in the title complex is square-planar with the NiP2S2 chromophore.

Keywords

dppv 2-Mercaptobenzothiazole Synthesis X-ray crystallography
Li, Y.-L., Xie, B., Zou, L.-K., Lin, X., & Zhu, S.-S. (2013). Synthesis, Characterization and Crystal Structure of Nickel Complex (dppv)Ni(C7H4NS2)2. Asian Journal of Chemistry, 26(1), 183–185. https://doi.org/10.14233/ajchem.2014.15478
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