Synthesis, Supramolecular Structure, Antimicrobial and Plant-Growth Regulation Activities of N-Benzoylthiourea

Meng-Meng Zhao; Xiu-Yan Dong; Yu-Hua Yang; Gang Li; Yu-Jie Zhang

doi:10.14233/ajchem.2014.15784

Issue

Vol. 26 No. 1 (2014): Vol 26 Issue 1

Issue Published : December 26, 2013

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Supramolecular Structure, Antimicrobial and Plant-Growth Regulation Activities of N-Benzoylthiourea

https://doi.org/10.14233/ajchem.2014.15784

Meng-Meng Zhao

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Xiu-Yan Dong

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Yu-Hua Yang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Gang Li

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Yu-Jie Zhang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Corresponding Author(s) : Xiu-Yan Dong

dxy568@163.com

Asian Journal of Chemistry, Vol. 26 No. 1 (2014): Vol 26 Issue 1
Article Published : December 26, 2013

Abstract

N-Benzoylthiourea has been synthesized and characterized by elemental analysis, IR and ¹H NMR etc. The X-ray crystallography of the compound indicates that the carbonyl group forms an intramolecular hydrogen bond with the N2-H2 group, which forms a six-membered ring (C7/N1/C8/N2/H2/O1) srtucture. Each molecule are linked by the intermolecular N2-H2A...S2 and N4-H4A...S1 hydrogen bonds to form a dimer, adjacent dimers are linked by the intermolecular N1-H1N...S2 and N3-H3N...S1 hydrogen bonds, leading to a hydrogen-bonded netty structure. The results indicated that the N-benzoylthiourea played the important role in plant-growth regulators and may be a potential source of active antimicrobial agents.

Keywords

Thiourea Synthesis Crystal structure Antibacterial Plant-growth regulation activity

Zhao, M.-M., Dong, X.-Y., Yang, Y.-H., Li, G., & Zhang, Y.-J. (2013). Synthesis, Supramolecular Structure, Antimicrobial and Plant-Growth Regulation Activities of N-Benzoylthiourea. Asian Journal of Chemistry, 26(1), 237–240. https://doi.org/10.14233/ajchem.2014.15784

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References

A. Jurasek, P. Saferr and V. Zvak, Chem. Pap., 41, 693 (1987).

S.G. Teoh, S.H. Ang, H.K. Fun and C.-W. Ong, J. Organomet. Chem., 580, 17 (1999); doi:10.1016/S0022-328X(98)01099-7.

U. Bierbach, T.W. Hambley, J.D. Roberts and N. Farrell, Inorg. Chem., 35, 4865 (1996); doi:10.1021/ic960314g.

R. del Campo, J.J. Criado, E. García, M.R. Hermosa, A. Jiménez-Sánchez, J.L. Manzano, E. Monte, E. Rodríguez-Fernández and F. Sanz, J. Inorg. Biochem., 89, 74 (2002); doi:10.1016/S0162-0134(01)00408-1.

J. Huang, J.R. Song and Y.H. Ren, Chinese J. Struct. Chem., 25, 168 (2006).

Y. Nan, H. Miao and Z. Yang, Org. Lett., 2, 297 (2000); doi:10.1021/ol991327b.

J.A.J. Breuzard, M.L. Tommasino, F. Touchard, M. Lemaire and M.C. Bonnet, J. Mol. Catal. A, Chem., 156, 223 (2000); doi:10.1016/S1381-1169(99)00401-X.

P. Buhlmann, S. Nishizawa, K.P. Xiao and Y. Umezawa, Tetrahedron, 53, 1647 (1997); doi:10.1016/S0040-4020(96)01094-0.

Y.M. Zhang, W.X. Xu, Y.Q. Zhou, H. Yao and T.-B. Wei, Acta Chim. Sin., 64, 79 (2006).

J. Valdés-Martínez, S. Hernández-Ortega, M. Rubio, D.T. Li, J.K. Swearingen, W. Kaminsky, D.R. Kelman and D.X. West, J. Chem. Crystallogr., 34, 533 (2004); doi:10.1023/B:JOCC.0000042022.16392.99.

K.R. Koch, C. Sacht and S. Bourne, Inorg. Chim. Acta, 232, 109 (1995); doi:10.1016/0020-1693(94)04375-6.

G.M. Sheldrick, SHELXL-97. Program for the Refinement of Crystal Structures. University of Göttingen, Germany 1997.

W.K. Dong, X.Q. Yang and J.H. Feng, Acta Crystallogr., E62, o3459 (2006); doi:10.1107/S1600536806027516.

W.K. Dong, X.Q. Yang, L.-Q. Chai, Y.-Q. Tian and J.-H. Feng, Phosphorus Sulfur Silicon Rel. Elem., 183, 1181 (2008); doi:10.1080/10426500701610952.

W.K. Dong, Y.X. Sun, Y.P. Zhang, L. Li, X.N. He and X.L. Tang, Inorg. Chim. Acta, 362, 117 (2009); doi:10.1016/j.ica.2008.03.128.

W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009); doi:10.1016/j.poly.2009.03.017.

W.K. Dong, Y.X. Sun, Y.P. Zhang, L. Li, X.N. He and X.L. Tang, Inorg. Chim. Acta, 362, 117 (2009); doi:10.1016/j.ica.2008.03.128.

Issue

Vol. 26 No. 1 (2014): Vol 26 Issue 1

Synthesis, Supramolecular Structure, Antimicrobial and Plant-Growth Regulation Activities of N-Benzoylthiourea

Corresponding Author(s) : Xiu-Yan Dong

Abstract

Keywords

Full Article

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