Issue

Vol. 26 No. 1 (2014): Vol 26 Issue 1

Copyright (c) 2014 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Crystal Structure of Charge Separate Manganese Complex

https://doi.org/10.14233/ajchem.2014.15836
Xiaoping Gan
Department of Applied Chemistry, School of Science, Anhui Agricultural University, Hefei 230036, P.R. China
Mingjie Chu
Department of Applied Chemistry, School of Science, Anhui Agricultural University, Hefei 230036, P.R. China
Jianguo Yao
Department of Applied Chemistry, School of Science, Anhui Agricultural University, Hefei 230036, P.R. China
Wenqian Geng
Department of Applied Chemistry, School of Science, Anhui Agricultural University, Hefei 230036, P.R. China
Xiuli Zhang
Department of Applied Chemistry, School of Science, Anhui Agricultural University, Hefei 230036, P.R. China
Yupeng Tian
School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, P.R. China
Hongping Zhou
School of Chemistry and Chemical Engineering, Anhui University, Hefei 230039, P.R. China

Corresponding Author(s) : Hongping Zhou

zhpzhp@263.net

Asian Journal of Chemistry, Vol. 26 No. 1 (2014): Vol 26 Issue 1

Abstract

A novel complex Mn(taba)2·4H2O [Htaba = 4-(1H-1,2,4-triazol-1-yl) benzoic acid] containing carboxylate-triazole ligands has been synthesized and characterized by elemental analyses, IR and X-ray single crystal diffraction. The crystal of the complex belongs to the triclinic system and P-1 space group with a = 6.153 (5) Å, b = 7.047 (5) Å, c = 12.257 (5) Å, a = 80.366 (5)°, b = 87.997 (5)°, g = 72.673 (5)°, Z = 1, V = 500.1 (6) Å3, Dc = 1.671 g cm-3, μ = 0.723 mm-1, F(000) = 259, Rint = 0.0373, wR = 0.0993. X-ray crystallography shows the manganese(II) ion is coordinated with two triazole nitrogen atoms from two ligands and four oxygen atoms from four water molecules. However, manganese(II) ions only coordinate with N from triazole and not with O from carboxylate group of the ligand, which is different with the reported manganese complexes. In additional, the title complex is a charge separate style that the positive charge center is in manganese atom and the negative charge center is in the carboxylic root of the ligand.

Keywords

Manganese complex Crystal structure Charge separate structure
Gan, X., Chu, M., Yao, J., Geng, W., Zhang, X., Tian, Y., & Zhou, H. (2013). Synthesis and Crystal Structure of Charge Separate Manganese Complex. Asian Journal of Chemistry, 26(1), 257–260. https://doi.org/10.14233/ajchem.2014.15836
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. N. Mitic, C.J. Noble, L.R. Gahan, G.R. Hanson and G. Schenk, J. Am. Chem. Soc., 131, 8173 (2009).
  2. B. Epel, K.-O. Schäfer, A. Quentmeier, C. Friedrich and W. Lubitz, J. Biol. Inorg. Chem., 10, 636 (2005).
  3. M.M. Najafpour, J. Photochem. Photobiol. B, 104, 111 (2011).
  4. A. Bagchi and T. Ghosh, Biochem. Biophys. Res. Commun., 335, 609 (2005).
  5. M.M. Najafpour, M. Holynska, A.N. Shamkhali, M. Amini, S.H. Kazemi, S. Zaynalpoor, R. Mohamadi, M. Bagherzadeh and T. Lis, Polyhedron, 34, 202 (2012).
  6. P. Zhu and H.M. Li, J. Mol. Struct., 992, 106 (2011).
  7. D.J. Gravert and J.H. Griffin, Inorg. Chem., 35, 4837 (1996).
  8. J. Carranza, J. Sletten, F. Lloret and M. Julve, Polyhedron, 28, 2249 (2009).
  9. L.V. Ababei, A. Kriza, C. Andronescu and A.M. Musuc, J. Therm. Anal. Calorim., 107, 573 (2012).
  10. R. Dey and D. Ghoshal, Polyhedron, 34, 24 (2012).
  11. X.S. Wang, Y.Z. Tang, X.F. Huang, Z.R. Qu, C.M. Che, P.W. Chan and R.G. Xiong, Inorg. Chem., 44, 5278 (2005).
  12. F. Nouar, J.F. Eubank, T. Bousquet, L. Wojtas, M.J. Zaworotko and M. Eddaoudi, J. Am. Chem. Soc., 130, 1833 (2008).
  13. Y. Zhang, R. Yang, F. Liu and K. Li, Anal. Chem., 76, 7336 (2004).
  14. T. Bando, H. Iida, Z.F. Tao, A. Narita, N. Fukuda, T. Yamori and H. Sugiyama, Chem. Biol., 10, 751 (2003).
  15. A.W. Addison, T.N. Rao, J. Reedijk, J. van Rijn and G.C. Verschoor, J. Chem. Soc. Dalton. Trans., 6, 1349 (1984).
  16. R.T. Conley, Infrared Spectroscopy, Allyn & Bacon, Boston, p. 5/153-5/168 (1966).
  17. D.W. Fu, J.Z. Ge, J. Dai, H.Y. Ye and Z.R. Qu, Inorg. Chem. Commun., 12, 994 (2009).
  18. G.M. Sheldrick, SHELXS-97 Program for Crystal Structure Determination, University of Göttingen, Germany, p. 3/43-4/122 (1997).
  19. S. Gao, J.W. Liu, L.H. Huo, H. Zhao and J.G. Zhao, Acta Crystallogr., C60, 537 (2004).
  20. M. Dinca, A.F. Yu and J.R. Long, J. Am. Chem. Soc., 128, 8904 (2006).
  21. G.W. Yang, Q.Y. Li, Y. Zhou, G.Q. Gu, Y.S. Ma and R.X. Yuan, Inorg. Chim. Acta., 362, 1234 (2009).
  22. Y. Liao, J.K. Feng, L. Yang, A.M. Ren and H.X. Zhang, Organometallics, 24, 385(2005).
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0