Comparison of Analysis Results and Modification of Na+-Montmorillonite with Ionic Liquids

Gulay Baysal; Haluk Aydin

doi:10.14233/ajchem.2014.15471

Issue

Vol. 26 No. 3 (2014): Vol 26 Issue 3

Issue Published : January 30, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Comparison of Analysis Results and Modification of Na+-Montmorillonite with Ionic Liquids

https://doi.org/10.14233/ajchem.2014.15471

Gulay Baysal

University of Dicle, Diyarbakir, Turkey

Haluk Aydin

Department of Chemistry, University of Dicle, Diyarbakir, Turkey

Corresponding Author(s) : Gulay Baysal

gulaybaysal@gmail.com

Asian Journal of Chemistry, Vol. 26 No. 3 (2014): Vol 26 Issue 3
Article Published : January 30, 2014

Abstract

In this study, preliminary data are reported on the modification of sodium montmorillonite modified with imidazolium and pyridinium-based ionic liquids. Commercially available unmodified clay was treated under different conditions with aqueous solutions of three ionic liquids such as 1-butyl 3-methyl imidazolium tetrafluoroborate, 1-butyl 4-methyl pyridinium tetrafluoroborate and 1-methyl 3-octyl imidazolium tetrafluoroborate and the results were compared with ammonium dodecyl sulphate. The modified materials were characterized by FTIR, TGA, SEM and WXRD analysis. The analysis results show an overall increase in interlamellar spacing as a result of sodium cation exchange with the cations of the ionic liquids and long chain quaternary ammonium salt. The thermal stabilities of the organoclays is higher than unmodified clay.

Keywords

Na -Montmorillonite Ionic liquids Organoclays Modification Quaternary ammonium salt

Baysal, G., & Aydin, H. (2014). Comparison of Analysis Results and Modification of Na+-Montmorillonite with Ionic Liquids. Asian Journal of Chemistry, 26(3), 672–676. https://doi.org/10.14233/ajchem.2014.15471

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References

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References

H. Zheng, K. Jiang, T. Abe and Z. Ogumi, Carbon, 44, 203 (2006); doi:10.1016/j.carbon.2005.07.038.

K. Haerens, E. Matthijs, A. Chmielarz and B. Van der Bruggen, J. Environ. Manage., 90, 3245 (2009); doi:10.1016/j.jenvman.2009.04.013.

W. Liu, L. Cheng, Y. Zhang, H. Wang and M. Yu, J. Mol. Liq., 140, 68 (2008); doi:10.1016/j.molliq.2008.01.008.

S. Nadeem, M.A. Munawar, S. Ahmad, M. Smiglak, D.M. Drab, K.I. Malik, R. Amjad, C.M. Ashraf and R.D. Rogers, ARKIVOC, (vii) 19 (2010).

M. Shamsipur, A.A.M. Beigi, M. Teymouri, S.M. Pourmortazavi and M. Irandoust, J. Mol. Liq., 157, 43 (2010); doi:10.1016/j.molliq.2010.08.005.

H. Erdemi, Ü. Akbey and H.W. Meyer, Solid State Ion., 181, 1586 (2010); doi:10.1016/j.ssi.2010.08.018.

V.V. Namboodiri and R.S. Varma, Tetrahedron Lett., 43, 5381 (2002); doi:10.1016/S0040-4039(02)01075-4.

H. Ohno and M. Yoshizawa, Solid State Ion., 154–155, 303 (2002); doi:10.1016/S0167-2738(02)00526-X.

R. Kanzaki, T. Mitsugi, S. Fukuda, K. Fujii, M. Takeuchi, Y. Soejima, T. Takamuku, T. Yamaguchi, Y. Umebayashi and S.- Ishiguro, J. Mol. Liq., 147, 77 (2009); doi:10.1016/j.molliq.2008.10.003.

S. Thomaier and W. Kunz, J. Mol. Liq., 130, 104 (2007); doi:10.1016/j.molliq.2006.04.013.

M. Mohammed, B. Tahar, D. Aicha and H.D. Eddine, E-J. Chem., 7(S1), S61 (2010); doi:10.1155/2010/637549.

Y. Zang, W. Xu, D. Qiu, D. Chen, R. Chen and S. Su, Thermochim. Acta, 474, 1 (2008); doi:10.1016/j.tca.2008.04.017

L.B. de Paiva, A.R. Morales and F.R. Valenzuela Díaz, Appl. Clay Sci., 42, 8 (2008); doi:10.1016/j.clay.2008.02.006.

A. Favre and G. Lagaly, Clay Miner., 26, 19 (1991); doi:10.1180/claymin.1991.026.1.03.

S. Abend and G. Lagaly, Appl. Clay Sci., 16, 201 (2000); doi:10.1016/S0169-1317(99)00040-X.

A. Chagnes, H. Allouchi, B. Carre and D. Lemordant, Solid State Ionics, 176, 1419 (2005); doi:10.1016/j.ssi.2005.03.005.

T. Mandalia and F. Bergaya, J. Phys. Chem. Solids, 67, 836 (2006); doi:10.1016/j.jpcs.2005.12.007.

B. Pourabas and V. Raeesi, Polymer, 46, 5533 (2005); doi:10.1016/j.polymer.2005.04.055.

M. Karna, M. Lahtinen and J. Valkonen, J. Mol. Struct., 922, 64 (2009); doi:10.1016/j.molstruc.2009.01.041.

N.E. Heimer, R.E. Del Sesto, Z. Meng, J.S. Wilkes and W.R. Carper, J. Mol. Liq., 124, 84 (2006); doi:10.1016/j.molliq.2005.08.004.

N.H. Kim, S.V. Malhotra and M. Xanthos, Microporous Mesoporous Mater., 96, 29 (2006); doi:10.1016/j.micromeso.2006.06.017.

W.H. Awad, J.W. Gilman, M. Nyden, R.H. Harris Jr., T.E. Sutto Jr., J. Callahan, P.C. Trulove, H.C. DeLong and D.M. Fox, Thermochim. Acta, 409, 3 (2004); doi:10.1016/S0040-6031(03)00334-4.

J.W. Gilman, W.H. Awad, R.D. Davis, J. Shields, R.H. Harris, C. Davis, A.B. Morgan, T.E. Sutto Jr., J. Callahan, P.C. Trulove and H.C. DeLong, Chem. Mater., 14, 3776 (2002); doi: 10.1021/cm011532x.

Issue

Vol. 26 No. 3 (2014): Vol 26 Issue 3

Comparison of Analysis Results and Modification of Na+-Montmorillonite with Ionic Liquids

Corresponding Author(s) : Gulay Baysal

Abstract

Keywords

Full Article

Download Citation

References

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