Ni(II) Complex Extended Structures Sustained by Hydrogen Bonding, p-p and C-H&middot;&middot;&middot;p Interactions

Zhen-Ming Zhang; Fu-Jun Yin; Gui Zhao; Li-Ping Wang; Hong Zhao

doi:10.14233/ajchem.2014.15613

Issue

Vol. 26 No. 3 (2014): Vol 26 Issue 3

Issue Published : January 30, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Ni(II) Complex Extended Structures Sustained by Hydrogen Bonding, p-p and C-H···p Interactions

https://doi.org/10.14233/ajchem.2014.15613

Zhen-Ming Zhang

School of Environment Science and Spatial Informatics, China University of Mining and Technology, Xuzhou 221116, P.R. China ; Jiangsu Development Research Insititute of Marine Resources, Huaihai Institute of Technology, Lianyungang 222005, P.R. China

Fu-Jun Yin

Jiangsu Development Research Insititute of Marine Resources, Huaihai Institute of Technology, Lianyungang 222005, P.R. China

Gui Zhao

Huaihai Institute of Technology, Lianyungang 222005, P.R. China

Li-Ping Wang

School of Environment Science and Spatial Informatics, China University of Mining and Technology, Xuzhou 221116, P.R. China

Hong Zhao

Jiangsu Development Research Insititute of Marine Resources, Huaihai Institute of Technology, Lianyungang 222005, P.R. China

Corresponding Author(s) : Li-Ping Wang

yinfujun2008@126.com

Asian Journal of Chemistry, Vol. 26 No. 3 (2014): Vol 26 Issue 3
Article Published : January 30, 2014

Abstract

The complex [Ni(NAA)₂(im)₆](1) (where H₂NAA = a-naphthylacetic acid and im = imidazole) has been synthesized under solvothermal conditions. The complex fully characterized by IR spectroscopy, elemental analysis and single crystal X-ray diffraction. In complex 1, Ni(II) is coordinated by six N atoms with a octahedral coordination geometry. This mononuclear complex is further extended into three-dimensional structure via p-p, C-H···p and hydrogen bonding interactions. The thermal stable property of complex 1 is also reported.

Keywords

Hydrogen bond C-H···p Interaction p-p Interaction Thermal stable property

Zhang, Z.-M., Yin, F.-J., Zhao, G., Wang, L.-P., & Zhao, H. (2014). Ni(II) Complex Extended Structures Sustained by Hydrogen Bonding, p-p and C-H···p Interactions. Asian Journal of Chemistry, 26(3), 814–816. https://doi.org/10.14233/ajchem.2014.15613

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L.F. Ma, L.Y. Wang, J.L. Hu, Y.Y. Wang, S.R. Batten and J.G. Wang, CrystEngComm, 11, 777 (2009); doi:10.1039/b815916e.

A.M. Beatty, Coord. Chem. Rev., 246, 131 (2003); doi:10.1016/S0010-8545(03)00120-6.

K. Biradha, CrystEngComm, 5, 374 (2003); doi:10.1039/b309903b.

A.H. Yang, H. Zhang, H.L. Gao, W.Q. Zhang, L. He and J.Z. Cui, Cryst. Growth Des., 8, 3354 (2008); doi:10.1021/cg800291p.

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F. Rakotondradany, M.A. Whitehead, A.M. Lebuis and H.F. Sleiman, Chem. Eur. J., 9, 4771 (2003); doi:10.1002/chem.200304864.

T.F. Tan, J. Mol. Struct., 840, 6 (2007); doi:10.1016/j.molstruc.2006.11.036.

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