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Ni(II) Complex Extended Structures Sustained by Hydrogen Bonding, p-p and C-H···p Interactions
Corresponding Author(s) : Li-Ping Wang
Asian Journal of Chemistry,
Vol. 26 No. 3 (2014): Vol 26 Issue 3
Abstract
The complex [Ni(NAA)2(im)6](1) (where H2NAA = a-naphthylacetic acid and im = imidazole) has been synthesized under solvothermal conditions. The complex fully characterized by IR spectroscopy, elemental analysis and single crystal X-ray diffraction. In complex 1, Ni(II) is coordinated by six N atoms with a octahedral coordination geometry. This mononuclear complex is further extended into three-dimensional structure via p-p, C-H···p and hydrogen bonding interactions. The thermal stable property of complex 1 is also reported.
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- S. Kitagawa, R. Kitaura and S.I. Noro, Angew. Chem. Int. Ed. Engl., 43, 2334 (2004); doi:10.1002/anie.200300610.
- L.F. Ma, L.Y. Wang, J.L. Hu, Y.Y. Wang, S.R. Batten and J.G. Wang, CrystEngComm, 11, 777 (2009); doi:10.1039/b815916e.
- A.M. Beatty, Coord. Chem. Rev., 246, 131 (2003); doi:10.1016/S0010-8545(03)00120-6.
- K. Biradha, CrystEngComm, 5, 374 (2003); doi:10.1039/b309903b.
- A.H. Yang, H. Zhang, H.L. Gao, W.Q. Zhang, L. He and J.Z. Cui, Cryst. Growth Des., 8, 3354 (2008); doi:10.1021/cg800291p.
- L.J. Prins, D.N. Reinhoudt and P. Timmerman, Angew. Chem. Int. Ed. Engl., 40, 2382 (2001); doi:10.1002/1521-3773(20010702)40:13<2382::AID-ANIE2382>3.0.CO;2-G.
- F. Rakotondradany, M.A. Whitehead, A.M. Lebuis and H.F. Sleiman, Chem. Eur. J., 9, 4771 (2003); doi:10.1002/chem.200304864.
- T.F. Tan, J. Mol. Struct., 840, 6 (2007); doi:10.1016/j.molstruc.2006.11.036.
- A. Rivera, J. Ríos-Motta, A.P. Hernández-Barragán and P. Joseph-Nathan, J. Mol. Struct., 831, 180 (2007); doi:10.1016/j.molstruc.2006.08.002.
- G.M. Sheldrick. A Program for the Siemens Areas Detector AB Sorption Correction, University of Göttingen, Germany (1997).
- G.M. Sheldrick, SHELX97, Program for Solution of Crystal Structure; University of Göttingen, Germany (1997).
- G. Wu, X.F. Wang, L. Guo and H.H. Li, J. Chem. Crystallogr., 41, 1071 (2011); doi:10.1007/s10870-011-0048-0.
References
S. Kitagawa, R. Kitaura and S.I. Noro, Angew. Chem. Int. Ed. Engl., 43, 2334 (2004); doi:10.1002/anie.200300610.
L.F. Ma, L.Y. Wang, J.L. Hu, Y.Y. Wang, S.R. Batten and J.G. Wang, CrystEngComm, 11, 777 (2009); doi:10.1039/b815916e.
A.M. Beatty, Coord. Chem. Rev., 246, 131 (2003); doi:10.1016/S0010-8545(03)00120-6.
K. Biradha, CrystEngComm, 5, 374 (2003); doi:10.1039/b309903b.
A.H. Yang, H. Zhang, H.L. Gao, W.Q. Zhang, L. He and J.Z. Cui, Cryst. Growth Des., 8, 3354 (2008); doi:10.1021/cg800291p.
L.J. Prins, D.N. Reinhoudt and P. Timmerman, Angew. Chem. Int. Ed. Engl., 40, 2382 (2001); doi:10.1002/1521-3773(20010702)40:13<2382::AID-ANIE2382>3.0.CO;2-G.
F. Rakotondradany, M.A. Whitehead, A.M. Lebuis and H.F. Sleiman, Chem. Eur. J., 9, 4771 (2003); doi:10.1002/chem.200304864.
T.F. Tan, J. Mol. Struct., 840, 6 (2007); doi:10.1016/j.molstruc.2006.11.036.
A. Rivera, J. Ríos-Motta, A.P. Hernández-Barragán and P. Joseph-Nathan, J. Mol. Struct., 831, 180 (2007); doi:10.1016/j.molstruc.2006.08.002.
G.M. Sheldrick. A Program for the Siemens Areas Detector AB Sorption Correction, University of Göttingen, Germany (1997).
G.M. Sheldrick, SHELX97, Program for Solution of Crystal Structure; University of Göttingen, Germany (1997).
G. Wu, X.F. Wang, L. Guo and H.H. Li, J. Chem. Crystallogr., 41, 1071 (2011); doi:10.1007/s10870-011-0048-0.