Synthesis and Crystal Structure of Supramolecular Copper(II) Dimer with Asymmetric Salamo-Type Ligand

Yu-Hua Yang; Li-Sha Zhang; Yu-Jie Zhang; Meng-Meng Zhao; Gang Li; Xiu-Yan Dong

doi:10.14233/ajchem.2014.15987

Issue

Vol. 26 No. 4 (2014): Vol 26 Issue 4

Issue Published : February 15, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Crystal Structure of Supramolecular Copper(II) Dimer with Asymmetric Salamo-Type Ligand

https://doi.org/10.14233/ajchem.2014.15987

Yu-Hua Yang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Li-Sha Zhang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Yu-Jie Zhang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Meng-Meng Zhao

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Gang Li

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Xiu-Yan Dong

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Corresponding Author(s) : Gang Li

li_gang78@126.com

Asian Journal of Chemistry, Vol. 26 No. 4 (2014): Vol 26 Issue 4
Article Published : February 15, 2014

Abstract

A novel Cu(II) dimer, [CuL]₂, has been synthesized via the complexation of Cu(II) acetate monohydrate with 6-ethoxy-4',6'-dibromo-2,2'-[ethylenedioxybis(nitrilo-methylidyne)] diphenol (H₂L) in methanol/acetone mixed solution and characterized structurally by X-ray diffraction method. X-ray crystallographic analysis reveals that the Cu:L is 2:2 in one dimer molecule and the coordination numbers of copper(II) atoms are four and five, resulting in slightly distorted square-planar and square-pyramidal geometries, respectively. With the help of intermolecular C1-H1A···O9, C19-H19B···O4, C20-H20B···O5 and C25-H25···O6 hydrogen-bonding interactions, a self-assembled 2D-layer supramolecular structure is formed.

Keywords

Asymmetric Salamo-type Ligand Cu(II) Dimer Synthesis Crystal Structure

Yang, Y.-H., Zhang, L.-S., Zhang, Y.-J., Zhao, M.-M., Li, G., & Dong, X.-Y. (2014). Synthesis and Crystal Structure of Supramolecular Copper(II) Dimer with Asymmetric Salamo-Type Ligand. Asian Journal of Chemistry, 26(4), 1116–1118. https://doi.org/10.14233/ajchem.2014.15987

Download Citation

References

S.S. Sun, C.L. Stern, S.T. Nguyen and J.T. Hupp, J. Am. Chem. Soc., 126, 6314 (2004); doi:10.1021/ja037378s.
S. Akine, T. Taniguchi and T. Nabeshima, Angew. Chem. Int. Ed., 41, 4670 (2002); doi:10.1002/anie.200290011.
S. Akine, W.K. Dong and T. Nabeshima, Inorg. Chem., 45, 4677 (2006); doi:10.1021/ic060055n.
T. Katsuki, Coord. Chem. Rev., 140, 189 (1995); doi:10.1016/0010-8545(94)01124-T.
M.F. Summers, L.G. Marzilli, N. Bresciani-Pahor and L. Randaccio, J. Am. Chem. Soc., 106, 4478 (1984); doi:10.1021/ja00328a030.
S. Di Bella and I. Fragala, Synth. Met., 115, 191 (2000); doi:10.1016/S0379-6779(00)00354-4.
P.G. Lacroix, Eur. J. Inorg. Chem., 2001, 339 (2001); doi:10.1002/1099-0682(200102)2001:2<339::AID-EJIC339>3.0.CO;2-Z.
J.P. Costes, F. Dahan and A. Dupuis, Inorg. Chem., 39, 165 (2000); doi:10.1021/ic990865h.
J.C.G. Bunzli and C. Piguet, Chem. Rev., 102, 1897 (2002); doi:10.1021/cr010299j.
T. Mizuno, M. Takeuchi and S. Shinkai, Tetrahedron, 55, 9455 (1999); doi:10.1016/S0040-4020(99)00519-0.
M.M. Bhadbhade and D. Srinivas, Inorg. Chem., 32, 6122 (1993); doi:10.1021/ic00078a037.
S. Akine, T. Taniguchi and T. Nabeshima, Chem. Lett., 30, 682 (2001); doi:10.1246/cl.2001.682.
S. Akine, T. Taniguchi, W.K. Dong, S. Masubuchi and T. Nabeshima, J. Org. Chem., 70, 1704 (2005); doi:10.1021/jo048030y.
S. Akine, T. Matsumoto, S. Sairenji and T. Nabeshima, Supramol. Chem., 23, 106 (2011); doi:10.1080/10610278.2010.514906.
(a) W.K. Dong, S.J. Xing, Y.X. Sun, L. Zhao, L.Q. Chai and X.H. Gao, J. Coord. Chem., 65, 1212 (2012); doi:10.1080/00958972.2012.669038.; (b) W.K. Dong, Y.X. Sun, S.J. Xing, Y. Wang and X.H. Gao, Z. Naturforsch, 67, 0197 (2012); doi:10.5560/ZNB.2012.67b0197.; (c) W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009); doi:10.1016/j.poly.2009.03.017.; (d) W.K. Dong, Y.X. Sun, C.Y. Zhao, X.Y. Dong and L. Xu, Polyhedron, 29, 2087 (2010); doi:10.1016/j.poly.2010.04.006.; (e) W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009); doi:10.1016/j.poly.2009.03.017.; (f) W.K. Dong, Y.X. Sun, G.H. Liu, L. Li, X.Y. Dong and X.H. Gao, Z. Anorg. Allg. Chem., 638, 1370 (2012); doi:10.1002/zaac.201200074.; (g) W.K. Dong, K.Q. Li, Y. Zhang, L. Xu, L. Wang and X.Y. Dong, Asian J. Chem., 25, 4398 (2013).
A.W. Addison, T.N. Rao, J. Reedijk, J.V. Rijn and G.C. Verschoor, J. Chem. Soc. Daltons Trans., 1349 (1984); doi:10.1039/DT9840001349.

References

S.S. Sun, C.L. Stern, S.T. Nguyen and J.T. Hupp, J. Am. Chem. Soc., 126, 6314 (2004); doi:10.1021/ja037378s.

S. Akine, T. Taniguchi and T. Nabeshima, Angew. Chem. Int. Ed., 41, 4670 (2002); doi:10.1002/anie.200290011.

S. Akine, W.K. Dong and T. Nabeshima, Inorg. Chem., 45, 4677 (2006); doi:10.1021/ic060055n.

T. Katsuki, Coord. Chem. Rev., 140, 189 (1995); doi:10.1016/0010-8545(94)01124-T.

M.F. Summers, L.G. Marzilli, N. Bresciani-Pahor and L. Randaccio, J. Am. Chem. Soc., 106, 4478 (1984); doi:10.1021/ja00328a030.

S. Di Bella and I. Fragala, Synth. Met., 115, 191 (2000); doi:10.1016/S0379-6779(00)00354-4.

P.G. Lacroix, Eur. J. Inorg. Chem., 2001, 339 (2001); doi:10.1002/1099-0682(200102)2001:2<339::AID-EJIC339>3.0.CO;2-Z.

J.P. Costes, F. Dahan and A. Dupuis, Inorg. Chem., 39, 165 (2000); doi:10.1021/ic990865h.

J.C.G. Bunzli and C. Piguet, Chem. Rev., 102, 1897 (2002); doi:10.1021/cr010299j.

T. Mizuno, M. Takeuchi and S. Shinkai, Tetrahedron, 55, 9455 (1999); doi:10.1016/S0040-4020(99)00519-0.

M.M. Bhadbhade and D. Srinivas, Inorg. Chem., 32, 6122 (1993); doi:10.1021/ic00078a037.

S. Akine, T. Taniguchi and T. Nabeshima, Chem. Lett., 30, 682 (2001); doi:10.1246/cl.2001.682.

S. Akine, T. Taniguchi, W.K. Dong, S. Masubuchi and T. Nabeshima, J. Org. Chem., 70, 1704 (2005); doi:10.1021/jo048030y.

S. Akine, T. Matsumoto, S. Sairenji and T. Nabeshima, Supramol. Chem., 23, 106 (2011); doi:10.1080/10610278.2010.514906.

(a) W.K. Dong, S.J. Xing, Y.X. Sun, L. Zhao, L.Q. Chai and X.H. Gao, J. Coord. Chem., 65, 1212 (2012); doi:10.1080/00958972.2012.669038.; (b) W.K. Dong, Y.X. Sun, S.J. Xing, Y. Wang and X.H. Gao, Z. Naturforsch, 67, 0197 (2012); doi:10.5560/ZNB.2012.67b0197.; (c) W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009); doi:10.1016/j.poly.2009.03.017.; (d) W.K. Dong, Y.X. Sun, C.Y. Zhao, X.Y. Dong and L. Xu, Polyhedron, 29, 2087 (2010); doi:10.1016/j.poly.2010.04.006.; (e) W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009); doi:10.1016/j.poly.2009.03.017.; (f) W.K. Dong, Y.X. Sun, G.H. Liu, L. Li, X.Y. Dong and X.H. Gao, Z. Anorg. Allg. Chem., 638, 1370 (2012); doi:10.1002/zaac.201200074.; (g) W.K. Dong, K.Q. Li, Y. Zhang, L. Xu, L. Wang and X.Y. Dong, Asian J. Chem., 25, 4398 (2013).

A.W. Addison, T.N. Rao, J. Reedijk, J.V. Rijn and G.C. Verschoor, J. Chem. Soc. Daltons Trans., 1349 (1984); doi:10.1039/DT9840001349.

Issue

Vol. 26 No. 4 (2014): Vol 26 Issue 4

Synthesis and Crystal Structure of Supramolecular Copper(II) Dimer with Asymmetric Salamo-Type Ligand

Corresponding Author(s) : Gang Li

Abstract

Keywords

Full Article

Download Citation

References

Table Of Contents