Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Separation and Enrichment of Flavonoids from Orange Peel Using Magnetic Nanoparticles
Corresponding Author(s) : Xiuxiang Huang
Asian Journal of Chemistry,
Vol. 26 No. 4 (2014): Vol 26 Issue 4
Abstract
In present study the Fe3O4 magnetic nanoparticles (MNPs) was acted as adsorption carrier to separate and concentrate flavonoids from the root extractive of orange peel. It involved synthesizing the Fe3O4 magnetic nanoparticle and extracting the flavonoids from orange peel. After magnetic separation and desorption process, the eluent was injected for HPLC analysis. Some parameters influenced extraction efficiency of flavonoids, including amount of Fe3O4 magnetic nanoparticles, shaking time and desorption condition were investigated. Under the optimal conditions, experimental result showed that the extraction efficiency of neohesperidin was higher than others flavonoids and the desorption ratio of neohesperidin is 89.3 %. This study demonstrated that the developed methods for separation and enrichment flavonoids was simple, lower cost and environmental friendly. Therefore, the proposed method had a potential for further application.
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- A.D. Ozsahin and O. Yilmaz, Asian J. Chem., 22, 6403 (2010).
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References
M.K. Khan, M. Abert-Vian, A.-S. Fabiano-Tixier, O. Dangles and F. Chemat, Food Chem., 119, 851 (2010); doi:10.1016/j.foodchem.2009.08.046.
E.G. Haggag, I.I. Mahmoud, E.A. Abou-Moustafa and T.J. Mabry, Asian J. Chem., 11, 707 (1999).
X.T. Geng, P. Ren, G.P. Pi, R.F. Shi, Z. Yuan and C.H. Wang, J. Chromatogr. A, 1216, 8331 (2009); doi:10.1016/j.chroma.2009.09.015.
C. Rice-Evans, Free Radic. Biol. Med., 36, 827 (2004); doi:10.1016/j.freeradbiomed.2003.12.012.
B. Mello and M.D. Hubinger, Int. J. Food Sci. Technol., 47, 2510 (2012); doi:10.1111/j.1365-2621.2012.03129.x.
A.D. Ozsahin and O. Yilmaz, Asian J. Chem., 22, 6403 (2010).
W. Routray and V. Orsat, Food Bioprocess Technol., 5, 409 (2012); doi:10.1007/s11947-011-0573-z.
E. de Rijke, P. Out, W.M.A. Niessen, F. Ariese, C. Gooijer and U.A.Th. Brinkman, J. Chromatogr. A, 1112, 31 (2006); doi:10.1016/j.chroma.2006.01.019.
L.H. Wang, Y.H. Mei, F. Wang, X.S. Liu and Y. Chen, Sep. Purif. Technol., 77, 397 (2011); doi:10.1016/j.seppur.2010.12.020.
M. Furusawa, H. Tsuchiya, M. Nagayama, T. Tanaka, K. Nakaya and M. Iinuma, J. Health Sci., 49, 475 (2003); doi:10.1248/jhs.49.475.
H. Bae, G.K. Jayaprakasha, J. Jifon and B.S. Patil, Food Chem., 130, 751 (2012); doi:10.1016/j.foodchem.2011.07.041.
X.T. Geng, P. Ren, G.P. Pi, R.F. Shi, Z. Yuan and C.H. Wang, J. Chromatogr. A, 1216, 8331 (2009); doi:10.1016/j.chroma.2009.09.015.
Y. Zhang, S. Li, X. Wu and X. Zhao, Chin. J. Chem. Eng., 15, 872 (2007); doi:10.1016/S1004-9541(08)60017-8.
L.G. Chen, T. Wang and J. Tong, TrAC Trends Anal. Chem., 30, 1095 (2011); doi:10.1016/j.trac.2011.02.013.
L.S. Qing, J. Xiong, Y. Xue, Y.M. Liu, B. Guang, L.S. Ding and X. Liao, J. Sep. Sci., 34, 3240 (2011); doi:10.1002/jssc.201100578.
H.F. Zhang and Y.P. Shi, Analyst, 137, 910 (2012); doi:10.1039/c1an15873b.
Y. Hiratsuka, N. Funaya, H. Matsunaga and J. Haginaka, J. Pharm. Biomed. Anal., 75, 180 (2013); doi:10.1016/j.jpba.2012.11.030.
Z. Wang, H. Guo, Y. Yu and N. He, J. Magnet. Magn. Mater., 302, 397 (2006); doi:10.1016/j.jmmm.2005.09.044.
K.M. Giannoulis, G.Z. Tsogas, D.L. Giokas and A.G. Vlessidis, Talanta, 99, 62 (2012); doi:10.1016/j.talanta.2012.05.021.
C.D. Stalikas, J. Sep. Sci., 30, 3268 (2007); doi:10.1002/jssc.200700261.