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Synthesis, Crystal Structure and Property of (CdCl3)n·nH3O With a One-Dimensional Infinite Chain-like Structure
Corresponding Author(s) : Wen-Tong Chen
Asian Journal of Chemistry,
Vol. 26 No. 4 (2014): Vol 26 Issue 4
Abstract
A cadmium chloride with protonated water molecules, (CdCl3)n·nH3O (1), has been synthesized via hydrothermal reaction and structurally characterized by single crystal X-ray diffraction. Compound 1 features a one-dimensional (1-D) infinite chain-like structure, which is constructed from edge-shared CdCl6 octahedra. Compound 1 displays an optical gap of 1.56 eV.
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- D.E. Reichert, J.S. Lewis and C.J. Anderson, Coord. Chem. Rev., 184, 3 (1999); doi:10.1016/S0010-8545(98)00207-0.
- P.J. Sadler, H.Y. Li and H.Z. Sun, Coord. Chem. Rev., 185–186, 689 (1999); doi:10.1016/S0010-8545(99)00018-1.
- C.W. Schwietert and J.P. McCue, Coord. Chem. Rev., 184, 67 (1999); doi:10.1016/S0010-8545(98)00205-7.
- A.D. Phillips, L. Gonsalvi, A. Romerosa, F. Vizza and M. Peruzzini, Coord. Chem. Rev., 248, 955 (2004); doi:10.1016/j.ccr.2004.03.010.
- G. Kortüm, Reflectance Spectroscopy, Springer Verlag: New York (1969).
- G.-L. Zhang, Y.-T. Li, X.-Q. Luo and Z.-Y. Wu, Chinese J. Struct. Chem., 27, 1230 (2008).
- H.-M. Guo, H.-D. Xian, J. Zhang, T.-K. Ying and G.-L. Zhao, Wuji Huaxue Xuebao (Chinese J. Inorg. Chem.), 24, 1709 (2008).
- F.Q. Huang, K. Mitchell and J.A. Ibers, Inorg. Chem., 40, 5123 (2001); doi:10.1021/ic0104353.
- K. Zweibel and R. Mitchell, In CuInSe2 and CdTe: Scale-Up for Manufacturing; SERI Publication, prepared for US DOE under Contract No. DE-AC02-83CH10093 (1989).
- R.H. Dube, Photovoltaic Materials; Imperial College Press, p. 184 (1988).
- R. Tillinski, C. Rumpf, C. Näther, P. Dürichen, I. Jeß, S.A. Schunk and W. Bensch, Z. Anorg. Allg. Chem., 624, 1285 (1998); doi:10.1002/(SICI)1521-3749(199808)624:8<1285::AID-ZAAC1285>3.0.CO;2-5.
- C.H. Champness, Phosphorous Sulfur Silicon Rel. Elem., 38, 385 (1988); doi:10.1080/03086648808079733.
References
D.E. Reichert, J.S. Lewis and C.J. Anderson, Coord. Chem. Rev., 184, 3 (1999); doi:10.1016/S0010-8545(98)00207-0.
P.J. Sadler, H.Y. Li and H.Z. Sun, Coord. Chem. Rev., 185–186, 689 (1999); doi:10.1016/S0010-8545(99)00018-1.
C.W. Schwietert and J.P. McCue, Coord. Chem. Rev., 184, 67 (1999); doi:10.1016/S0010-8545(98)00205-7.
A.D. Phillips, L. Gonsalvi, A. Romerosa, F. Vizza and M. Peruzzini, Coord. Chem. Rev., 248, 955 (2004); doi:10.1016/j.ccr.2004.03.010.
G. Kortüm, Reflectance Spectroscopy, Springer Verlag: New York (1969).
G.-L. Zhang, Y.-T. Li, X.-Q. Luo and Z.-Y. Wu, Chinese J. Struct. Chem., 27, 1230 (2008).
H.-M. Guo, H.-D. Xian, J. Zhang, T.-K. Ying and G.-L. Zhao, Wuji Huaxue Xuebao (Chinese J. Inorg. Chem.), 24, 1709 (2008).
F.Q. Huang, K. Mitchell and J.A. Ibers, Inorg. Chem., 40, 5123 (2001); doi:10.1021/ic0104353.
K. Zweibel and R. Mitchell, In CuInSe2 and CdTe: Scale-Up for Manufacturing; SERI Publication, prepared for US DOE under Contract No. DE-AC02-83CH10093 (1989).
R.H. Dube, Photovoltaic Materials; Imperial College Press, p. 184 (1988).
R. Tillinski, C. Rumpf, C. Näther, P. Dürichen, I. Jeß, S.A. Schunk and W. Bensch, Z. Anorg. Allg. Chem., 624, 1285 (1998); doi:10.1002/(SICI)1521-3749(199808)624:8<1285::AID-ZAAC1285>3.0.CO;2-5.
C.H. Champness, Phosphorous Sulfur Silicon Rel. Elem., 38, 385 (1988); doi:10.1080/03086648808079733.