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Vol. 26 No. 2 (2014): Vol 26 Issue 2

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Synthesis and Crystal Structure of Two Polydimensional Molecular Architectures from Cobalt(II), Copper(II) Complexes of 2,4-Diamino-6-pyridyl-1,3,5-triazine

https://doi.org/10.14233/ajchem.2014.15424
Jia-Yan Li1
1Oxbridge College, Kunming University of Science and Technology, 650106 Kunming, P.R. China 2Department of Chemistry, Yunnan University, 650031 Kunming, P.R. China 3State Key Lab of Advanced Technologies for PGM, Kunming Institute of Precious Metals, 650106 Kunming, P.R. China *Corresponding authors: E-mail: ningping58@sina.com
Ming-Jin Xie2
1Oxbridge College, Kunming University of Science and Technology, 650106 Kunming, P.R. China 2Department of Chemistry, Yunnan University, 650031 Kunming, P.R. China 3State Key Lab of Advanced Technologies for PGM, Kunming Institute of Precious Metals, 650106 Kunming, P.R. China *Corresponding authors: E-mail: ningping58@sina.com
Jing Jiang3
1Oxbridge College, Kunming University of Science and Technology, 650106 Kunming, P.R. China 2Department of Chemistry, Yunnan University, 650031 Kunming, P.R. China 3State Key Lab of Advanced Technologies for PGM, Kunming Institute of Precious Metals, 650106 Kunming, P.R. China *Corresponding authors: E-mail: ningping58@sina.com
Qiao-Wen Chang3
1Oxbridge College, Kunming University of Science and Technology, 650106 Kunming, P.R. China 2Department of Chemistry, Yunnan University, 650031 Kunming, P.R. China 3State Key Lab of Advanced Technologies for PGM, Kunming Institute of Precious Metals, 650106 Kunming, P.R. China *Corresponding authors: E-mail: ningping58@sina.com
Qing-Song Ye3
1Oxbridge College, Kunming University of Science and Technology, 650106 Kunming, P.R. China 2Department of Chemistry, Yunnan University, 650031 Kunming, P.R. China 3State Key Lab of Advanced Technologies for PGM, Kunming Institute of Precious Metals, 650106 Kunming, P.R. China *Corresponding authors: E-mail: ningping58@sina.com
Wei-Ping Liu3
1Oxbridge College, Kunming University of Science and Technology, 650106 Kunming, P.R. China 2Department of Chemistry, Yunnan University, 650031 Kunming, P.R. China 3State Key Lab of Advanced Technologies for PGM, Kunming Institute of Precious Metals, 650106 Kunming, P.R. China *Corresponding authors: E-mail: ningping58@sina.com
Jia-Lin Chen3
1Oxbridge College, Kunming University of Science and Technology, 650106 Kunming, P.R. China 2Department of Chemistry, Yunnan University, 650031 Kunming, P.R. China 3State Key Lab of Advanced Technologies for PGM, Kunming Institute of Precious Metals, 650106 Kunming, P.R. China *Corresponding authors: E-mail: ningping58@sina.com
Ping Ning1
1Oxbridge College, Kunming University of Science and Technology, 650106 Kunming, P.R. China 2Department of Chemistry, Yunnan University, 650031 Kunming, P.R. China 3State Key Lab of Advanced Technologies for PGM, Kunming Institute of Precious Metals, 650106 Kunming, P.R. China *Corresponding authors: E-mail: ningping58@sina.com

Asian Journal of Chemistry, Vol. 26 No. 2 (2014): Vol 26 Issue 2

Abstract

Two new Co(II) and Cu(II) complexes of 2,4-diamino-6-pyridyl-1,3,5-triazine (ptzda) have been synthesized and structurally characterized. Crystal structure studies reveal that Co atom is six-coordinated by four nitrogen atoms from four dicyanamide anions and the other two nitrogen atoms from 2,4-diamino-6-pyridyl-1,3,5-triazine and each cobalt atom are connected by two [N(CN)2]– anions to form an infinite double-stranded bridge fashion to give 2D ladder-like motifs. Whereas, Cu atom is five-coordinated by two nitrogen atoms from two dicyanamide anions and the other two nitrogen atoms from 2,4-diamino-6-pyridyl-1,3,5-triazine and each copper atom is connected by one methanol to form an infinite double-stranded bridge fashion to give 1D ladder-like motifs.

Keywords

1 3 5-Triazines Polydimentional molecular architectures X-Ray crystal structure.
Li1, J.-Y., Xie2, M.-J., Jiang3, J., Chang3, Q.-W., Ye3, Q.-S., Liu3, W.-P., … Ning1, P. (2014). Synthesis and Crystal Structure of Two Polydimensional Molecular Architectures from Cobalt(II), Copper(II) Complexes of 2,4-Diamino-6-pyridyl-1,3,5-triazine. Asian Journal of Chemistry, 26(2), 419–422. https://doi.org/10.14233/ajchem.2014.15424
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