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Synthesis and Crystal Structure of New Nickel(II) Complex with Salen-Type Bisoxime Ligand
Asian Journal of Chemistry,
Vol. 26 No. 2 (2014): Vol 26 Issue 2
Abstract
A new nickel(II) complex, [(NiL{MeOH})2(OAc)2Ni]·2MeOH, has been synthesized via the complexation of nickel(II) acetate tetrahydrate with a new Salen-type bisoxime ligand (H2L). X-Ray crystal structure determination of the nickel(II) complex shows that the hexa-coordinated terminal nickel(II) atoms lie in the N2O2 coordination sphere of Salen-type bisoxime ligands, quadruple μ-phenoxo oxygen atoms from two [NiL] chelates coordinated to the central nickel(II) atom and the two acetate anions coordinated to three nickel(II) atoms through Ni-O-C-O-Ni bridges. Thus, all the three nickel(II) atoms of the Ni(II) complex have distorted octahedral geometries.
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- R. Ziessel, Coord. Chem. Rev., 216-217, 195 (2001); doi:10.1016/S0010-8545(00)00410-0.
- L. Gomes, E. Pereira and B. de Castro, J. Chem. Soc., Dalton Trans., 1373 (2000); doi: 10.1039/A908330H.
- W.K. Dong, C.E. Zhu, H.L. Wu, Y.-J. Ding and T.-Z. Yu, Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 37, 61 (2007); doi:10.1080/15533170601172492.
- W.K. Dong, J.Y. Shi, L. Xu, J.K. Zhong, J.G. Duan and Y.P. Zhang, Appl. Organomet. Chem., 22, 89 (2008); doi:10.1002/aoc.1355.
- W.K. Dong, S.J. Xing, Y.X. Sun, L. Zhao, L.Q. Chai and X.H. Gao, J. Coord. Chem., 65, 1212 (2012); doi:10.1080/00958972.2012.669038.
- W.K. Dong, L. Li, Y.X. Sun, J.F. Tong and J.C. Wu, Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 42, 716 (2012); doi: 10.1080/15533174.2011.615780.
- G.M. Sheldrick, SHELXS97, Program for Crystal Structure Determination, University of Göttingen, Germany (1996).
- G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.
- J. Reglinski, S. Morris and D.E. Stevenson, Polyhedron, 21, 2175 (2002); doi:10.1016/S0277-5387(02)01172-5.
- K. Ueno and A.E. Martell, J. Phys. Chem., 60, 1270 (1956); doi:10.1021/j150543a029.
- W.K. Dong, Y.X. Sun, S.J. Xing, Y. Wang and X.H. Gao, Z. Naturforsch, 67b, 197 (2012); doi:10.5560/ZNB.2012.67b0197.
- H.L. Wu, X.C. Huang, J.K. Yuan, F. Kou, F. Jia, B. Liu and Y. Bai, Z. Naturforsch, 66b, 1049 (2011); doi:10.5560/ZNB.2011.66b1049.
References
R. Ziessel, Coord. Chem. Rev., 216-217, 195 (2001); doi:10.1016/S0010-8545(00)00410-0.
L. Gomes, E. Pereira and B. de Castro, J. Chem. Soc., Dalton Trans., 1373 (2000); doi: 10.1039/A908330H.
W.K. Dong, C.E. Zhu, H.L. Wu, Y.-J. Ding and T.-Z. Yu, Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 37, 61 (2007); doi:10.1080/15533170601172492.
W.K. Dong, J.Y. Shi, L. Xu, J.K. Zhong, J.G. Duan and Y.P. Zhang, Appl. Organomet. Chem., 22, 89 (2008); doi:10.1002/aoc.1355.
W.K. Dong, S.J. Xing, Y.X. Sun, L. Zhao, L.Q. Chai and X.H. Gao, J. Coord. Chem., 65, 1212 (2012); doi:10.1080/00958972.2012.669038.
W.K. Dong, L. Li, Y.X. Sun, J.F. Tong and J.C. Wu, Synth. React. Inorg. Met.-Org. Nano-Met. Chem., 42, 716 (2012); doi: 10.1080/15533174.2011.615780.
G.M. Sheldrick, SHELXS97, Program for Crystal Structure Determination, University of Göttingen, Germany (1996).
G.M. Sheldrick, Acta Crystallogr. A, 64, 112 (2008); doi:10.1107/S0108767307043930.
J. Reglinski, S. Morris and D.E. Stevenson, Polyhedron, 21, 2175 (2002); doi:10.1016/S0277-5387(02)01172-5.
K. Ueno and A.E. Martell, J. Phys. Chem., 60, 1270 (1956); doi:10.1021/j150543a029.
W.K. Dong, Y.X. Sun, S.J. Xing, Y. Wang and X.H. Gao, Z. Naturforsch, 67b, 197 (2012); doi:10.5560/ZNB.2012.67b0197.
H.L. Wu, X.C. Huang, J.K. Yuan, F. Kou, F. Jia, B. Liu and Y. Bai, Z. Naturforsch, 66b, 1049 (2011); doi:10.5560/ZNB.2011.66b1049.