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Catalytic Pyrolysis of Soybean Oil in Presence of Al-MCM-41 Type Catalysts
Corresponding Author(s) : Fengwen Yu
Asian Journal of Chemistry,
Vol. 26 No. 2 (2014): Vol 26 Issue 2
Abstract
The catalysts Al-MCM-41 with different Si/Al ratios (Si/Al = 0, 20, 40, 60, 80, 100) were synthesized hydrothermally, the catalytic activity of the catalysts was studied from the pyrolysis of soybean oil in terms of the yield and composition of the pyrolysis products. The pyrolytic oil was examined by gas chromatograph-mass spectrometry and elemental analysis. Some fuel properties of the bio-fuel were also studied according to China GB methods. The results showed that the bio-fuel obtained from the soybean oil pyrolysis in the presence of Al-MCM-41(80) catalyst has a good agreement with the specification in China.
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References
H. Li, P. Yu and B. Shen, Fuel Process. Technol., 90, 1087 (2009).
B.L. Salvi and N.L. Panwar, Renew. Sustain. Energy Rev., 16, 3680 (2012).
R. Sree, N. Seshu Babu, P.S. Sai Prasad and N. Lingaiah, Fuel Process. Technol., 90, 152 (2009).
E. Kozliak, R. Mota, D. Rodriguez, P. Overby, A. Kubátová, D. Stahl, V. Niri, G. Ogden and W. Seames, Ind. Crops Prod., 43, 386 (2013).
A. Marcilla, A. Gómez-Siurana, J.C.G. Quesada and D. Berenguer, J. Anal. Appl. Pyrol., 85, 327 (2009).
R. Savidha, A. Pandurangan, M. Palanichamy and V. Murugesan, J. Mol. Catal. A: Chem., 211, 165 (2004).
J.S. Beck, J.C. Vartuli, W.J. Roth, M.E. Leonowicz, C.T. Kresge, K.D. Schmitt, C.T.W. Chu, D.H. Olson and E.W. Sheppard, J. Am. Chem. Soc., 114, 10834 (1992).
K.D. Maher and D.C. Bressler, Bioresour. Technol., 98, 2351 (2007).