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Comparative Biodiesel Production Potential of Food Waste Oils as Renewable Energy Source
Asian Journal of Chemistry,
Vol. 26 No. 2 (2014): Vol 26 Issue 2
Abstract
The present study aimed at the production of biodiesel from used soybean, sunflower and canola cooking oil. These oils are used in food processing industry and at retails for deep frying. Waste cooking oil,due to its readily-availability and cost-effectiveness is considered as the most appropriate candidate for the production of biodiesel. Lipase mediated transestrification for the production of fatty acid methyl ester (FAME) of waste cooking oils needs optimization of some important variable such as type of alcohol, temperature, reaction time and oil to alcohol ratio. The best combination for maximum production of biodiesel through transesterification, was achieved at reaction temperature 50 ºC, by using methanol to oil ratio of 1:6 and optimal reaction time of 2 h. The biodiesel conversions from soybean (93 %), sunflower (90 %) and canola (57.5 %) were obtained when oil to alcohol ratio was 1:6. The FT-IR spectroscopy was used to assess biodiesel composition.
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- Y.C. Sharma and B. Singh, Renew. Sustain. Energy Rev., 13, 1646 (2009); doi:10.1016/j.rser.2008.08.009.
- S.A. Ranganathan, S.L. Narasimhan and K. Muthukumar, Bioresour. Technol., 99, 3975 (2008); doi:10.1016/j.biortech.2007.04.060.
- A. Demirbas, Progr. Energy Combust. Sci., 31, 466 (2005); doi:10.1016/j.pecs.2005.09.001.
- G.H. Huang, F. Chen, D. Wei, X.W. Zhang and G. Chen, Appl. Energy, 87, 38 (2010); doi:10.1016/j.apenergy.2009.06.016.
- I. Dincer, Renew. Sustain. Energy Rev., 4, 157 (2000); doi:10.1016/S1364-0321(99)00011-8.
- M. Lapuerta, Progr. Energy Combust., 34, 198 (2008); doi:10.1016/j.pecs.2007.07.001.
- A. Demirbas, Energy Convers. Manage., 50, 14 (2009); doi: 10.1016/j.enconman.2008.09.001.
- U. Schuchardt, R. Sercheli and R.M. Vargas, J. Braz. Chem. Soc., 9, 199 (1998); doi: 10.1590/S0103-50531998000300002.
- H. Fukuda, A. Kondo and H. Noda, J. Biosci. Bioeng., 92, 405 (2001).
- A. Demirbas, Energy Convers. Manage., 43, 2349 (2002); doi:10.1016/S0196-8904(01)00170-4.
- J.Z. Yin, M. Xiao and J.B. Song, Energy Convers. Manage., 49, 908 (2008); doi:10.1016/j.enconman.2007.10.018.
- S. Pleanjai and S.H. Gheewala, Appl. Energy, 86, 209 (2009); doi:10.1016/j.apenergy.2009.05.013.
- A.A. Zabaniotou, E.K. Kantarelis and D.C. Theodoropoulos, Bioresour. Technol., 99, 3174 (2008); doi:10.1016/j.biortech.2007.05.060.
- G.W. Huber, P. O’Connor and A. Corma, Appl. Catal. A Gen., 329, 120 (2007); doi:10.1016/j.apcata.2007.07.002.
- M. Canakci, Bioresour. Technol., 98, 183 (2007); doi:10.1016/j.biortech.2005.11.022.
- J. Connemann and J. Fischer, Biodiesel in Europe 1998: biodiesel processing technologies. pp 1-16. Paper presented at the International Liquid Biofuels Congress, Brazil, (1998).
- W. Zhou, S.K. Konar and D.G.B. Boocock, J. Am. Oil Chem. Soc., 80, 367 (2003); doi:10.1007/s11746-003-0705-1.
- H. Noureddini, X. Gao and R.S. Philkana, Bioresour. Technol., 96, 769 (2005); doi:10.1016/j.biortech.2004.05.029.
- F. Ma and M.A. Hanna, Bioresour. Technol., 70, 1 (1999); doi:10.1016/S0960-8524(99)00025-5.
- P. Nakpong and S. Wootthikanokkhan, J. Sustain. Energy Environ., 1, 105 (2010).
- M. Mathiyazhagan, A. Ganapathi, B. Jaganath, N. Renganayaki and N. Sasireka, Int. J. Chem. Environ. Eng., 2, 119 (2011).
- A. Murugesan, C. Umarani, T.R. Chinnusamy, M. Krishnan, R. Subramanian and N. Neduzchezhain, Renew. Sustain. Energy Rev., 13, 825 (2009); doi:10.1016/j.rser.2008.02.003.
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- S. Saka and D. Kusdiana, Fuel, 80, 225 (2001); doi:10.1016/S0016-2361(00)00083-1.
- R.M. Silverstein, F.X. Webster and D.J. Kiemle, Spectrometric Identification of Organic Compounds, 6th Ed. John Wiley and Sons: New York (1998).
References
Y.C. Sharma and B. Singh, Renew. Sustain. Energy Rev., 13, 1646 (2009); doi:10.1016/j.rser.2008.08.009.
S.A. Ranganathan, S.L. Narasimhan and K. Muthukumar, Bioresour. Technol., 99, 3975 (2008); doi:10.1016/j.biortech.2007.04.060.
A. Demirbas, Progr. Energy Combust. Sci., 31, 466 (2005); doi:10.1016/j.pecs.2005.09.001.
G.H. Huang, F. Chen, D. Wei, X.W. Zhang and G. Chen, Appl. Energy, 87, 38 (2010); doi:10.1016/j.apenergy.2009.06.016.
I. Dincer, Renew. Sustain. Energy Rev., 4, 157 (2000); doi:10.1016/S1364-0321(99)00011-8.
M. Lapuerta, Progr. Energy Combust., 34, 198 (2008); doi:10.1016/j.pecs.2007.07.001.
A. Demirbas, Energy Convers. Manage., 50, 14 (2009); doi: 10.1016/j.enconman.2008.09.001.
U. Schuchardt, R. Sercheli and R.M. Vargas, J. Braz. Chem. Soc., 9, 199 (1998); doi: 10.1590/S0103-50531998000300002.
H. Fukuda, A. Kondo and H. Noda, J. Biosci. Bioeng., 92, 405 (2001).
A. Demirbas, Energy Convers. Manage., 43, 2349 (2002); doi:10.1016/S0196-8904(01)00170-4.
J.Z. Yin, M. Xiao and J.B. Song, Energy Convers. Manage., 49, 908 (2008); doi:10.1016/j.enconman.2007.10.018.
S. Pleanjai and S.H. Gheewala, Appl. Energy, 86, 209 (2009); doi:10.1016/j.apenergy.2009.05.013.
A.A. Zabaniotou, E.K. Kantarelis and D.C. Theodoropoulos, Bioresour. Technol., 99, 3174 (2008); doi:10.1016/j.biortech.2007.05.060.
G.W. Huber, P. O’Connor and A. Corma, Appl. Catal. A Gen., 329, 120 (2007); doi:10.1016/j.apcata.2007.07.002.
M. Canakci, Bioresour. Technol., 98, 183 (2007); doi:10.1016/j.biortech.2005.11.022.
J. Connemann and J. Fischer, Biodiesel in Europe 1998: biodiesel processing technologies. pp 1-16. Paper presented at the International Liquid Biofuels Congress, Brazil, (1998).
W. Zhou, S.K. Konar and D.G.B. Boocock, J. Am. Oil Chem. Soc., 80, 367 (2003); doi:10.1007/s11746-003-0705-1.
H. Noureddini, X. Gao and R.S. Philkana, Bioresour. Technol., 96, 769 (2005); doi:10.1016/j.biortech.2004.05.029.
F. Ma and M.A. Hanna, Bioresour. Technol., 70, 1 (1999); doi:10.1016/S0960-8524(99)00025-5.
P. Nakpong and S. Wootthikanokkhan, J. Sustain. Energy Environ., 1, 105 (2010).
M. Mathiyazhagan, A. Ganapathi, B. Jaganath, N. Renganayaki and N. Sasireka, Int. J. Chem. Environ. Eng., 2, 119 (2011).
A. Murugesan, C. Umarani, T.R. Chinnusamy, M. Krishnan, R. Subramanian and N. Neduzchezhain, Renew. Sustain. Energy Rev., 13, 825 (2009); doi:10.1016/j.rser.2008.02.003.
Q. Shu, Q. Zhang, G. Xu, Z. Nawaz, D. Wang and J. Wang, Fuel Process. Technol., 90, 1002 (2009); doi:10.1016/j.fuproc.2009.03.007.
S. Saka and D. Kusdiana, Fuel, 80, 225 (2001); doi:10.1016/S0016-2361(00)00083-1.
R.M. Silverstein, F.X. Webster and D.J. Kiemle, Spectrometric Identification of Organic Compounds, 6th Ed. John Wiley and Sons: New York (1998).