Synthesis and Crystal Structure of New Pyridyl Derivative

Xinping Ge; Wei Li; Fuying Hao; Shengli Li; Feng Jin; Hongping Zhou

doi:10.14233/ajchem.2014.17269

Issue

Vol. 26 No. 5 (2014): Vol 26 Issue 5

Issue Published : March 1, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Crystal Structure of New Pyridyl Derivative

https://doi.org/10.14233/ajchem.2014.17269

Xinping Ge

College of Chemistry and Chemical Engineering, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230039, P.R. China

Wei Li

College of Chemistry and Chemical Engineering, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230039, P.R. China

Fuying Hao

College of Chemistry and Chemical Engineering, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230039, P.R. China; Department of Chemistry, Fuyang Normal College, Fuyang 236041, P.R. China

Shengli Li

College of Chemistry and Chemical Engineering, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230039, P.R. China

Feng Jin

Hongping Zhou

College of Chemistry and Chemical Engineering, Key Laboratory of Functional Inorganic Materials Chemistry of Anhui Province, Anhui University, Hefei 230039, P.R. China

Corresponding Author(s) : Feng Jin

zhpzhp@263.net

Asian Journal of Chemistry, Vol. 26 No. 5 (2014): Vol 26 Issue 5
Article Published : March 4, 2014

Abstract

A pyridyl derivative with four stereo centers has been prepared by an efficient synthetic method based on a solvent-free reaction. The structure was characterized by elemental analyses, IR, ¹H NMR, mass spectra and single crystal X-ray diffraction. The crystal structure shows that the cyclohexyl group is a chair conformation and three intramolecular hydrogen bonds generate the trimer.

Keywords

Pyridine Crystal structure Chair conformation Pyridyl derivative Imidazole

Ge, X., Li, W., Hao, F., Li, S., Jin, F., & Zhou, H. (2014). Synthesis and Crystal Structure of New Pyridyl Derivative. Asian Journal of Chemistry, 26(5), 1494–1496. https://doi.org/10.14233/ajchem.2014.17269

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References

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References

H. Lee and J.F. Jordan, J. Am. Chem. Soc., 127, 9384 (2005); doi:10.1021/ja0527673.

T. Sajoto, P.I. Djurovich, A. Tamayo, M. Yousufuddin, R. Bau, M.E. Thompson, R.J. Holmes and S.R. Forrest, J. Inorg. Chem., 44, 7992 (2005); doi:10.1021/ic051296i.

F. Hossain, M.A. Rigsby, C.T. Duncan, P.L. Milligan, R.L. Lord, M. H. Baik and F.A. Schultz, J. Inorg. Chem., 46, 2596 (2007); doi:10.1021/ic062224+.

S. Develay, O. Blackburn, A.L. Thompson and J.A.G. Williams, J. Inorg. Chem., 47, 11129 (2008); doi:10.1021/ic8014157.

H.W. Wang, Y. Chen, W.B. Ye, J.K. Xu, D.F. Liu, J.X. Yang, L. Kong, H.P. Zhou, Y. Tian and X.T. Tao, Dyes Pigments, 96, 738 (2013); doi:10.1016/j.dyepig.2012.11.009.

L. Li, J.X. Yang, Y.P. Tian, P. Liu, B. Jin, X.T. Tao and M.H. Jiang, Transition Met. Chem., 33, 85 (2008); doi:10.1007/s11243-007-9016-0.

Y.H. Gao, J.Y. Wu, Y.M. Li, P.P. Sun, H.P. Zhou, J.X. Yang, S.Y. Zhang, B.K. Jin and Y.P. Tian, J. Am. Chem. Soc., 131, 5208 (2009); doi:10.1021/ja808606d.

Y.H. Gao, W. Zhou, L. Li, J.Y. Wu, H.P. Zhou, J.X. Yang and Y.P. Tian, J. Cryst. Growth Des., 9, 253 (2009); doi:10.1021/cg8004085.

S. Betanzos-Lara, L. Salassa, A. Habtemariam, O. Novakova, A.M. Pizarro, G.J. Clarkson, B. Liskova, V. Brabec and P.J. Sadler, J. Organometallics, 31, 3466 (2012); doi:10.1021/om201177y.

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G.M. Sheldrick, SHELXTL V5.1 Software Reference Manual, Bruker AXS, Inc., Madison, Wisconsin, USA (1997).

W.Q. Geng, H.P. Zhou, L.H. Cheng, F.Y. Hao, G.Y. Xu, F.X. Zhou, Z.P. Yu, Z. Zheng, J.Q. Wang, J.Y. Wu and Y.P. Tian, Polyhedron, 31, 738 (2012); doi:10.1016/j.poly.2011.10.032.

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(a) G.W.V. Cave and C.L. Raston, Chem. Commun., 2199 (2000); doi:10.1039/b007431o.; (b) G.W.V. Cave and C.L. Raston, J. Chem. Soc. Perkin Trans. I, 3258 (2001); doi: 10.1039/B107302H; (c) Z. Zhang, Y.W. Dong, G.W. Wang and K. Komatsu, Synlett, 61 (2004); doi:10.1055/s-2003-43350.

F. Jin, F.X. Zhou, X.F. Yang, L.H. Cheng, Y.Y. Duan, H.P. Zhou, L.Kong, F.Y. Hao, J.Y. Wu and Y.P. Tian, Polyhedron, 43, 1 (2012); doi:10.1016/j.poly.2012.04.001.

Issue

Vol. 26 No. 5 (2014): Vol 26 Issue 5

Synthesis and Crystal Structure of New Pyridyl Derivative

Corresponding Author(s) : Feng Jin

Abstract

Keywords

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