Co-Crystal Compounded by Coordination, Halogen and Hydrogen Bonds and its Self-Protective Phosphorescence

Qun Shao; Yajun Ji

doi:10.14233/ajchem.2014.17266

Issue

Vol. 26 No. 5 (2014): Vol 26 Issue 5

Issue Published : March 1, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Co-Crystal Compounded by Coordination, Halogen and Hydrogen Bonds and its Self-Protective Phosphorescence

https://doi.org/10.14233/ajchem.2014.17266

Qun Shao

School of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei 230601, P.R. China

Yajun Ji

School of Materials and Chemical Engineering, Anhui Jianzhu University, Hefei 230601, P.R. China

Corresponding Author(s) : Qun Shao

qunshao1234567@163.com

Asian Journal of Chemistry, Vol. 26 No. 5 (2014): Vol 26 Issue 5
Article Published : March 4, 2014

Abstract

The cocrystal has been compounded by 5-iodosalicylic acid (5-Isal) and lead ion. Lead ion coordinated with two carboxyl groups of two 5-Isal molecules to form “V-like” structure. Via the interactions of respective two C-I···C halogen bondings (XBs) and C-H···I-C hydrogen bondings (HBs), the “V-like” structure cemented into one dimension (1D) infinite “Zigzag-like” chain structures. The oxygen molecules were prevented from freely diffuse and permeate in cocrystal due to the compact structure, resulting to the generation of non-protective room-temperature phosphorescence. The synergistic cooperation and competition among various weak interactions should be an important factor to assembly supramolecular organic solid materials and understand the generation mechanism of novel property.

Keywords

Supramolecular chemistry Self-assembly 5-Iodosalicylic acid (5-Isal) Self-protective phosphorescence

Shao, Q., & Ji, Y. (2014). Co-Crystal Compounded by Coordination, Halogen and Hydrogen Bonds and its Self-Protective Phosphorescence. Asian Journal of Chemistry, 26(5), 1484–1486. https://doi.org/10.14233/ajchem.2014.17266

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References

G.A. Jeffrey, An Introduction to Hydrogen Bonding, Oxford University Press, Oxford (1997).

O. Ermer and A. Eling, J. Chem. Soc. Perkin Trans., 925 (1994); doi:10.1039/p29940000925.

C.B. Aacheröy and K.R. Seddon, Chem. Soc. Rev., 22, 397 (1993); doi:10.1039/cs9932200397.

J.P. Sauvage, Transition Metals in Supramolecular Chemistry, Wiley, Chichester (1999).

H. Woo, S. Cho, Y. Han, W.-S. Chae, D.-R. Ahn, Y. You and W. Nam, J. Am. Chem. Soc., 135, 4771 (2013); doi:10.1021/ja3123202.

A.C. Legon, Angew. Chem. Int. Ed., 38, 2686 (1999); doi:10.1002/(SICI)1521-3773(19990917)38:18<2686::AID-ANIE2686>3.0.CO;2-6.

P. Metrangolo, H. Neukirch, T. Pilati and G. Resnati, Acc. Chem. Res., 38, 386 (2005); doi:10.1021/ar0400995.

W.S. Zou, J. Han and W.J. Jin, J. Phys. Chem. A, 113, 10125 (2009); doi:10.1021/jp905914q.

F. Zordan, L. Brammer and P. Sherwood, J. Am. Chem. Soc., 127, 5979 (2005); doi:10.1021/ja0435182.

P. Metrangolo and G. Resnati, Chem. Eur. J., 7, 2511 (2001); doi:10.1002/1521-3765(20010618)7:12<2511::AID-CHEM25110>3.0.CO;2-T.

T. Caronna, R. Liantonio, T.A. Logothetis, P. Metrangolo, T. Pilati and G. Resnati, J. Am. Chem. Soc., 126, 4500 (2004); doi:10.1021/ja039884n.

C.B. Aakeröy, M. Fasulo, N. Schultheiss, J. Desper and C. Moore, J. Am. Chem. Soc., 129, 13772 (2007); doi:10.1021/ja073201c.

H.D. Arman, R.L. Gieseking, T.W. Hanks and W.T. Pennington, Chem. Commun., 46, 1854 (2010); doi:10.1039/b925710a.

P. Wu and X.-P. Yan, Chem. Soc. Rev., 42, 5489 (2013); doi:10.1039/c3cs60017c.

W.-S. Zou, J. Yang, T.-T. Yang, X. Hu and H.-Z. Lian, J. Mater. Chem., 22, 4720 (2012); doi:10.1039/c2jm15139a.

I. Sánchez-Barragán, J.M. Costa-Fernández, A. Sanz-Medel, M. Valledor and J.C. Campo, TrAC Trends Anal. Chem., 25, 958 (2006); doi:10.1016/j.trac.2006.07.009.

J.F. Lovell, T.W.B. Liu, J. Chen and G. Zheng, Chem. Rev., 110, 2839 (2010); doi:10.1021/cr900236h.

R. Bonnett, Chem. Soc. Rev., 24, 19 (1995); doi:10.1039/cs9952400019.

A.P. Castano, P. Mroz and M.R. Hamblin, Nat. Rev. Cancer, 6, 535 (2006); doi:10.1038/nrc1894.

W.-S. Zou, D. Sheng, X. Ge, J.-Q. Qiao and H.-Z. Lian, Anal. Chem., 83, 30 (2011); doi:10.1021/ac1008942.

W.-S. Zou, J.-Q. Qiao, X. Hu, X. Ge and H.-Z. Lian, Anal. Chim. Acta, 708, 134 (2011); doi:10.1016/j.aca.2011.09.044.

Y.-Q. Wang and W.-S. Zou, Talanta, 85, 469 (2011); doi:10.1016/j.talanta.2011.04.014.

Y. He, H.-F. Wang and X.-P. Yan, Anal. Chem., 80, 3832 (2008); doi:10.1021/ac800100y.

Q.J. Shen, H.Q. Wei, W.S. Zou, H.L. Sun and W.J. Jin, CrystEngComm, 14, 1010 (2012); doi:10.1039/c1ce06069d.

H.Y. Gao, Q.J. Shen, X.R. Zhao, X.Q. Yan, X. Pang and W.J. Jin, J. Mater. Chem., 22, 5336 (2012); doi:10.1039/c2jm16257a.

H.Y. Gao, X.R. Zhao, H. Wang, X. Pang and W.J. Jin, Cryst. Growth Des., 12, 4377 (2012); doi:10.1021/cg300515a.

Issue

Vol. 26 No. 5 (2014): Vol 26 Issue 5

Co-Crystal Compounded by Coordination, Halogen and Hydrogen Bonds and its Self-Protective Phosphorescence

Corresponding Author(s) : Qun Shao

Abstract

Keywords

Full Article

Download Citation

References

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