Preparation and Fluorescence Behaviour of Violet Waterborne Polyurethane using Disperse Violet 28 as Extender

Xianhai Hu; Jin Liu; Yu Li; Fengmin Cao

doi:10.14233/ajchem.2014.17260

Issue

Vol. 26 No. 5 (2014): Vol 26 Issue 5

Issue Published : March 1, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Preparation and Fluorescence Behaviour of Violet Waterborne Polyurethane using Disperse Violet 28 as Extender

https://doi.org/10.14233/ajchem.2014.17260

Xianhai Hu

School of Materials and Chemical Engineering, Anhui University of Architecture, Hefei 230022, P.R. China

Jin Liu

School of Materials and Chemical Engineering, Anhui University of Architecture, Hefei 230022, P.R. China

Yu Li

School of Materials and Chemical Engineering, Anhui University of Architecture, Hefei 230022, P.R. China

Fengmin Cao

School of Materials and Chemical Engineering, Anhui University of Architecture, Hefei 230022, P.R. China

Corresponding Author(s) : Xianhai Hu

hxyh@ahjzu.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 5 (2014): Vol 26 Issue 5
Article Published : March 4, 2014

Abstract

A polymeric dye, waterborne polyurethane-based disperse violet 28 (WPU-DV28), was prepared by incorporation of disperse violet 28 (DV28) into waterborne polyurethane chains. The structure of waterborne polyurethane-based dye was confirmed by FT-IR and UV-visible spectra. This polymeric dye exhibited intriguing optical behaviour. WPU-DV28 latex engendered a new peaks at 490 nm with contrast to disperse violet 28 in UV-visible spectra. The fluorescence intensity of WPU-DV28 latex was dramatically enhanced with contrast to that of disperse violet 28, which was attributed to hindering the formation of exciplexes in the disperse violet 28 units and augmentation of light absorption area. Furthermore, the fluorescence of WPU-DV28 was not sensitive to hydroquinone quencher.

Keywords

Polymeric dye Waterborne polyurethane Fluorescence enhancement Disperse violet 28

Hu, X., Liu, J., Li, Y., & Cao, F. (2014). Preparation and Fluorescence Behaviour of Violet Waterborne Polyurethane using Disperse Violet 28 as Extender. Asian Journal of Chemistry, 26(5), 1464–1466. https://doi.org/10.14233/ajchem.2014.17260

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References

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References

B.Y. Wang, X.Y. Liu, S.L. Ding and Z.X. Su, J. Polym. Res., 18, 1315 (2011); doi:10.1007/s10965-010-9534-x.

B.K. Jang, S.Y. Kim and J.Y. Do, Dyes Pigments, 94, 217 (2012); doi:10.1016/j.dyepig.2012.01.012.

X.H. Hu, X.Y. Zhang, J.B. Dai and J. Liu, J. Lumin., 131, 2160 (2011); doi:10.1016/j.jlumin.2011.05.026.

X.H. Hu, X.Y. Zhang, J.B. Dai and G.W. Xu, Chin. Chem. Lett., 15, 515 (2004).

S. Yamaguchi and T.M. Swager, J. Am. Chem. Soc., 123, 12087 (2001); doi:10.1021/ja016692o.

CostaFerreiraPrata. A.I. Costa, L.F.V. Ferreira and J.V. Prata, J. Polym. Sci. A; Polym. Chem., 46, 6477 (2008); doi:10.1002/pola.22957.

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H. Xianhai, X. Zhang, J. Liu and J. Dai, J. Lumin., 142, 23 (2013); doi:10.1016/j.jlumin.2013.02.048.

X.H. Hu, X.Y. Zhang and J.B. Dai, Chin. Chem. Lett., 23, 855 (2012); doi:10.1016/j.cclet.2012.05.020.

X.H. Hu, X.Y. Zhang, J. Liu and J.B. Dai, J. Chem., 25, 5503 (2013); doi: 0.14233/ajchem.2013.OH1.

Issue

Vol. 26 No. 5 (2014): Vol 26 Issue 5

Preparation and Fluorescence Behaviour of Violet Waterborne Polyurethane using Disperse Violet 28 as Extender

Corresponding Author(s) : Xianhai Hu

Abstract

Keywords

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