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General Synthesis and Phase Control of Different Copper Molybdate Structures
Corresponding Author(s) : Qifang Ren
Asian Journal of Chemistry,
Vol. 26 No. 5 (2014): Vol 26 Issue 5
Abstract
Different phases and morphologies of copper molybdate have been successfully prepared via a simple hydrothermal process. The pH and reaction tempertaure of the solution have a crucial influence on the synthesis and shapes evolution of the final copper molybdate products. At the same time, surfactants PEG-400 and PEG-20000 have also been used to control the formation of copper molybdate.
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- M.T. Pope, Heteropo1y and Isopoly Oxometalates, Springer, Berlin, 1983.
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- Y. Ding, S.H. Yu, C. Liu and Z.A. Zang, Chem. Eur. J., 13, 746 (2007); doi:10.1002/chem.200601426.
- J.W. Mullin, Crystallization, Butterworth-Heinemaan, Oxford, edn 3 (1997).
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- S.H. Yu, H. Cölfen, J. Hartmann and M. Antonietti, Adv. Funct. Mater., 12, 541 (2002); doi:10.1002/1616-3028(20020805)12:8<541::AID-ADFM541>3.0.CO;2-3.
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References
M.T. Pope, Heteropo1y and Isopoly Oxometalates, Springer, Berlin, 1983.
J.C. Sczancoski, M.D.R. Bomio, L.S. Cavalcante, M.R. Joya, P.S. Pizani, J.A. Varela, E. Longo, M.S. Li and J.A. Andrés, J. Phys. Chem. C, 113, 5812 (2009); doi:10.1021/jp810294q.
J.C. Jung, H. Kim, Y.S. Kim, Y.M. Chung, T.J. Kim, S.J. Lee, S.H. Oh and I.K. Song, Appl. Catal. A, 317, 244 (2007); doi:10.1016/j.apcata.2006.10.021.
Y. Ding, Y. Wan, Y.-L. Min, W. Zhang and S.-H. Yu, Inorg. Chem., 47, 7813 (2008); doi:10.1021/ic8007975.
J.H. Bi, L. Wu, Y.F. Zhang, Z.H. Li, J.Q. Li and X.Z. Fu, Appl. Catal. B, 91, 135 (2009); doi:10.1016/j.apcatb.2009.05.016.
H.E. Swanson, M.C. Morris, R.P. Stinchfield and E.H. Evans, NBS Monogr. (USA), 25, 24 (1963).
X. Cui, S.-H. Yu, L. Li, L. Biao, H. Li, M. Mo and X.-M. Liu, Chem. Eur. J., 10, 218 (2004); doi:10.1002/chem.200305429.
Y. Ding, S.H. Yu, C. Liu and Z.A. Zang, Chem. Eur. J., 13, 746 (2007); doi:10.1002/chem.200601426.
J.W. Mullin, Crystallization, Butterworth-Heinemaan, Oxford, edn 3 (1997).
H. Cölfen and L.M. Qi, Chem. Eur. J., 7, 106 (2001); doi:10.1002/1521-3765(20010105)7:1<106::AID-CHEM106>3.0.CO;2-D.
S.H. Yu, H. Cölfen, J. Hartmann and M. Antonietti, Adv. Funct. Mater., 12, 541 (2002); doi:10.1002/1616-3028(20020805)12:8<541::AID-ADFM541>3.0.CO;2-3.
H. Tlatlik, P. Simon, A. Kawska, D. Zahn and R. Kniep, Angew. Chem. Int. Ed., 45, 1905 (2006); doi:10.1002/anie.200503610.