Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Characterization of Si-Ti-C-O Matrix Using Polycarbosilane for Fiber Reinforced Ceramic Matrix Composites by Blending Technique
Corresponding Author(s) : Kwang Yeon Cho
Asian Journal of Chemistry,
Vol. 26 No. 5 (2014): Vol 26 Issue 5
Abstract
To fabricate Si-Ti-C-O matrix, we introduced titanium to polycarbosilane by simply mixing titanium isopropoxide and polycarbosilane. The mixed solution was cured at 200 ºC and heat treated at 1300 ºC both with inert atmosphere. We successfully synthesized the Si-Ti-C-O matrix. It is confirmed that Si-Ti-C-O matrix has Si-O-Ti connection by FT-IR spectroscope and TiC phase by XRD analysis. For TiC phase, it is expected that Si-Ti-C-O matrix composite has better thermal properties like oxygen resistance and mechanical strength at high temperature.
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- K. Jian, Z.H. Chen, Q.S. Ma and W.W. Zheng, Mater. Sci. Eng. A, 390, 154 (2005); doi:10.1016/j.msea.2004.07.064.
- K. Itatani, T. Tanaka and I.J. Davies, J. Eur. Ceram. Soc., 26, 703 (2006); doi:10.1016/j.jeurceramsoc.2005.07.008.
- H.A. Liu and K.J. Balkus Jr., Mater. Lett., 63, 2361 (2009); doi:10.1016/j.matlet.2009.08.009.
- Y. Xu, L. Zhang, L. Cheng and D. Yan, Carbon, 36, 1051 (1998); doi:10.1016/S0008-6223(98)00076-1.
- J.C. Bae, K.Y. Cho, D.H. Yoon, S.S. Baek, J.K. Park, J.I. Kim, D.W. Im and D.H. Riu, Ceram. Int., 39, 5623 (2013); doi:10.1016/j.ceramint.2012.12.078.
- A.R. Bunsell and A. Piant, J. Mater. Sci., 41, 823 (2006); doi:10.1007/s10853-006-6566-z.
- P.H. Kang, J.P. Jeun, D.K. Seo and Y.C. Nho, Radiat. Phys. Chem., 78, 493 (2009); doi:10.1016/j.radphyschem.2009.03.033.
- K. Jian, Z.H. Chen, Q.S. Ma and W.W. Zheng, Mater. Sci. Eng. A, 390, 154 (2005); doi:10.1016/j.msea.2004.07.064.
- Z. Li, H. Li, S. Zhang and K. Li, Ceram. Int., 38, 3419 (2012); doi:10.1016/j.ceramint.2011.12.054.
- T. Ogasawara, T. Ishikawa, H. Ito, N. Watanabe and I.J. Davies, J. Am. Ceram. Soc., 84, 1565 (2001); doi:10.1111/j.1151-2916.2001.tb00878.x.
- G.A. Pribytkov, Y.V. Svitich, I.V. Polev, M.I. Vagner and S.S. Borisov, Refr. Ind. Ceram., 39, 179 (1998); doi:10.1007/BF02764269.
- V.A. Zeitler and C.A. Brown, J. Phys. Chem., 61, 1174 (1957); doi:10.1021/j150555a010.
- J.F. Shackelford and W. Alexander, CRC Materials Science and Engineering Handbook, Lewis Publishers, pp. 50, 279, 508 (2000).
References
K. Jian, Z.H. Chen, Q.S. Ma and W.W. Zheng, Mater. Sci. Eng. A, 390, 154 (2005); doi:10.1016/j.msea.2004.07.064.
K. Itatani, T. Tanaka and I.J. Davies, J. Eur. Ceram. Soc., 26, 703 (2006); doi:10.1016/j.jeurceramsoc.2005.07.008.
H.A. Liu and K.J. Balkus Jr., Mater. Lett., 63, 2361 (2009); doi:10.1016/j.matlet.2009.08.009.
Y. Xu, L. Zhang, L. Cheng and D. Yan, Carbon, 36, 1051 (1998); doi:10.1016/S0008-6223(98)00076-1.
J.C. Bae, K.Y. Cho, D.H. Yoon, S.S. Baek, J.K. Park, J.I. Kim, D.W. Im and D.H. Riu, Ceram. Int., 39, 5623 (2013); doi:10.1016/j.ceramint.2012.12.078.
A.R. Bunsell and A. Piant, J. Mater. Sci., 41, 823 (2006); doi:10.1007/s10853-006-6566-z.
P.H. Kang, J.P. Jeun, D.K. Seo and Y.C. Nho, Radiat. Phys. Chem., 78, 493 (2009); doi:10.1016/j.radphyschem.2009.03.033.
K. Jian, Z.H. Chen, Q.S. Ma and W.W. Zheng, Mater. Sci. Eng. A, 390, 154 (2005); doi:10.1016/j.msea.2004.07.064.
Z. Li, H. Li, S. Zhang and K. Li, Ceram. Int., 38, 3419 (2012); doi:10.1016/j.ceramint.2011.12.054.
T. Ogasawara, T. Ishikawa, H. Ito, N. Watanabe and I.J. Davies, J. Am. Ceram. Soc., 84, 1565 (2001); doi:10.1111/j.1151-2916.2001.tb00878.x.
G.A. Pribytkov, Y.V. Svitich, I.V. Polev, M.I. Vagner and S.S. Borisov, Refr. Ind. Ceram., 39, 179 (1998); doi:10.1007/BF02764269.
V.A. Zeitler and C.A. Brown, J. Phys. Chem., 61, 1174 (1957); doi:10.1021/j150555a010.
J.F. Shackelford and W. Alexander, CRC Materials Science and Engineering Handbook, Lewis Publishers, pp. 50, 279, 508 (2000).