Cyclic Microwave-Assisted Metathetic Synthesis of SPION/Ca3V2O8:Er3+,Yb3+ Nanocomposites and Their Optical Properties

Chang Sung Lim

doi:10.14233/ajchem.2014.16520

Issue

Vol. 26 No. 6 (2014): Vol 26 Issue 6

Issue Published : March 10, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Cyclic Microwave-Assisted Metathetic Synthesis of SPION/Ca3V2O8:Er3+,Yb3+ Nanocomposites and Their Optical Properties

https://doi.org/10.14233/ajchem.2014.16520

Chang Sung Lim

Department of Advanced Materials Science & Engineering, Hanseo University, Seosan 356-706, Republic of Korea

Corresponding Author(s) : Chang Sung Lim

cslim@hanseo.ac.kr

Asian Journal of Chemistry, Vol. 26 No. 6 (2014): Vol 26 Issue 6
Article Published : March 13, 2014

Abstract

Er³⁺/Yb³⁺ co-doped Ca₃V₂O₈ (Ca₃V₂O₈:Er³⁺/Yb³⁺) nanocomposites with superparamagnetic iron oxide nanoparticles (SPIONs) have been successfully synthesized by a cyclic microwave-assisted metathetic method followed by heat-treatment. The microstructure exhibited well-defined and homogeneous morphology with the Ca₃V₂O₈:Er³⁺/Yb³⁺ particle size of 1-2 μm and Fe₃O₄ particle size of 100-500 nm. The Fe₃O₄ nonoparticles were self-preferentially crystallized and immobilized on the surface of Ca₃V₂O₈:Er³⁺/Yb³⁺ particles. The synthesized SPION/Ca₃V₂O₈:Er³⁺/Yb³⁺ nanocomposites were characterized by X-ray diffraction, scanning electron microscopy and energy-dispersive X-ray spectroscopy. Other optical properties were also examined using photoluminescence emission measurements and Raman spectroscopy.

Keywords

Cyclic microwave-assisted metathetic synthesis Optical properties SPION/Ca3V2O8:Er3 /Yb3 Nanocomposites

Sung Lim, C. (2014). Cyclic Microwave-Assisted Metathetic Synthesis of SPION/Ca3V2O8:Er3+,Yb3+ Nanocomposites and Their Optical Properties. Asian Journal of Chemistry, 26(6), 1869–1872. https://doi.org/10.14233/ajchem.2014.16520

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D. Liu, L. Tong, J. Shi and H. Yang, J. Alloy. Comp., 512, 361 (2012); doi:10.1016/j.jallcom.2011.09.100.

L. Liu, L. Xiao and H.Y. Zhu, Chem. Phys. Lett., 539-540, 112 (2012); doi:10.1016/j.cplett.2012.04.063.

Q. Wang, X. Yang, L. Yu and H. Yang, J. Alloy. Comp., 509, 9098 (2011); doi:10.1016/j.jallcom.2011.06.058.

D. Wang, Z. Zou and J. Ye, Res. Chem. Intermed., 31, 433 (2005); doi:10.1163/1568567053956635.

M. Kurzawa and A. Blonska-Tabero, J. Therm. Anal. Calorim., 77, 17 (2004); doi:10.1023/B:JTAN.0000033183.50187.d5.

P. Parhi and V. Manivannan, Mater. Res. Bull., 43, 2966 (2008); doi:10.1016/j.materresbull.2007.12.003.

S.S. Kim, H. Ikuta and M. Wakihara, Solid State Ion., 139, 57 (2001); doi:10.1016/S0167-2738(00)00816-X.

P. Parhi, V. Manivannan, S. Kohli and P. Mccurdy, Bull. Mater. Sci., 31, 885 (2008); doi:10.1007/s12034-008-0141-y.

V. Manivannan, P. Parhi and J. Howard, J. Cryst. Growth, 310, 2793 (2008); doi:10.1016/j.jcrysgro.2008.02.021.

R. Szymczak, M. Baran, J. Fink-Finowicki, B. Krzymanska, P. Aleshkevych, H. Szymczak, S.N. Barilo, G.L. Bychkov and S.V. Shiryaev, J. Non-Cryst. Solids, 354, 4186 (2008); doi:10.1016/j.jnoncrysol.2008.06.082.

T. Thongtem, A. Phuruangrat and S. Thongtem, J. Nanopart. Res., 12, 2287 (2010); doi:10.1007/s11051-009-9797-5.

C.S. Lim, Mater. Res. Bull., 47, 4220 (2012); doi:10.1016/j.materresbull.2012.09.029.

C.S. Lim, Asian J. Chem., 25, 63 (2013); doi:10.14233/ajchem.2013.12636A.

S. Das, A.K. Mukhopadhyay, S. Datta and D. Basu, Bull. Mater. Sci., 32, 1 (2009); doi:10.1007/s12034-009-0001-4.

C.S. Lim, J. Lumin., 132, 1774 (2012); doi:10.1016/j.jlumin.2012.02.024.

C.S. Lim, Mater. Chem. Phys., 131, 714 (2012); doi:10.1016/j.matchemphys.2011.10.039.

Y. Toyozawa and M. Inoue, J. Phys. Soc. Jpn., 21, 1663 (1966); doi:10.1143/JPSJ.21.1663.

E.G. Reut, Izv. Akad. Nauk SSSR, Ser. Fiz., 43, 1186 (1979).

Y. Zhang, N.A.W. Holzwarth and R.T. Williams, Phys. Rev. B, 57, 12738 (1998); doi:10.1103/PhysRevB.57.12738.

J. Van Tol, Mol. Phys., 88, 803 (1996); doi:10.1080/00268979650026316.

V.B. Mikhailik, H. Kraus, D. Wahl and M.S. Mykhaylyk, Phys. Status Solid B, 242, R17 (2005); doi:10.1002/pssb.200409087.

T.T. Basiev, A.A. Sobol, Y.K. Voronko and P.G. Zverev, Opt. Mater., 15, 205 (2000); doi:10.1016/S0925-3467(00)00037-9.

T.T. Basiev, A.A. Sobol, P.G. Zverev, L.I. Ivleva, V.V. Osiko and R.C. Powell, Opt. Mater., 11, 307 (1999); doi:10.1016/S0925-3467(98)00030-5.

Issue

Vol. 26 No. 6 (2014): Vol 26 Issue 6

Cyclic Microwave-Assisted Metathetic Synthesis of SPION/Ca3V2O8:Er3+,Yb3+ Nanocomposites and Their Optical Properties

Corresponding Author(s) : Chang Sung Lim

Abstract

Keywords

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