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Vol. 31 No. 11 (2019): Vol 31 Issue 11

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Fresh Neem Leaves (Azadirachta indica A. Juss) Extraction and Application: An Optimization using Response Surface Methodology

https://doi.org/10.14233/ajchem.2019.22207
E. Rahayuningsih
Department of Chemical Engineering, Universitas Gadjah Mada, Jalan Grafika No. 2 Kampus UGM, Yogyakarta 55281, Indonesia
I.S. Subagya
Department of Chemical Engineering, Universitas Gadjah Mada, Jalan Grafika No. 2 Kampus UGM, Yogyakarta 55281, Indonesia
F.A. Setiawan
Department of Chemical Engineering, Universitas Jember, Jalan Kalimantan No. 37 Kampus Tegalboto, East Java 68121, Indonesia
https://orcid.org/0000-0002-7379-3713
H.T.B.M. Petrus
Department of Chemical Engineering, Universitas Gadjah Mada, Jalan Grafika No. 2 Kampus UGM, Yogyakarta 55281, Indonesia

Corresponding Author(s) : E. Rahayuningsih

edia_rahayu@ugm.ac.id

Asian Journal of Chemistry, Vol. 31 No. 11 (2019): Vol 31 Issue 11

Abstract

Fresh neem leaves (Azadirachta indica A. Juss) consist of quercetin (flavonoid) compound, responsible for yellow colour as a natural dye. The study investigated the variable optimization in fresh neem leaf extraction process and its application. The optimization was conducted using response surface methodology (RSM) and ANOVA test. The coefficients of determination (R2) were generalized at 96.46 and 96.39 % for optimizing extraction process and application process parameter of natural dyes from neem leaves, respectively. The optimum variables for the extraction process were obtained at 50 % w/v feed-solvent ratio, the temperature of 80 ºC and extraction duration of 80 min with the response concentration of 46.19 g/L. Furthermore, the optimum variable on the application of natural dyes from neem leaves was recorded when alum was applied as fixator as much as 14.09 g/L and Turkish red oil (TRO) as mordant at 11.16 g/L resulted the response of 0 % on the degree of faded.

Keywords

Neem leaves Quercetin Natural dyes Response surface methodology
Rahayuningsih, E., Subagya, I., Setiawan, F., & Petrus, H. (2019). Fresh Neem Leaves (Azadirachta indica A. Juss) Extraction and Application: An Optimization using Response Surface Methodology. Asian Journal of Chemistry, 31(11), 2567–2574. https://doi.org/10.14233/ajchem.2019.22207
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References
  1. C.J. Ogugbue and T. Sawidis, Biotechnol. Res. Int., 2011, Article ID 967925 (2011); https://doi.org/10.4061/2011/967925.
  2. T. Robinson, G. McMullan, R. Marchant and P. Nigam, Bioresour. Technol., 77, 247 (2001); https://doi.org/10.1016/S0960-8524(00)00080-8.
  3. H. Zollinger, Properties of Organic Dyes and Pigments in Color Chemistry, VCH Publishers: New York (1978).
  4. K. El-Nagar, S.H. Sanad, A.S. Mohamed and A. Ramadan, Polym. Plast. Technol. Eng., 44, 1269 (2005); https://doi.org/10.1080/03602550500207816.
  5. M.J. Iqbal and M.N. Ashiq, J. Hazard. Mater., 139, 57 (2007); https://doi.org/10.1016/j.jhazmat.2006.06.007.
  6. M. Parvinzadeh Gashti, B. Katozian, M. Shaver and A. Kiumarsi, Color. Technol., 130, 54 (2014); https://doi.org/10.1111/cote.12065.
  7. A. Kiumarsi, M. Parvinzadeh Gashti, P. Salehi and M. Dayeni, J. Textil. Inst., 108, 66 (2017); https://doi.org/10.1080/00405000.2016.1153865.
  8. M. Alam, M. Rahman and M. Haque, Bangladesh J. Sci. Ind. Res., 42, 217 (1970); https://doi.org/10.3329/bjsir.v42i2.475.
  9. T. Bechtold, A.M. Ali, E. Ganglberger and S. Geissler, Int. J. Environ. Waste Manag., 2, 215 (2008); https://doi.org/10.1504/IJEWM.2008.018244.
  10. B. Chengaiah, K.M. Rao, K.M. Kumar, M. Alagusundaram and C.M. Chetty, Int. J. Pharm. Technol. Res., 2, 144 (2010).
  11. F. Giacomini, M.A.B. Menegazzo, J.C.O. dos Santos, P.A. Arroyo and M.A.S.D. de Barros, Text. Res. J., 87, 829 (2017); https://doi.org/10.1177/0040517516641357.
  12. M. Shahid, Shahid-ul-Islam and F. Mohammad, J. Clean. Prod., 53, 310 (2013); https://doi.org/10.1016/j.jclepro.2013.03.031.
  13. Shahid-ul-Islam, M. Shahid and F. Mohammad, J. Clean. Prod., 57, 2 (2013); https://doi.org/10.1016/j.jclepro.2013.06.004.
  14. B. Patel, Natural Dyes, In: Handbook of Textile and Industrial Dyeing, Elsevier, pp 395-424 (2011).
  15. H. Schweppe, Handbuch der Naturfarbstoffe: Vorkommen, Verwendung, Nachweis: Germany (1992).
  16. E. Dedhia, Colourage, 45, 45 (1998).
  17. H. Bukhari, M. Heba and Q. Khadijah, Int. J. Technol. Res. Appl., 2, 2320 (2014).
  18. S. Adeel, K.M. Zia, M. Abdullah and F. Rehman, M. Salman and M. Zuber, Nat. Prod. Res., 33, 2060 (2019); https://doi.org/10.1080/14786419.2018.1484466.
  19. N. Baaka, A. Mahfoudhi, W. Haddar, M.F. Mhenni and Z. Mighri, Nat. Prod. Res., 31, 22 (2017); https://doi.org/10.1080/14786419.2016.1207072.
  20. M.M. Hasan, K.A. Nayem, A.Y.M. Anwarul Azim and N.C. Ghosh, J. Text. 2015, Article ID 932627 (2015); https://doi.org/10.1155/2015/932627.
  21. M.A. Bezerra, R.E. Santelli, E.P. Oliveira, L.S. Villar and L.A. Escaleira, Talanta, 76, 965 (2008); https://doi.org/10.1016/j.talanta.2008.05.019.
  22. L. Mohajeri, H.A. Aziz, M.H. Isa and M.A. Zahed, Bioresour. Technol., 101, 893 (2010); https://doi.org/10.1016/j.biortech.2009.09.013.
  23. D.C. Montgomery, Design and Analysis of Experiments, John Wiley & Sons (2017).
  24. E. Rahayuningsih, M.S. Pamungkas, M. Olvianas and A.D.P. Putera, J. Food Sci. Technol., 55, 1028 (2018); https://doi.org/10.1007/s13197-017-3016-7.
  25. R. Mansour, B. Ezzili and M. Farouk, J. Text. Inst., 108, 528 (2017); https://doi.org/10.1080/00405000.2016.1172821.
  26. K. Sinha, S. Chowdhury, P.D. Saha and S. Datta, Ind. Crops Prod.,, 41, 165 (2013); https://doi.org/10.1016/j.indcrop.2012.04.004.
  27. N. Vedaraman, K. Sandhya, N. Charukesh, B. Venkatakrishnan, K. Haribabu, M. Sridharan and R. Nagarajan, Process Intensif., 114, 46 (2017); https://doi.org/10.1016/j.cep.2017.01.008.
  28. S.E. Agarry and O.O. Ogunleye, J. Environ. Prot., 3, 748 (2012); https://doi.org/10.4236/jep.2012.38089.
  29. J.P. Maran and S. Manikandan, Dyes and Pigment, 95, 465 (2012); https://doi.org/10.1016/j.dyepig.2012.06.007.
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