Synthesis and Structural Characterization of Diiron Dithiolate Complex [(&mu;-SCH2)2NCH2PhFe2(CO)5]2(Ph2PCH2CH2CH2PPh2) with Bridging Diphosphine Ligand

Wei Gao; Lian-Qi Tian; Jing Yang

doi:10.14233/ajchem.2014.16183A

Issue

Vol. 26 No. 7 (2014): Vol 26 Issue 7

Issue Published : March 22, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Structural Characterization of Diiron Dithiolate Complex [(μ-SCH2)2NCH2PhFe2(CO)5]2(Ph2PCH2CH2CH2PPh2) with Bridging Diphosphine Ligand

https://doi.org/10.14233/ajchem.2014.16183A

Wei Gao

School of Pharmacy, Henan University of Traditional Chinese Medicine, Zhengzhou 450046, P.R. China

Lian-Qi Tian

School of Pharmacy, Henan University of Traditional Chinese Medicine, Zhengzhou 450046, P.R. China

Jing Yang

School of Pharmacy, Henan University of Traditional Chinese Medicine, Zhengzhou 450046, P.R. China

Corresponding Author(s) : Jing Yang

weigao415@aliyun.com

Asian Journal of Chemistry, Vol. 26 No. 7 (2014): Vol 26 Issue 7
Article Published : March 31, 2014

Abstract

A novel diiron dithiolate complex [(μ-SCH₂)₂NCH₂PhFe₂(CO)₅]₂(Ph₂PCH₂CH₂CH₂PPh₂) (1), as the active site model of [FeFe]-hydrogenases, has been prepared and structurally characterized. The title complex could be prepared by reaction of [(μ-SCH₂)₂NCH₂Ph]Fe₂(CO)₆ (A) with 1,3-bis(diphenylphosphinopropane) (DPPP) (Ph₂PCH₂CH₂CH₂PPh₂) in the presence of Me₃NO·2H₂O in MeCN at room temperature in 54 % yield. The new complex 1 was characterized by IR, ¹H NMR and ³¹P NMR spectroscopy.

Keywords

Diiron dithiolate Synthesis Characterization. Characterization 1,3-bis(diphenylphosphino)propane

Gao, W., Tian, L.-Q., & Yang, J. (2014). Synthesis and Structural Characterization of Diiron Dithiolate Complex [(μ-SCH2)2NCH2PhFe2(CO)5]2(Ph2PCH2CH2CH2PPh2) with Bridging Diphosphine Ligand. Asian Journal of Chemistry, 26(7), 2086–2088. https://doi.org/10.14233/ajchem.2014.16183A

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References

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References

(a) P.-H. Zhao, Y.-Q. Liu and G.-Z. Zhao, Polyhedron, 53, 144 (2013); doi:10.1016/j.poly.2013.01.048; (b) C.A. Mebi, D.S. Karr and B.C. Noll, Polyhedron, 50, 164 (2013); doi:10.1016/j.poly.2012.11.001; (c) P.H. Zhao, Y.Q. Liu and X.A. Li, Asian J. Chem., 25, 5428 (2013); doi:10.14233/ajchem.2013.14537; (d) X.F. Liu, Z.Q. Jiang and Z.J. Jia, Polyhedron, 33, 166 (2012); doi:10.1016/j.poly.2011.11.032.

(a) J.W. Peters, W.N. Lanzilotta, B.J. Lemon and L.C. Seefeldt, Science, 282, 1853 (1998); doi:10.1126/science.282.5395.1853; (b) Y. Nicolet, C. Piras, P. Legrand, C.E. Hatchikian and J.C. Fontecilla-Camps, Structure, 7, 13 (1999); doi:10.1016/S0969-2126(99)80005-7.

(a) X.F. Liu and B.S. Yin, J. Coord. Chem., 63, 4061 (2010); doi:10.1080/00958972.2010.531715.; (b) X.F. Liu, X.W. Xiao and L.J. Shen, J. Coord. Chem., 64, 1023 (2011); doi:10.1080/00958972.2011.561838.; (c) X.F. Liu, X.W. Xiao, L.J. Shen, J.H. Fang, J.R. Wang, H.Q. Gao and X.H. Liu, Chinese J. Struct. Chem., 30, 1016 (2011); (d) B.S. Yin, T.B. Li and M.S. Yang, J. Coord. Chem., 64, 2066 (2011); doi:10.1080/00958972.2011.588330.

(a) X.F. Liu and B.S. Yin, Z. Anorg. Allg. Chem., 637, 377 (2011); doi:10.1002/zaac.201000412; (b) X.F. Liu, X.W. Xiao and L.J. Shen, Transition Met. Chem., 36, 465 (2011); doi:10.1007/s11243-011-9491-1; (c) X.F. Liu and X.W. Xiao, J. Organomet. Chem., 696, 2767 (2011); doi:10.1016/j.jorganchem.2011.05.007.

(a) X.F. Liu, Inorg. Chim. Acta, 378, 338 (2011); doi:10.1016/j.ica.2011.09.012; (b) X.F. Liu, X.W. Xiao and X.H. Liu, Chinese J. Struct. Chem., 30, 1437 (2011); (c) X.F. Liu and X.Y. Yu, Acta Crystallogr., E67, m1552 (2011); (d) B.S. Yin, T.B. Li and M.S. Yang, Acta Crystallogr., E67, m1502 (2011); (e) X.F. Liu and H.Q. Gao, J. Clust. Sci., 25, 367 (2014); doi:10.1007/s10876-013-0615-y.

(a) X.H. Liu, C.X. Tan and J.Q. Weng, Asian J. Chem., 23, 4064 (2011); (b) X.H. Liu, J.Q. Weng, C.X. Tan, L. Pan, B.L. Wang and Z.M. Li, Asian J. Chem., 23, 4031 (2011); (c) Y.L. Xue, Y.G. Zhang and X.H. Liu, Asian J. Chem., 24, 3016 (2012); (d) P.Q. Chen, C.X. Tan, J.Q. Weng and X.H. Liu, Asian J. Chem., 24, 2808 (2012); (e) Y.L. Xue, Y.G. Zhang and X.H. Liu, Asian J. Chem., 24, 1571 (2012); (f) Y.L. Xue, Y.G. Zhang and X.H. Liu, Asian J. Chem., 24, 5087 (2012); (g) X.F. Liu and X.H. Liu, Acta Crystallogr. Sect. E Struct. Rep. Online, 67, o202 (2011); doi:10.1107/S1600536810052116.; (h) L.J. Luo, X.F. Liu and H.Q. Gao, J. Coord. Chem., 66, 1077 (2013); doi:10.1080/00958972.2013.775431.

H. Li and T.B. Rauchfuss, J. Am. Chem. Soc., 124, 726 (2002); doi:10.1021/ja016964n.

Issue

Vol. 26 No. 7 (2014): Vol 26 Issue 7

Synthesis and Structural Characterization of Diiron Dithiolate Complex [(μ-SCH2)2NCH2PhFe2(CO)5]2(Ph2PCH2CH2CH2PPh2) with Bridging Diphosphine Ligand

Corresponding Author(s) : Jing Yang

Abstract

Keywords

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