Synthesis and Characterization of Some New Metallo-Organic Derivatives of Germanium(IV)

Blassan Samuel; Kiran Tummalapalli; Prasanth Vuppalapati Giri; Arun An; Madhvesh Pathak

doi:10.14233/ajchem.2014.15625

Issue

Vol. 26 No. 7 (2014): Vol 26 Issue 7

Issue Published : March 22, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of Some New Metallo-Organic Derivatives of Germanium(IV)

https://doi.org/10.14233/ajchem.2014.15625

Blassan Samuel

Materials Chemistry Division, School of Advanced Sciences, VIT University, Vellore-632 014, India

Kiran Tummalapalli

Materials Chemistry Division, School of Advanced Sciences, VIT University, Vellore-632 014, India

Prasanth Vuppalapati Giri

Materials Chemistry Division, School of Advanced Sciences, VIT University, Vellore-632 014, India

Arun An

Materials Chemistry Division, School of Advanced Sciences, VIT University, Vellore-632 014, India

Madhvesh Pathak

Materials Chemistry Division, School of Advanced Sciences, VIT University, Vellore-632 014, India

Corresponding Author(s) : Madhvesh Pathak

madhveshpathak@vit.ac.in

Asian Journal of Chemistry, Vol. 26 No. 7 (2014): Vol 26 Issue 7
Article Published : March 31, 2014

Abstract

Compounds of the type GeG_n(OR)_4-2n [where G = O(CH₂)₂S(CH₂)O, S(CH₂)₂O(CH₂)₂S, S(CH₂)₂S(CH₂)₂S; R = Et, Prⁱ and n = 1, 2] have been prepared by the reaction of Ge(OR)₄ with 2-hydroxyethyl sulfide, 2-mercaptoethyl ether and 2-mercaptoethyl sulfide in 1:1 and 1:2 molar ratios in refluxing anhydrous benzene. All these complexes are white sticky solid in appearance. After purification and spectral analyses (IR and ¹H and ¹³C NMR) tetra coordination geometry is proposed around germanium atom.

Keywords

Metallo-organic compounds Germanium alkoxides Bifunctional tridentate ligands

Samuel, B., Tummalapalli, K., Vuppalapati Giri, P., An, A., & Pathak, M. (2014). Synthesis and Characterization of Some New Metallo-Organic Derivatives of Germanium(IV). Asian Journal of Chemistry, 26(7), 2019–2021. https://doi.org/10.14233/ajchem.2014.15625

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References

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M. Pathak, R. Bohra, R.C. Mehrotra, I.-P. Lorenz and H. Piotrowski, J. Chem. Res., 377 (2004); doi:10.3184/0308234041423808.
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Ya. Lepikh and V.A. Smyntyna, Tech. Phys. Lett., 26, 168 (2000); doi:10.1134/1.1262780.
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H. Darwish, S.N. Salama and S.M. Salman, Thermochim. Acta, 374, 129 (2001); doi:10.1016/S0040-6031(01)00481-6.
C.P. Avanzato, J.M. Follieri, I.A. Banerjee and K.R. Fath, J. Compos. Mater., 43, 897 (2009); doi:10.1177/0021998308103158.
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M. Pathak, R. Bohra and R.C. Mehrotra, J. Chem. Res., 567 (2003); doi:10.3184/030823403322597333.
A.Y. Shah, A. Wadawale, B.S. Naidu, V. Sudarsan, R.K. Vatsa, V.K. Jain, V. Dhayal, M. Nagar and R. Bohra, Inorg. Chim. Acta, 363, 3680 (2010); doi:10.1016/j.ica.2010.05.018.
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D.L. Tabern, W.R. Orndorff and L.M. Dennis, J. Am. Chem. Soc., 47, 2039 (1925); doi:10.1021/ja01684a038.
A.I. Vogel, A Text Book of Quantitative Inorganic Analysis, London, edn 5 (1989).
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J.E. Drake, A.G. Mislankar and M.L.Y. Wong, Inorg. Chem., 30, 2174 (1991); doi:10.1021/ic00009a041.

References

D.C. Bradley, R.C. Mehrotra, I.P. Rothwell and A. Singh, Alkoxo and Aryloxo Derivatives of Metals, Academic Press, San-Diego, USA (2001).

M. Pathak, R. Bohra, R.C. Mehrotra, I.-P. Lorenz and H. Piotrowski, J. Chem. Res., 377 (2004); doi:10.3184/0308234041423808.

Y.Z. Fang, C. Lu, J.H. Zhou and W.Y. Ma, Chin. Chem. Lett., 19, 493 (2008); doi:10.1016/j.cclet.2008.01.036.

Ya. Lepikh and V.A. Smyntyna, Tech. Phys. Lett., 26, 168 (2000); doi:10.1134/1.1262780.

D.C. Bradley and J.M. Thomas, Philos. Trans. R. Soc. Lond. A, 330, 167 (1990); doi:10.1098/rsta.1990.0010.

M. Ardyanian, H. Rinnert and M. Vergnat, J. Lumin., 129, 729 (2009); doi:10.1016/j.jlumin.2009.02.013.

X.C. Wu, W.H. Song, B. Zhao, Y.P. Sun and J.J. Du, Chem. Phys. Lett., 349, 210 (2001); doi:10.1016/S0009-2614(01)01213-1.

H. Darwish, S.N. Salama and S.M. Salman, Thermochim. Acta, 374, 129 (2001); doi:10.1016/S0040-6031(01)00481-6.

C.P. Avanzato, J.M. Follieri, I.A. Banerjee and K.R. Fath, J. Compos. Mater., 43, 897 (2009); doi:10.1177/0021998308103158.

Z. Fu, Y. Tan, J. Zhang, S. Liao, D. Su, H. Chen, Y. Yu and J. Peng, Inorg. Chem. Commun., 15, 221 (2012); doi:10.1016/j.inoche.2011.10.031.

M. Pathak, R. Bohra and R.C. Mehrotra, J. Chem. Res., 567 (2003); doi:10.3184/030823403322597333.

A.Y. Shah, A. Wadawale, B.S. Naidu, V. Sudarsan, R.K. Vatsa, V.K. Jain, V. Dhayal, M. Nagar and R. Bohra, Inorg. Chim. Acta, 363, 3680 (2010); doi:10.1016/j.ica.2010.05.018.

D.H. Chen, H.C. Chiang and C.H. Ueng, Inorg. Chim. Acta, 208, 99 (1993); doi:10.1016/S0020-1693(00)82890-X.

N.V. Alekseev and E.V. Chernyshev, J. Struct. Chem., 51, 419 (2010); doi:10.1007/s10947-010-0063-6.

D.L. Tabern, W.R. Orndorff and L.M. Dennis, J. Am. Chem. Soc., 47, 2039 (1925); doi:10.1021/ja01684a038.

A.I. Vogel, A Text Book of Quantitative Inorganic Analysis, London, edn 5 (1989).

D.C. Bradley, F.M. Abd-El Halim and W. Wardlaw, J. Chem. Soc., 3450 (1950); doi:10.1039/jr9500003450.

J.E. Drake, A.G. Mislankar and M.L.Y. Wong, Inorg. Chem., 30, 2174 (1991); doi:10.1021/ic00009a041.

Issue

Vol. 26 No. 7 (2014): Vol 26 Issue 7

Synthesis and Characterization of Some New Metallo-Organic Derivatives of Germanium(IV)

Corresponding Author(s) : Madhvesh Pathak

Abstract

Keywords

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