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Effect of Almudinah Almonawarah Soil Solution on the Corrosion of Steel in Acidic Media
Corresponding Author(s) : Aisha M. Al-Turkustani
Asian Journal of Chemistry,
Vol. 26 No. 8 (2014): Vol 26 Issue 8
Abstract
The effect of Almadinah Almonawarah soil solution on the corrosion of steel in 2 M H2SO4 was studied using chemical (gravimetric and gasometric) techniques at 30 and 60° C and electrochemical (impedance and polarization) techniques at 30 ° C. The results revealed that the studied soil solution inhibits the corrosion of steel in acid media and the inhibition efficiency increase with increasing concentration of soil solution but decrease with rising temperature. Polarization showed that Almadinah Almonawarah soil solution acts as mixed type inhibitor. The experimental data were corroborated with the Freundlish as well as Langmuir adsorption isotherms. The values of activation energy suggest that the inhibition process is activation controlled.
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- G. Wranglen, An Introduction to Corrosion and Protection of Metals, Chapman and Hall, New York, London (1985).
- www. Corrosion-doctors.org/SoilCorrosion/Introduction.htm.
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- A.Y. El-Etre, Corros. Sci., 45, 2485 (2003); doi:10.1016/S0010-938X(03)00066-0.
- M. Behpour, S.M. Ghoreishi, M. Khayatkashani and N. Soltani, Mater. Chem. Phys., 131, 621 (2012); doi:10.1016/j.matchemphys.2011.10.027.
- K.O. Orubite and N.C. Oforka, Mater. Lett., 58, 1768 (2004); doi:10.1016/j.matlet.2003.11.030.
- S.T. Arab, A.M. Al-Turkustani and S.Y. Al-Nami, Mater. Sci. Res. Ind., 3, 99 (2005).
- A.M. Abdel-Gaber, B.A. Abd-El-Nabey, I.M. Sidahmed, A.M. El-Zayady and M. Saadawy, Corros. Sci., 48, 2765 (2006); doi:10.1016/j.corsci.2005.09.017.
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- F. Kiby, Hist. Soc., 121 (1990).
- S. Muralidharan, M. Quraishi and S. Iyer, Corros. Sci., 37, 1739 (1995); doi:10.1016/0010-938X(95)00068-U.
- S. Muralidharan, B. Ramesh Babu, S. Venkatakrishna Iyer and S. Rengamani, J. Appl. Electrochem., 26, 291 (1996); doi:10.1007/BF00242098.
- A. Fouda and M. El-Semongym, J. Indian Chem. Soc., 59, 89 (1982).
- E. Hopson and K. Tales, Iron Fever, The Iron Industry Permeates Kent. Kent, Ct: The Kent Historical Society (1990).
- E.E. Ebenso, Bull. Electrochem., 19, 209 (2003).
- I. Farooqi, M. Quraishi and P. Saini, Eurocorr., 97, 347 (1997).
- N. Subramaniah and K. Ramakrishnaia, Ind. J. Tech., 8, 369 (1970).
- H.M. Bhajiwala and R.T. Vashi, Bull. Electrochem., 17, 446 (2001).
- G.K. Gomma and M.H. Wahdan, Bull. Chem. Soc. Jpn., 67, 2621 (1994); doi:10.1246/bcsj.67.2621.
References
H.H. Uhlig, Corrosion and Corrosion Control, John Wiley & Sons Inc., London, edn 2 (1971).
G. Wranglen, An Introduction to Corrosion and Protection of Metals, Chapman and Hall, New York, London (1985).
www. Corrosion-doctors.org/SoilCorrosion/Introduction.htm.
P.P. Roberge, Handbook of Corrosion Engineering, McGraw-Hill Professional, New York (2000).
A. Minhaj, P. Saini, M. Quraishi and I. Farooqi, Corros. Preven. & Control, 46, 32 (1999).
E. Khamis and N. Al-Andis, Materialwiss. Werkstofftech., 33, 550 (2002); doi:10.1002/1521-4052(200209)33:9<550::AID-MAWE550>3.0.CO;2-G.
O.K. Abiola, N.C. Oforka and E.E. Ebenso, J. Corros. Sci. Eng., 5, Preprint 10 (2003).
A.Y. El-Etre, Corros. Sci., 45, 2485 (2003); doi:10.1016/S0010-938X(03)00066-0.
M. Behpour, S.M. Ghoreishi, M. Khayatkashani and N. Soltani, Mater. Chem. Phys., 131, 621 (2012); doi:10.1016/j.matchemphys.2011.10.027.
K.O. Orubite and N.C. Oforka, Mater. Lett., 58, 1768 (2004); doi:10.1016/j.matlet.2003.11.030.
S.T. Arab, A.M. Al-Turkustani and S.Y. Al-Nami, Mater. Sci. Res. Ind., 3, 99 (2005).
A.M. Abdel-Gaber, B.A. Abd-El-Nabey, I.M. Sidahmed, A.M. El-Zayady and M. Saadawy, Corros. Sci., 48, 2765 (2006); doi:10.1016/j.corsci.2005.09.017.
A.Y. El-Etre, Appl. Surf. Sci., 252, 8521 (2006); doi:10.1016/j.apsusc.2005.11.066.
E. Khamis, A. Hefnawy and A.M. El- Demerdash, Materialwiss. Werkstofftech., 38, 227 (2007); doi:10.1002/mawe.200600097.
E.E Ebenso, A. Hailemichael, S. A. Umoren and I.B. Obot, Int., J. Electrochem. Soc., 3, 1325 (2008).
M.H. Hussin and M.J. Kassim, Mater. Chem. Phys., 125, 461 (2011); doi:10.1016/j.matchemphys.2010.10.032.
E.A. Noor, J. Eng. Appl. Sci., 3, 23 (2008).
S.T. Arab, A.M. Al-Turkustani and R.H. Al-Dahiri, J. Kor. Chem. Soc., 52, 281 (2008); doi:10.5012/jkcs.2008.52.3.281.
N.O. Eddy, S.A. Odoemelam and P. Ekwumemgbo, Available online at http:// www.Academic journals. Org/ SRE, vol. 4, pp. 33-38 (2009).
B.R. Pandian and G.S. Mathur, Iran J. Chem. Eng., 28, 77 (2009).
E. Chaieb, A. Bouyanzer, B. Hammouti and M. Berrabahm, Acta Phys. Chim. Sin., 25, 1254 (2009); doi:10.3866/PKU.WHXB20090709.
U.F. Ekanem, S.A. Umoren, I.I. Udousoro and P.A. Udoh, J. Mater. Sci., 45, 5558 (2010); doi:10.1007/s10853-010-4617-y.
A.M. Al-Turkustani, S.T. Arab and L.S.S. Al-Qarni, J. Saudi Chem, Soc., 15, 73 (2011); doi:10.1016/j.jscs.2010.10.008.
K. Belmokre, N. Azzouz, F. Kermiche, M. Wery and J. Pagetti, Mater. Corros., 49, 108 (1998); doi:10.1002/(SICI)1521-4176(199802)49:2<108::AID-MACO108>3.0.CO;2-P.
M. Norin and T.G. Vinka, Mater. Corros., 54, 641 (2003); doi:10.1002/maco.200303680.
A. Benmoussat and M. Hadjel, Eurasian Chem. Technol. J., 7, 147 (2005).
A. Benmoussa, M. Hadjel and M. Traisnel, Mater. Corros., 57, 771 (2006); doi:10.1002/maco.200503964.
Y.S. Choi, J.G. Kim and S.J. Yang, Corrosion, 62, 522 (2006); doi:10.5006/1.3279911.
C.A.M. Ferreira, J.A.C. Ponciano, D.S. Vaitsman and D.V. Pérez, Sci. Total Environ., 388, 250 (2007); doi:10.1016/j.scitotenv.2007.07.062.
Z.Y. Liu, X.G. Li, C.W. Du, G.I. Zhai and Y.F. Cheng, Corros. Sci., 50, 2251 (2008); doi:10.1016/j.corsci.2008.05.011.
M. Saheb, D. Neff, P. Dillmann, H. Matthiesen, E. Foy and L. Bellot-Gurlet, Mater. Corros., 60, 99 (2009); doi:10.1002/maco.200805017.
E.A. Noor, Mater. Corr., 62, 786 (2011); doi:10.1002/maco.200905572.
S.S. Abd El Rehim, M.A.M. Ibrahim and K.F. Khalid, Mater. Chem. Phys., 70, 268 (2001); doi:10.1016/S0254-0584(00)00462-4.
E.E. Oguzie, B.N. Okolue, E.E. Ebenso, G.N. Onuoha and A.I. Onuchukwu, Mater. Chem. Phys., 87, 394 (2004); doi:10.1016/j.matchemphys.2004.06.003.
G. El-Mahdy and S. Mahmoud, Corrosion, 51, 436 (1995); doi:10.5006/1.3293609.
A. Frignani, G. Trabanelli, F. Zucchi and M. Zucchini, Proceedings of the 4th Eur. Sym. on Corros. Inh. Univ. Ferrara, Italy, vol. 3, p. 652 (1975).
S.T. Arab and K.M. Emran, Commun. Fac. Sci. Univ. Ank. Series B, 52, 6394 (2006).
F. Mansfeld, Corrosion, 37, 301 (1981); doi:10.5006/1.3621688.
F. Mansfeld, M.W. Kendig and S. Tsai, Corrosion, 38, 478 (1982); doi:10.5006/1.3577363.
F. Kiby, Hist. Soc., 121 (1990).
S. Muralidharan, M. Quraishi and S. Iyer, Corros. Sci., 37, 1739 (1995); doi:10.1016/0010-938X(95)00068-U.
S. Muralidharan, B. Ramesh Babu, S. Venkatakrishna Iyer and S. Rengamani, J. Appl. Electrochem., 26, 291 (1996); doi:10.1007/BF00242098.
A. Fouda and M. El-Semongym, J. Indian Chem. Soc., 59, 89 (1982).
E. Hopson and K. Tales, Iron Fever, The Iron Industry Permeates Kent. Kent, Ct: The Kent Historical Society (1990).
E.E. Ebenso, Bull. Electrochem., 19, 209 (2003).
I. Farooqi, M. Quraishi and P. Saini, Eurocorr., 97, 347 (1997).
N. Subramaniah and K. Ramakrishnaia, Ind. J. Tech., 8, 369 (1970).
H.M. Bhajiwala and R.T. Vashi, Bull. Electrochem., 17, 446 (2001).
G.K. Gomma and M.H. Wahdan, Bull. Chem. Soc. Jpn., 67, 2621 (1994); doi:10.1246/bcsj.67.2621.