Preparation and Characterization of Molecular Imprinted Polymer for Melamine Based on Methacrylamide and 9-Vinylcarbazole as Complexing Monomer

Nor Azah Yusof; Wong Ling Wei; Nor Amirah Maamor; Norhidayah Azeman

doi:10.14233/ajchem.2014.15699

Issue

Vol. 26 No. 8 (2014): Vol 26 Issue 8

Issue Published : April 15, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Preparation and Characterization of Molecular Imprinted Polymer for Melamine Based on Methacrylamide and 9-Vinylcarbazole as Complexing Monomer

https://doi.org/10.14233/ajchem.2014.15699

Nor Azah Yusof

Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 Serdang, Selangor, Malaysia ;Institute of Advanced Technology, Universiti Putra Malaysia, 43400 Serdang, Selangor, Malaysia

Wong Ling Wei

Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 Serdang, Selangor, Malaysia

Nor Amirah Maamor

Department of Chemistry, Faculty of Science, Universiti Putra Malaysia, 43400 Serdang, Selangor, Malaysia

Norhidayah Azeman

Institute of Advanced Technology, Universiti Putra Malaysia, 43400 Serdang, Selangor, Malaysia

Corresponding Author(s) : Nor Azah Yusof

azahy@upm.edu.my

Asian Journal of Chemistry, Vol. 26 No. 8 (2014): Vol 26 Issue 8
Article Published : April 16, 2014

Abstract

Molecular imprinted polymer (MIP) for melamine has been fabricated using precipitation polymerization method using methacrylamide and 9-vinylcarbazole. The molecular imprinted polymer was characterized using Fourier transform infrared spectroscopy, thermo gravimetric analysis, photon cross correlation spectroscopy analysis and scanning electron microscope. Both molecular imprinted polymer (metacrylamide and 9-vinylcarbazole based) have shown reasonable thermal stability. For molecular imprinted polymer of methacrylamide, the average particle size is 158.03 nm while the average particle size molecular imprinted polymer of 9-vinylcarbazole is 298.41 nm. From SEM result, molecular imprinted polymer shows a cloud like structure resulting form aggregated particles.

Keywords

Molecular imprinted polymer Melamine Methacrylamide 9-Vinylcarbazole

Azah Yusof, N., Ling Wei, W., Amirah Maamor, N., & Azeman, N. (2014). Preparation and Characterization of Molecular Imprinted Polymer for Melamine Based on Methacrylamide and 9-Vinylcarbazole as Complexing Monomer. Asian Journal of Chemistry, 26(8), 2285–2288. https://doi.org/10.14233/ajchem.2014.15699

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References

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References

H. Yang, W. Zhou, X. Guo, F. Chen, H. Zhao, L. Lin and X. Wang, Talanta, 80, 821 (2009); doi:10.1016/j.talanta.2009.07.067.

B. Puschner, R.H. Poppenga, L.J. Lowenstine, M.S. Filigenzi and P.A. Pesavento, J. Vet. Diagn. Invest., 19, 616 (2007); doi:10.1177/104063870701900602.

L. He, Y. Su, Y. Zheng, X. Huang, L. Wu, Y. Liu, Z. Zeng and Z. Chen, J. Chromatogr. A, 1216, 6196 (2009); doi:10.1016/j.chroma.2009.06.081.

N.D. Zakaria, N.A. Yusof, J. Haron and A.H. Abdullah, Int. J. Mol. Sci., 10, 354 (2009); doi:10.3390/ijms10010354.

C. He, Y. Long, J. Pan, K. Li and F. Liu, J. Biochem. Biophys. Methods, 70, 133 (2007); doi:10.1016/j.jbbm.2006.07.005.

C.Y. He, F. Liu, K.A. Li and H.W. Liu, Anal. Lett., 39, 275 (2006); doi:10.1080/00032710500476946.

H.H. Yang, S.Q. Zhang, F. Tan, Z.X. Zhuang and X.R. Wang, J. Am. Chem. Soc., 127, 1378 (2005); doi:10.1021/ja0467622.

S. Asman, N.A. Yusof, A.H. Abdullah and M.J. Haron, Molecules, 17, 1916 (2012); doi:10.3390/molecules17021916.

Nor Dyana Zakaria, Asian J. Chem., 23, 2456 (2011).

S. Asman, Asian J. Chem., 23, 4786 (2011).

N.A. Yusof, Sains Malaysiana, 39, 829 (2010).

J. Li, Z. Chen and Y. Li, Anal. Chim. Acta, 706, 255 (2011); doi:10.1016/j.aca.2011.08.048.

J. Yu, C. Zhang, P. Dai and S. Ge, Anal. Chim. Acta, 651, 209 (2009); doi:10.1016/j.aca.2009.08.018.

L. He, Y. Su, Y. Zheng, X. Huang, L. Wu, Y. Liu, Z. Zeng and Z. Chen, J. Chromatogr. A, 1216, 6196 (2009); doi:10.1016/j.chroma.2009.06.081.

Issue

Vol. 26 No. 8 (2014): Vol 26 Issue 8

Preparation and Characterization of Molecular Imprinted Polymer for Melamine Based on Methacrylamide and 9-Vinylcarbazole as Complexing Monomer

Corresponding Author(s) : Nor Azah Yusof

Abstract

Keywords

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