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Vibrational Spectroscopic Study of Two Dimensional Polymer Compounds of 5-Aminouracil
Corresponding Author(s) : Celal Bayrak
Asian Journal of Chemistry,
Vol. 26 No. 8 (2014): Vol 26 Issue 8
Abstract
In this study, FT-IR and FT-Raman spectra of two dimensional coordination polymer compounds, M(5AU)2Ni(CN)4 (where M = Mn, Co, Ni, Zn and Cd; 5AU = 5-aminouracil i.e., 5-amino-2,4-dihydroxypyrimidine) were reported. 5-Aminouracil molecules are found to involve coordination through one of the pyrimidine ring nitrogen atoms. The spectral features suggest that the compounds are similar in structure to the Hofmann type two dimensional coordination polymer compounds, formed with Ni(CN)42- ions bridged by M(5AU)22+ cations. Vibrational bands originated from both 5AU and Ni(CN)4 group were assigned.
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- M.A. Palafox, O.F. Nielsen, K. Lang, P. Garg and V.K. Rastogi, Asian Chem. Lett., 8, 81 (2004).
- O.A. Fathalla, Arch. Pharm. Res., 22, 571 (1999); doi:10.1007/BF02975328.
- A.S. Georgopoulou, S. Ulvenlund, D.P. Mingos, I. Baxter and D.J. Williams, J. Chem. Soc., Dalton Trans., 4, 547 (1999); doi:10.1039/a807723a.
- S. Ulvenlund, A.S. Georgopoulou, D.M.P. Mingos, I. Baxter, S.E. Lawrence, A.J.P. White and D.J. Williams, J. Chem. Soc., Dalton Trans., 11, 1869 (1998); doi:10.1039/a800682b.
- F. Hueso-Ureña, N.A. Illán-Cabeza, M.N. Moreno-Carretero, J.M. Martínez-Martos and M.J. Ramírez-Expósito, J. Inorg. Biochem., 94, 326 (2003); doi:10.1016/S0162-0134(03)00025-4.
- T. Iwamoto, in eds.: J.L. Atwood, J.E.D. Davies and D.D. MacNicol, Inclusion Compounds, Springer, Berlin, Vol. 5, Ch. 6, pp. 177.
- T. Iwamoto, J. Incl. Phenom, 24, 61 (1996); doi:10.1007/BF01053426.
- M. Alcolea Palafox, G. Tardajos, A. Guerrero-Martínez, V.K. Rastogi, D. Mishra, S.P. Ojha and W. Kiefer, Chem. Phys., 340, 17 (2007); doi:10.1016/j.chemphys.2007.07.032.
- S.J. Singh, Spectrosc. Lett., 41, 122 (2008); doi:10.1080/00387010701799761.
- S. Akyüz and J.E.D. Davies, J. Mol. Struct., 95, 157 (1982); doi:10.1016/0022-2860(82)90141-7.
- K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons Inc., New York, edn. 4, p. 279 (1986).
- B. Ishimoto, K. Tonan and S.I. Ikawa, Spectrochim. Acta [A], 55, 2321 (1999); doi:10.1016/S1386-1425(99)00120-1.
- F. Hueso-Urena, N.A. Illan-Cabeza, M.N. Moreno-Carretero, J.M. Martinez-Martos and M.J. Ramirez-Exposito, J. Inorg. Biochem., 94, 326 (2003); doi:10.1016/S0162-0134(03)00025-4.
- S. Cherayath, J. Alice and C.P. Prabhakaran, Trans. Met. Chem. (Weinh.), 15, 449 (1990); doi:10.1007/BF01040774.
- G. Koz, H. Kaya, D. Astley, İ. Yaşa and S. Astley, Gazi University, J. Sci., 24, 407 (2011).
- C. Bayrak, Hacettepe, J. Biol. Chem., 40, 419 (2012).
- C. Bayrak and S. Bayarı, Hacettepe, J. Biol. Chem., 38, 107 (2010).
- S. Akyüz, L. Andreeva, B. Minceva-Sukarova and G. Başar, J. Mol. Struct., 834–836, 399 (2007); doi:10.1016/j.molstruc.2006.11.057.
- S. Akyüz and T. Akyüz, J. Mol. Struct., 744–747, 277 (2005); doi:10.1016/j.molstruc.2004.10.048.
- S. Akyüz, T. Akyüz, Y. Akkaya and E. Akalin, J. Mol. Struct., 834-836, 403 (2007); doi:10.1016/j.molstruc.2006.11.042.
- S. Akyüz and T. Akyüz, J. Mol. Struct., 924-926, 37 (2009); doi:10.1016/j.molstruc.2009.01.023.
- L. Andreeva and B. Minceva-Sukarova, J. Mol. Struct., 408–409, 431 (1997); doi:10.1016/S0022-2860(96)09716-5.
- B. Minceva-Sukarova, L. Andreeva, S. Akyüz and C.A. Koh, Proc. of the 6th Int. Conf. on Fundamental and Applied aspects of Physical Chemistry, vol. I, Belgrade, Yugoslavia, 2002, pp. 66.
- S. Akyüz, A.B. Dempster and R.L. Morehouse, Spectrochim. Acta A, 30, 1989 (1974); doi:10.1016/0584-8539(74)80046-2.
References
M.A. Palafox, O.F. Nielsen, K. Lang, P. Garg and V.K. Rastogi, Asian Chem. Lett., 8, 81 (2004).
O.A. Fathalla, Arch. Pharm. Res., 22, 571 (1999); doi:10.1007/BF02975328.
A.S. Georgopoulou, S. Ulvenlund, D.P. Mingos, I. Baxter and D.J. Williams, J. Chem. Soc., Dalton Trans., 4, 547 (1999); doi:10.1039/a807723a.
S. Ulvenlund, A.S. Georgopoulou, D.M.P. Mingos, I. Baxter, S.E. Lawrence, A.J.P. White and D.J. Williams, J. Chem. Soc., Dalton Trans., 11, 1869 (1998); doi:10.1039/a800682b.
F. Hueso-Ureña, N.A. Illán-Cabeza, M.N. Moreno-Carretero, J.M. Martínez-Martos and M.J. Ramírez-Expósito, J. Inorg. Biochem., 94, 326 (2003); doi:10.1016/S0162-0134(03)00025-4.
T. Iwamoto, in eds.: J.L. Atwood, J.E.D. Davies and D.D. MacNicol, Inclusion Compounds, Springer, Berlin, Vol. 5, Ch. 6, pp. 177.
T. Iwamoto, J. Incl. Phenom, 24, 61 (1996); doi:10.1007/BF01053426.
M. Alcolea Palafox, G. Tardajos, A. Guerrero-Martínez, V.K. Rastogi, D. Mishra, S.P. Ojha and W. Kiefer, Chem. Phys., 340, 17 (2007); doi:10.1016/j.chemphys.2007.07.032.
S.J. Singh, Spectrosc. Lett., 41, 122 (2008); doi:10.1080/00387010701799761.
S. Akyüz and J.E.D. Davies, J. Mol. Struct., 95, 157 (1982); doi:10.1016/0022-2860(82)90141-7.
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons Inc., New York, edn. 4, p. 279 (1986).
B. Ishimoto, K. Tonan and S.I. Ikawa, Spectrochim. Acta [A], 55, 2321 (1999); doi:10.1016/S1386-1425(99)00120-1.
F. Hueso-Urena, N.A. Illan-Cabeza, M.N. Moreno-Carretero, J.M. Martinez-Martos and M.J. Ramirez-Exposito, J. Inorg. Biochem., 94, 326 (2003); doi:10.1016/S0162-0134(03)00025-4.
S. Cherayath, J. Alice and C.P. Prabhakaran, Trans. Met. Chem. (Weinh.), 15, 449 (1990); doi:10.1007/BF01040774.
G. Koz, H. Kaya, D. Astley, İ. Yaşa and S. Astley, Gazi University, J. Sci., 24, 407 (2011).
C. Bayrak, Hacettepe, J. Biol. Chem., 40, 419 (2012).
C. Bayrak and S. Bayarı, Hacettepe, J. Biol. Chem., 38, 107 (2010).
S. Akyüz, L. Andreeva, B. Minceva-Sukarova and G. Başar, J. Mol. Struct., 834–836, 399 (2007); doi:10.1016/j.molstruc.2006.11.057.
S. Akyüz and T. Akyüz, J. Mol. Struct., 744–747, 277 (2005); doi:10.1016/j.molstruc.2004.10.048.
S. Akyüz, T. Akyüz, Y. Akkaya and E. Akalin, J. Mol. Struct., 834-836, 403 (2007); doi:10.1016/j.molstruc.2006.11.042.
S. Akyüz and T. Akyüz, J. Mol. Struct., 924-926, 37 (2009); doi:10.1016/j.molstruc.2009.01.023.
L. Andreeva and B. Minceva-Sukarova, J. Mol. Struct., 408–409, 431 (1997); doi:10.1016/S0022-2860(96)09716-5.
B. Minceva-Sukarova, L. Andreeva, S. Akyüz and C.A. Koh, Proc. of the 6th Int. Conf. on Fundamental and Applied aspects of Physical Chemistry, vol. I, Belgrade, Yugoslavia, 2002, pp. 66.
S. Akyüz, A.B. Dempster and R.L. Morehouse, Spectrochim. Acta A, 30, 1989 (1974); doi:10.1016/0584-8539(74)80046-2.