Vibrational Spectroscopic Study of Two Dimensional Polymer Compounds of 5-Aminouracil

Celal Bayrak; Nilgun secken

doi:10.14233/ajchem.2014.15679

Issue

Vol. 26 No. 8 (2014): Vol 26 Issue 8

Issue Published : April 15, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Vibrational Spectroscopic Study of Two Dimensional Polymer Compounds of 5-Aminouracil

https://doi.org/10.14233/ajchem.2014.15679

Celal Bayrak

Department of Physics, Faculty of Education, Hacettepe University, 06800 Beytepe, Ankara, Turkey ;

Nilgun secken

Department of Chemistry, Faculty of Education, Hacettepe University, 06800 Beytepe, Ankara, Turkey

Corresponding Author(s) : Celal Bayrak

cbayrak@hacettepe.edu.tr

Asian Journal of Chemistry, Vol. 26 No. 8 (2014): Vol 26 Issue 8
Article Published : April 16, 2014

Abstract

In this study, FT-IR and FT-Raman spectra of two dimensional coordination polymer compounds, M(5AU)₂Ni(CN)₄ (where M = Mn, Co, Ni, Zn and Cd; 5AU = 5-aminouracil i.e., 5-amino-2,4-dihydroxypyrimidine) were reported. 5-Aminouracil molecules are found to involve coordination through one of the pyrimidine ring nitrogen atoms. The spectral features suggest that the compounds are similar in structure to the Hofmann type two dimensional coordination polymer compounds, formed with Ni(CN)₄^2- ions bridged by M(5AU)₂²⁺ cations. Vibrational bands originated from both 5AU and Ni(CN)₄ group were assigned.

Keywords

FT-IR and Raman spectra Hofmann type complexes Tetracyanonickelate 5-Aminouracil

Bayrak, C., & secken, N. (2014). Vibrational Spectroscopic Study of Two Dimensional Polymer Compounds of 5-Aminouracil. Asian Journal of Chemistry, 26(8), 2241–2245. https://doi.org/10.14233/ajchem.2014.15679

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References

M.A. Palafox, O.F. Nielsen, K. Lang, P. Garg and V.K. Rastogi, Asian Chem. Lett., 8, 81 (2004).
O.A. Fathalla, Arch. Pharm. Res., 22, 571 (1999); doi:10.1007/BF02975328.
A.S. Georgopoulou, S. Ulvenlund, D.P. Mingos, I. Baxter and D.J. Williams, J. Chem. Soc., Dalton Trans., 4, 547 (1999); doi:10.1039/a807723a.
S. Ulvenlund, A.S. Georgopoulou, D.M.P. Mingos, I. Baxter, S.E. Lawrence, A.J.P. White and D.J. Williams, J. Chem. Soc., Dalton Trans., 11, 1869 (1998); doi:10.1039/a800682b.
F. Hueso-Ureña, N.A. Illán-Cabeza, M.N. Moreno-Carretero, J.M. Martínez-Martos and M.J. Ramírez-Expósito, J. Inorg. Biochem., 94, 326 (2003); doi:10.1016/S0162-0134(03)00025-4.
T. Iwamoto, in eds.: J.L. Atwood, J.E.D. Davies and D.D. MacNicol, Inclusion Compounds, Springer, Berlin, Vol. 5, Ch. 6, pp. 177.
T. Iwamoto, J. Incl. Phenom, 24, 61 (1996); doi:10.1007/BF01053426.
M. Alcolea Palafox, G. Tardajos, A. Guerrero-Martínez, V.K. Rastogi, D. Mishra, S.P. Ojha and W. Kiefer, Chem. Phys., 340, 17 (2007); doi:10.1016/j.chemphys.2007.07.032.
S.J. Singh, Spectrosc. Lett., 41, 122 (2008); doi:10.1080/00387010701799761.
S. Akyüz and J.E.D. Davies, J. Mol. Struct., 95, 157 (1982); doi:10.1016/0022-2860(82)90141-7.
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons Inc., New York, edn. 4, p. 279 (1986).
B. Ishimoto, K. Tonan and S.I. Ikawa, Spectrochim. Acta [A], 55, 2321 (1999); doi:10.1016/S1386-1425(99)00120-1.
F. Hueso-Urena, N.A. Illan-Cabeza, M.N. Moreno-Carretero, J.M. Martinez-Martos and M.J. Ramirez-Exposito, J. Inorg. Biochem., 94, 326 (2003); doi:10.1016/S0162-0134(03)00025-4.
S. Cherayath, J. Alice and C.P. Prabhakaran, Trans. Met. Chem. (Weinh.), 15, 449 (1990); doi:10.1007/BF01040774.
G. Koz, H. Kaya, D. Astley, İ. Yaşa and S. Astley, Gazi University, J. Sci., 24, 407 (2011).
C. Bayrak, Hacettepe, J. Biol. Chem., 40, 419 (2012).
C. Bayrak and S. Bayarı, Hacettepe, J. Biol. Chem., 38, 107 (2010).
S. Akyüz, L. Andreeva, B. Minceva-Sukarova and G. Başar, J. Mol. Struct., 834–836, 399 (2007); doi:10.1016/j.molstruc.2006.11.057.
S. Akyüz and T. Akyüz, J. Mol. Struct., 744–747, 277 (2005); doi:10.1016/j.molstruc.2004.10.048.
S. Akyüz, T. Akyüz, Y. Akkaya and E. Akalin, J. Mol. Struct., 834-836, 403 (2007); doi:10.1016/j.molstruc.2006.11.042.
S. Akyüz and T. Akyüz, J. Mol. Struct., 924-926, 37 (2009); doi:10.1016/j.molstruc.2009.01.023.
L. Andreeva and B. Minceva-Sukarova, J. Mol. Struct., 408–409, 431 (1997); doi:10.1016/S0022-2860(96)09716-5.
B. Minceva-Sukarova, L. Andreeva, S. Akyüz and C.A. Koh, Proc. of the 6th Int. Conf. on Fundamental and Applied aspects of Physical Chemistry, vol. I, Belgrade, Yugoslavia, 2002, pp. 66.
S. Akyüz, A.B. Dempster and R.L. Morehouse, Spectrochim. Acta A, 30, 1989 (1974); doi:10.1016/0584-8539(74)80046-2.

References

M.A. Palafox, O.F. Nielsen, K. Lang, P. Garg and V.K. Rastogi, Asian Chem. Lett., 8, 81 (2004).

O.A. Fathalla, Arch. Pharm. Res., 22, 571 (1999); doi:10.1007/BF02975328.

A.S. Georgopoulou, S. Ulvenlund, D.P. Mingos, I. Baxter and D.J. Williams, J. Chem. Soc., Dalton Trans., 4, 547 (1999); doi:10.1039/a807723a.

S. Ulvenlund, A.S. Georgopoulou, D.M.P. Mingos, I. Baxter, S.E. Lawrence, A.J.P. White and D.J. Williams, J. Chem. Soc., Dalton Trans., 11, 1869 (1998); doi:10.1039/a800682b.

F. Hueso-Ureña, N.A. Illán-Cabeza, M.N. Moreno-Carretero, J.M. Martínez-Martos and M.J. Ramírez-Expósito, J. Inorg. Biochem., 94, 326 (2003); doi:10.1016/S0162-0134(03)00025-4.

T. Iwamoto, in eds.: J.L. Atwood, J.E.D. Davies and D.D. MacNicol, Inclusion Compounds, Springer, Berlin, Vol. 5, Ch. 6, pp. 177.

T. Iwamoto, J. Incl. Phenom, 24, 61 (1996); doi:10.1007/BF01053426.

M. Alcolea Palafox, G. Tardajos, A. Guerrero-Martínez, V.K. Rastogi, D. Mishra, S.P. Ojha and W. Kiefer, Chem. Phys., 340, 17 (2007); doi:10.1016/j.chemphys.2007.07.032.

S.J. Singh, Spectrosc. Lett., 41, 122 (2008); doi:10.1080/00387010701799761.

S. Akyüz and J.E.D. Davies, J. Mol. Struct., 95, 157 (1982); doi:10.1016/0022-2860(82)90141-7.

K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, John Wiley & Sons Inc., New York, edn. 4, p. 279 (1986).

B. Ishimoto, K. Tonan and S.I. Ikawa, Spectrochim. Acta [A], 55, 2321 (1999); doi:10.1016/S1386-1425(99)00120-1.

F. Hueso-Urena, N.A. Illan-Cabeza, M.N. Moreno-Carretero, J.M. Martinez-Martos and M.J. Ramirez-Exposito, J. Inorg. Biochem., 94, 326 (2003); doi:10.1016/S0162-0134(03)00025-4.

S. Cherayath, J. Alice and C.P. Prabhakaran, Trans. Met. Chem. (Weinh.), 15, 449 (1990); doi:10.1007/BF01040774.

G. Koz, H. Kaya, D. Astley, İ. Yaşa and S. Astley, Gazi University, J. Sci., 24, 407 (2011).

C. Bayrak, Hacettepe, J. Biol. Chem., 40, 419 (2012).

C. Bayrak and S. Bayarı, Hacettepe, J. Biol. Chem., 38, 107 (2010).

S. Akyüz, L. Andreeva, B. Minceva-Sukarova and G. Başar, J. Mol. Struct., 834–836, 399 (2007); doi:10.1016/j.molstruc.2006.11.057.

S. Akyüz and T. Akyüz, J. Mol. Struct., 744–747, 277 (2005); doi:10.1016/j.molstruc.2004.10.048.

S. Akyüz, T. Akyüz, Y. Akkaya and E. Akalin, J. Mol. Struct., 834-836, 403 (2007); doi:10.1016/j.molstruc.2006.11.042.

S. Akyüz and T. Akyüz, J. Mol. Struct., 924-926, 37 (2009); doi:10.1016/j.molstruc.2009.01.023.

L. Andreeva and B. Minceva-Sukarova, J. Mol. Struct., 408–409, 431 (1997); doi:10.1016/S0022-2860(96)09716-5.

B. Minceva-Sukarova, L. Andreeva, S. Akyüz and C.A. Koh, Proc. of the 6th Int. Conf. on Fundamental and Applied aspects of Physical Chemistry, vol. I, Belgrade, Yugoslavia, 2002, pp. 66.

S. Akyüz, A.B. Dempster and R.L. Morehouse, Spectrochim. Acta A, 30, 1989 (1974); doi:10.1016/0584-8539(74)80046-2.

Issue

Vol. 26 No. 8 (2014): Vol 26 Issue 8

Vibrational Spectroscopic Study of Two Dimensional Polymer Compounds of 5-Aminouracil

Corresponding Author(s) : Celal Bayrak

Abstract

Keywords

Full Article

Download Citation

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