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Synthesis and Determination of the Stability Constant of Mixed Ligand Complex of Y(III)
Corresponding Author(s) : T. Cam
Asian Journal of Chemistry,
Vol. 26 No. 8 (2014): Vol 26 Issue 8
Abstract
In this study, the stability constants of a mixed ligand complex of the yttrium ion by using ethylenediaminetetraacetic acid (EDTA, H2A) as a primary ligand and 2,3-dihydroxy benzoic acid (2,3-DHBA, H3B) as a secondary ligand has been investigated. The stability constants of the binary and mixed ligand complexes have been determined by using a potentiometric method and the BEST computer program at 25 ºC in a 0.1 M NaCl ionic medium. In addition, the identified complex by potentiometry was isolated as solids and the structural characteristics have been examined using IR, NMR, elemental analysis, AAS, ICP-OES, differential thermal analysis, thermogravimetric analysis and the conductivity method.
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- A. Kula and W. Brzyska, Pol. J. Chem., 74, 45 (2000).
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- T. Çam, N. Turkel and U. Ozer, Main Group Met. Chem., 30, 203 (2007); doi:10.1515/MGMC.2007.30.4.203.
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- E.J. Wheelwright, F.H. Spedding and G. Schwarzenbach, J. Am. Chem. Soc., 75, 4196 (1953); doi:10.1021/ja01113a020.
- K. Kumar, C.A. Chang, L.C. Francesconi, D.D. Dischino, M.F. Malley, J.Z. Gougoutas and M.F. Tweedle, Inorg. Chem., 33, 3567 (1994); doi:10.1021/ic00094a021.
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- J.L. Mackey, J.E. Powell and F.H. Spedding, J. Am. Chem. Soc., 84, 2047 (1962); doi:10.1021/ja00870a007.
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References
F.A. Cotton and G. Wilkison, Advanced Inorganic Chemistry, John Wiley & Sons, New York (1988).
J. Wang, X.D. Zhang, R. Ma and D.M. Fan, Chin. J. Inorg. Chem, 17, 119 (2001).
J. Wang and X.D. Zhang, X. Ling, W.G. Jia and D.M. Fan, Rare Met., 21, 106 (2002).
J. Wang, J. Zhao, X.D. Zhang and J.Q. Gao, Rare Met., 19, 241 (2000).
J. Wang, X.D. Zha and R. Ma, Chem. Res. Chin. Univ., 18, 237 (2002).
J. Wang, D. M. Fan, X.D. Zhang and R. Ma, Acta Chim. Sinica, 60, 536 (2002).
J. Wang, Y. Wang, Zh.H. Zhang, X.D. Zhang, J. Tong, X.Zh. Liu, X.Y. Liu, Y. Zhang and Zh.J. Pan, J. Struct. Chem., 46, 895 (2005); doi:10.1007/s10947-006-0216-9.
L.Q. Zhang, T.T. Fan, J. Wang, B. Liu, D. Li, G.X. Han, R. Xu and X.D. Zhang, Russ. J. Coord. Chem., 36, 389 (2010); doi:10.1134/S107032841005012X.
Holleman-Wiberg’s Inorganic Chemistry, Academic Press, USA (2001).
P. Thakur, P.N. Pathak, T. Gedris and G.R. Choppin, J. Solution Chem., 38, 265 (2009); doi:10.1007/s10953-009-9373-8.
P.A. Baisden, G.R. Choppin and B.B. Garrett, Inorg. Chem., 16, 1367 (1977); doi:10.1021/ic50172a023.
R. Aydin and U. Özer, Chem. Pharm. Bull. (Tokyo), 52, 33 (2004); doi:10.1248/cpb.52.33.
A. Kula and W. Brzyska, Pol. J. Chem., 74, 45 (2000).
K. Burger, Biocoordination Chemistry, Ellis Horwood Limited, Chichester (1990).
G. Gran, Analyst, 77, 661 (1952); doi:10.1039/an9527700661.
G. Schwarzenbach and H. Flaschka, Complexometric Titrations. Interscience Publishers, New York (1969).
J.C. Rossotti and H. Rossotti, J. Chem. Educ., 42, 375 (1965); doi:10.1021/ed042p375.
T. Çam, G. İrez and R. Aydin, J. Chem. Eng. Data, 56, 1813 (2011); doi:10.1021/je100799h.
E. Martell and R.J. Motekaitis, The Determination and Use of Stability Constants, John Wiley & Sons Inc., New York (1988).
T. Çam, N. Turkel and U. Ozer, Main Group Met. Chem., 30, 203 (2007); doi:10.1515/MGMC.2007.30.4.203.
M.R. Smith and A.E. Martell, Critical Stability Constants, Plenum Press, New York (1989).
T. Kiss, K. Atkári, M. Jezowska-bojczuk and P. Decock, J. Coord. Chem., 29, 81 (1993); doi:10.1080/00958979308037128.
R. Aydin and U. Özer, Turkish J. Chem., 21, 428 (1997).
E.J. Wheelwright, F.H. Spedding and G. Schwarzenbach, J. Am. Chem. Soc., 75, 4196 (1953); doi:10.1021/ja01113a020.
K. Kumar, C.A. Chang, L.C. Francesconi, D.D. Dischino, M.F. Malley, J.Z. Gougoutas and M.F. Tweedle, Inorg. Chem., 33, 3567 (1994); doi:10.1021/ic00094a021.
G. Schwarzenbach, R. Gut and G. Anderegg, Helv. Chim. Acta, 37, 937 (1954); doi:10.1002/hlca.19540370402.
J.L. Mackey, J.E. Powell and F.H. Spedding, J. Am. Chem. Soc., 84, 2047 (1962); doi:10.1021/ja00870a007.
S.K. Sahoo, R.K. Bera, L.M. Bara and B.K. Kanungo, Acta Chim. Slov., 55, 243 (2008).
J.E. Huheey, E.A. Keiter and R.L. Keiter, Inorganic Chemistry, Harper Collins College Publishers, New York (1993).
D.R. Lide, Handbook of Chemistry and Physics, CRC Press, New York (2003-2004).