A Supramolecular Copper(II) Complex with an Asymmetric Salamo-Type Ligand: Synthesis and Crystal Structure

W.-K. Dong; Y. Bai; L.-S. Zhang; X.-Y. Dong; M.-M. Zhao; G. Li

doi:10.14233/ajchem.2014.15903

Issue

Vol. 26 No. 8 (2014): Vol 26 Issue 8

Issue Published : April 15, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

A Supramolecular Copper(II) Complex with an Asymmetric Salamo-Type Ligand: Synthesis and Crystal Structure

https://doi.org/10.14233/ajchem.2014.15903

W.-K. Dong

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Y. Bai

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

L.-S. Zhang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

X.-Y. Dong

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

M.-M. Zhao

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

G. Li

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Corresponding Author(s) : W.-K. Dong

dongwk@126.com

Asian Journal of Chemistry, Vol. 26 No. 8 (2014): Vol 26 Issue 8
Article Published : April 16, 2014

Abstract

A supramolecular mononuclear Cu(II) complex, [CuL], has been synthesized via the complexation of copper(II) acetate monohydrate with 4-chloro-4',6'-dibromo-2,2'-[ethylenediyldioxybis(nitrilomethylidyne)]diphenol (H₂L) in methanol/acetone solution and characterized by X-ray diffraction method. X-Ray crystallographic analysis reveals that the Cu(II) atom is tetra-coodinated by N₂O₂ donor atoms from the asymmetic Salamo-type L^2- unit, resulting in an almost regular distorted square-planar geometry. With the help of intermolecular C2-H2A···O2 and C2-H2B···Br1 hydrogen-bonding interactions, a self-assembled 2D-layer supramolecular structure is formed.

Keywords

Asymmetric Salamo-type Ligand Cu(II) Complex Synthesis Crystal structure

Dong, W.-K., Bai, Y., Zhang, L.-S., Dong, X.-Y., Zhao, M.-M., & Li, G. (2014). A Supramolecular Copper(II) Complex with an Asymmetric Salamo-Type Ligand: Synthesis and Crystal Structure. Asian Journal of Chemistry, 26(8), 2341–2343. https://doi.org/10.14233/ajchem.2014.15903

Download Citation

References

(a) P. Pfeiffer, E. Breith, E. Lübbe and T. Tsumaki, Liebigs Ann. Chem., 503, 84 (1933); doi:10.1002/jlac.19335030106; (b) P. Pfeiffer, T. Hesse, H. Pfitzner, W. Scholl and H. Thielert, J. Prakt. Chem., 149, 217 (1937); doi:10.1002/prac.19371490801.
S. Akine, T. Taniguchi and T. Nabeshima, Chem. Lett., 682 (2001); doi:10.1246/cl.2001.682.
L. Xu, Y.P. Zhang and Y.X. Sun, Chinese J. Inorg. Chem., 23, 1999 (2007).
W.K. Dong and Y.J. Ding, Cryst. Res. Technol., 43, 321 (2008); doi:10.1002/crat.200710985.
S. Akine, W.K. Dong and T. Nabeshima, Inorg. Chem., 45, 4677 (2006); doi:10.1021/ic060055n.
W.K. Dong, J.G. Duan, Y.H. Guan, J.Y. Shi and C.Y. Zhao, Inorg. Chim. Acta, 362, 1129 (2009); doi:10.1016/j.ica.2008.05.028.
S. Akine, T. Taniguchi, W.K. Dong, S. Masubuchi and T. Nabeshima, J. Org. Chem., 70, 1704 (2005); doi:10.1021/jo048030y.
Y.M. Jeon, J. Heo and C.A. Mirkin, Tetrahedron Lett., 48, 2591 (2007); doi:10.1016/j.tetlet.2007.01.023.
G.J. Kim and J.H. Shin, Catal. Lett., 63, 83 (1999); doi:10.1023/A:1019040215323.
W.K. Dong, Y.X. Sun, G.H. Liu, L. Li, X.Y. Dong and X.H. Gao, Z. Anorg. Allg. Chem., 638, 1370 (2012); doi:10.1002/zaac.201200074.
S. Akine, T. Matsumoto, S. Sairenji and T. Nabeshima, Supramol. Chem., 23, 106 (2011); doi:10.1080/10610278.2010.514906.
W.K. Dong, K.Q. Li, Y. Zhang, L. Xu, L. Wang and X.Y. Dong, Asian J. Chem., 25, 4398 (2013); doi:10.14233/ajchem.2013.13990.
W.K. Dong, S.J. Xing, Y.X. Sun, L. Zhao, L.Q. Chai and X.H. Gao, J. Coord. Chem., 65, 1212 (2012); doi:10.1080/00958972.2012.669038.
H.L. Wu, X.C. Huang, J.K. Yuan, F. Kou, F. Jia, B. Liu and Y. Bai, Z. Naturforsch., 66b, 1049 (2011); doi:10.5560/ZNB.2011.66b1049.

References

(a) P. Pfeiffer, E. Breith, E. Lübbe and T. Tsumaki, Liebigs Ann. Chem., 503, 84 (1933); doi:10.1002/jlac.19335030106; (b) P. Pfeiffer, T. Hesse, H. Pfitzner, W. Scholl and H. Thielert, J. Prakt. Chem., 149, 217 (1937); doi:10.1002/prac.19371490801.

S. Akine, T. Taniguchi and T. Nabeshima, Chem. Lett., 682 (2001); doi:10.1246/cl.2001.682.

L. Xu, Y.P. Zhang and Y.X. Sun, Chinese J. Inorg. Chem., 23, 1999 (2007).

W.K. Dong and Y.J. Ding, Cryst. Res. Technol., 43, 321 (2008); doi:10.1002/crat.200710985.

S. Akine, W.K. Dong and T. Nabeshima, Inorg. Chem., 45, 4677 (2006); doi:10.1021/ic060055n.

W.K. Dong, J.G. Duan, Y.H. Guan, J.Y. Shi and C.Y. Zhao, Inorg. Chim. Acta, 362, 1129 (2009); doi:10.1016/j.ica.2008.05.028.

S. Akine, T. Taniguchi, W.K. Dong, S. Masubuchi and T. Nabeshima, J. Org. Chem., 70, 1704 (2005); doi:10.1021/jo048030y.

Y.M. Jeon, J. Heo and C.A. Mirkin, Tetrahedron Lett., 48, 2591 (2007); doi:10.1016/j.tetlet.2007.01.023.

G.J. Kim and J.H. Shin, Catal. Lett., 63, 83 (1999); doi:10.1023/A:1019040215323.

W.K. Dong, Y.X. Sun, G.H. Liu, L. Li, X.Y. Dong and X.H. Gao, Z. Anorg. Allg. Chem., 638, 1370 (2012); doi:10.1002/zaac.201200074.

S. Akine, T. Matsumoto, S. Sairenji and T. Nabeshima, Supramol. Chem., 23, 106 (2011); doi:10.1080/10610278.2010.514906.

W.K. Dong, K.Q. Li, Y. Zhang, L. Xu, L. Wang and X.Y. Dong, Asian J. Chem., 25, 4398 (2013); doi:10.14233/ajchem.2013.13990.

W.K. Dong, S.J. Xing, Y.X. Sun, L. Zhao, L.Q. Chai and X.H. Gao, J. Coord. Chem., 65, 1212 (2012); doi:10.1080/00958972.2012.669038.

H.L. Wu, X.C. Huang, J.K. Yuan, F. Kou, F. Jia, B. Liu and Y. Bai, Z. Naturforsch., 66b, 1049 (2011); doi:10.5560/ZNB.2011.66b1049.

Issue

Vol. 26 No. 8 (2014): Vol 26 Issue 8

A Supramolecular Copper(II) Complex with an Asymmetric Salamo-Type Ligand: Synthesis and Crystal Structure

Corresponding Author(s) : W.-K. Dong

Abstract

Keywords

Full Article

Download Citation

References

Table Of Contents