Synthesis, Characterization and Crystal Structure of 2D Copper(II) Complex with 6-Ethoxy-4',6'-dichloro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol

W.-K. Dong; W.-M. Zhou; X.-Y. Zhang; M.-M. Zhao; G. Li; X.-Y. Dong

doi:10.14233/ajchem.2014.15902

Issue

Vol. 26 No. 8 (2014): Vol 26 Issue 8

Issue Published : April 15, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Characterization and Crystal Structure of 2D Copper(II) Complex with 6-Ethoxy-4',6'-dichloro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol

https://doi.org/10.14233/ajchem.2014.15902

W.-K. Dong

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

W.-M. Zhou

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

X.-Y. Zhang

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

M.-M. Zhao

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

G. Li

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

X.-Y. Dong

School of Chemical and Biological Engineering, Lanzhou Jiaotong University, Lanzhou 730070, P.R. China

Corresponding Author(s) : W.-K. Dong

dongwk@126.com

Asian Journal of Chemistry, Vol. 26 No. 8 (2014): Vol 26 Issue 8
Article Published : April 16, 2014

Abstract

A new Cu(II) complex with asymmetric Salamo-type ligand, 6-ethoxy-4',6'-dichloro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol (H₂L) has been synthesized and characterized by elemental analyses, FT-IR, UV-visible spectra and single crystal X-ray crystallography. The X-ray crystal structure of the Cu(II) complex reveals it to be a mononuclear structure, which contains one Cu(II) atom and one deprotonated L^2- unit. The center Cu(II) atom is tetra-coordinated, showing that the coordination sphere can be described as a square planar geometry distorted tetrahedrally by 33.07(4)º. In addition, the Cu(II) complex is linked to form an infinite 2D layer supramolecular structure through intermolecular C-H···O and C-H···Cl hydrogen bonds and p···p stacking interactions.

Keywords

Asymmetric Salamo-type ligand Cu(II) complex Synthesis Crystal structure

Dong, W.-K., Zhou, W.-M., Zhang, X.-Y., Zhao, M.-M., Li, G., & Dong, X.-Y. (2014). Synthesis, Characterization and Crystal Structure of 2D Copper(II) Complex with 6-Ethoxy-4’,6’-dichloro-2,2’-[ethylenedioxybis(nitrilomethylidyne)]diphenol. Asian Journal of Chemistry, 26(8), 2337–2340. https://doi.org/10.14233/ajchem.2014.15902

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References

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(a) W.K. Dong, Y.X. Sun, C.Y. Zhao, X.Y. Dong and L. Xu, Polyhedron, 29, 2087 (2010); doi:10.1016/j.poly.2010.04.006; (b) W.K. Dong, Y.X. Sun, G.H. Liu, L. Li, X.Y. Dong and X.H. Gao, Z. Anorg. Allg. Chem., 638, 1370 (2012); doi:10.1002/zaac.201200074; (c) W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009); doi:10.1016/j.poly.2009.03.017.; (d) W.K. Dong, Y.X. Sun, Y.P. Zhang, L. Li, X.N. He and X.L. Tang, Inorg. Chim. Acta, 362, 117 (2009); doi:10.1016/j.ica.2008.03.128; (e) W.K. Dong, L. Li, C.F. Li, L. Xu and J.G. Duan, Spectrochim. Acta A, 71, 650 (2008); doi:10.1016/j.saa.2008.01.020; (f) W.K. Dong, J.Y. Shi, L. Xu, J.K. Zhong, J.G. Duan and Y.P. Zhang, Appl. Organomet. Chem., 22, 89 (2008); doi:10.1002/aoc.1355; (g) W.K. Dong, S.J. Xing, Y.X. Sun, L. Zhao, L.Q. Chai and X.H. Gao, J. Coord. Chem., 65, 1212 (2012); doi:10.1080/00958972.2012.669038; (h) W.K. Dong, K.Q. Li, Y. Zhang, L. Xu, L. Wang and X.Y. Dong, Asian J. Chem., 25, 4398 (2013); doi:10.14233/ajchem.2013.13990.
H.L. Wu, J.K. Yuan, Y. Bai, F. Jia, B. Liu, F. Kou and J. Kong, Transition Met. Chem., 36, 819 (2011); doi:10.1007/s11243-011-9536-5.
H.L. Wu, K. Li, T. Sun, F. Kou, F. Jia, J.K. Yuan, B. Liu and B.L. Qi, Transition Met. Chem., 36, 21 (2011); doi:10.1007/s11243-010-9429-z.
K. Ueno and A.E. Martell, J. Phys. Chem., 60, 1270 (1956); doi:10.1021/j150543a029.
T. Ghosh, B. Mondal, T. Ghosh, M. Sutradhar, G. Mukherjee and M.G.B. Drew, Inorg. Chim. Acta, 360, 1753 (2007); doi:10.1016/j.ica.2006.10.003.
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References

D. Hall and T.N. Waters, J. Chem. Soc., 2644 (1960); doi:10.1039/jr9600002644.

J. Reglinski, S. Morris and D.E. Stevenson, Polyhedron, 21, 2167 (2002); doi:10.1016/S0277-5387(02)01171-3.

A.D. Garnovskii, A.L. Nivorozhkin and V.I. Minkin, Coord. Chem. Rev., 126, 1 (1993); doi:10.1016/0010-8545(93)85032-Y.

Z.L. You, H.L. Zhu and W.S. Liu, Z. Anorg. Allg. Chem., 630, 1617 (2004); doi:10.1002/zaac.200400125.

Z.L. You and H.L. Zhu, Z. Anorg. Allg. Chem., 630, 2754 (2004); doi:10.1002/zaac.200400270.

D. Chen and A.E. Martell, Inorg. Chem., 26, 1026 (1987); doi:10.1021/ic00254a013.

K. Oyaizu and E. Tsuchida, Inorg. Chim. Acta, 355, 414 (2003); doi:10.1016/S0020-1693(03)00311-6.

H.Q. Yang, L. Zhang, L. Zhong, Q. Yang and C. Li, Angew. Chem. Int. Ed., 46, 6861 (2007); doi:10.1002/anie.200701747.

S. Jain, X. Zheng, C.W. Jones, M. Weck and R.J. Davis, Inorg. Chem., 46, 8887 (2007); doi:10.1021/ic700782f.

K.D. Karlin and Z. Tyeklar, Bioinorganic Chemistry of Copper, Chapman & Hall, New York (1993).

A. Elmali, C.T. Zeyrek and Y. Elerman, J. Mol. Struct., 693, 225 (2004); doi:10.1016/j.molstruc.2004.02.037.

E.J. Gao, M.S. Chen, Y. Yu and Y.G. Sun, Chinese J. Struct. Chem., 26, 59 (2007).

S.S. Sun, C.L. Stern, S.T. Nguyen and J.T. Hupp, J. Am. Chem. Soc., 126, 6314 (2004); doi:10.1021/ja037378s.

(a) W.K. Dong, Y.X. Sun, C.Y. Zhao, X.Y. Dong and L. Xu, Polyhedron, 29, 2087 (2010); doi:10.1016/j.poly.2010.04.006; (b) W.K. Dong, Y.X. Sun, G.H. Liu, L. Li, X.Y. Dong and X.H. Gao, Z. Anorg. Allg. Chem., 638, 1370 (2012); doi:10.1002/zaac.201200074; (c) W.K. Dong, X.N. He, H.B. Yan, Z.W. Lv, X. Chen, C.Y. Zhao and X.L. Tang, Polyhedron, 28, 1419 (2009); doi:10.1016/j.poly.2009.03.017.; (d) W.K. Dong, Y.X. Sun, Y.P. Zhang, L. Li, X.N. He and X.L. Tang, Inorg. Chim. Acta, 362, 117 (2009); doi:10.1016/j.ica.2008.03.128; (e) W.K. Dong, L. Li, C.F. Li, L. Xu and J.G. Duan, Spectrochim. Acta A, 71, 650 (2008); doi:10.1016/j.saa.2008.01.020; (f) W.K. Dong, J.Y. Shi, L. Xu, J.K. Zhong, J.G. Duan and Y.P. Zhang, Appl. Organomet. Chem., 22, 89 (2008); doi:10.1002/aoc.1355; (g) W.K. Dong, S.J. Xing, Y.X. Sun, L. Zhao, L.Q. Chai and X.H. Gao, J. Coord. Chem., 65, 1212 (2012); doi:10.1080/00958972.2012.669038; (h) W.K. Dong, K.Q. Li, Y. Zhang, L. Xu, L. Wang and X.Y. Dong, Asian J. Chem., 25, 4398 (2013); doi:10.14233/ajchem.2013.13990.

H.L. Wu, J.K. Yuan, Y. Bai, F. Jia, B. Liu, F. Kou and J. Kong, Transition Met. Chem., 36, 819 (2011); doi:10.1007/s11243-011-9536-5.

H.L. Wu, K. Li, T. Sun, F. Kou, F. Jia, J.K. Yuan, B. Liu and B.L. Qi, Transition Met. Chem., 36, 21 (2011); doi:10.1007/s11243-010-9429-z.

K. Ueno and A.E. Martell, J. Phys. Chem., 60, 1270 (1956); doi:10.1021/j150543a029.

T. Ghosh, B. Mondal, T. Ghosh, M. Sutradhar, G. Mukherjee and M.G.B. Drew, Inorg. Chim. Acta, 360, 1753 (2007); doi:10.1016/j.ica.2006.10.003.

H.E. Smith, Chem. Rev., 83, 359 (1983); doi:10.1021/cr00056a001.

L. Gomes, E. Pereira and B. de Castro, J. Chem. Soc., Dalton Trans., 1373 (2000); doi:10.1039/a908330h.

Issue

Vol. 26 No. 8 (2014): Vol 26 Issue 8

Synthesis, Characterization and Crystal Structure of 2D Copper(II) Complex with 6-Ethoxy-4',6'-dichloro-2,2'-[ethylenedioxybis(nitrilomethylidyne)]diphenol

Corresponding Author(s) : W.-K. Dong

Abstract

Keywords

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