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Vol. 31 No. 11 (2019): Vol 31 Issue 11

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Tris-Triazole Based Chemosensors for Selective Sensing of Pb2+ Ions

https://doi.org/10.14233/ajchem.2019.22076
Poonam Rani
Department of Chemistry, Guru Jambheshwar University of Science & Technology, Hisar-125001, India
Kashmiri Lal
Department of Chemistry, Guru Jambheshwar University of Science & Technology, Hisar-125001, India
Rahul Shrivastava
Department of Chemistry, Manipal University Jaipur, V.P.O. Dehmi Kalan, Jaipur-Ajmer Expressway, Jaipur-303007, India

Corresponding Author(s) : Kashmiri Lal

klal_iitd@yahoo.com

Asian Journal of Chemistry, Vol. 31 No. 11 (2019): Vol 31 Issue 11

Abstract

A series of novel tris-trizole based neutral chemosensors (4a-c) have been synthesized via click reaction and characterized by various spectral techniques. All the synthesized triazoles were evaluated for their ion binding properties towards various cations (Cu2+, Zn2+, Ca2+, Co2+, Cd2+, Hg2+, Pb2+ and Ni2+) by UV-visible titration experiments. It was observed that the addition of Pb2+ ions to compound 4a led to significant changes in UV-visible spectrum and a new UV band was observed at 262 nm. Further, the Job′s plot confirmed the formation of 1:1 complex between compound 4a and Pb2+. The synthesized chemosensor selectively sense Pb2+ ions in preference to other cations like Cu2+, Zn2+, Ca2+, Co2+, Cd2+, Hg2+, Pb2+ and Ni2+.

Keywords

1,2,3-Triazoles Click reaction Chemosensors Lead ions
Rani, P., Lal, K., & Shrivastava, R. (2019). Tris-Triazole Based Chemosensors for Selective Sensing of Pb2+ Ions. Asian Journal of Chemistry, 31(11), 2443–2447. https://doi.org/10.14233/ajchem.2019.22076
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