Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Adsorptive Removal of Cr(VI) by Acinetobacter junii VITSUKMW3 Immobilized on Coconut Fiber in Batch and Continuous Flow Reactor
Corresponding Author(s) : Amitava Mukherjee
Asian Journal of Chemistry,
Vol. 26 No. 9 (2014): Vol 26 Issue 9
Abstract
The removal of Cr(VI) by the biomass of Acinetobacter junii immobilized on coconut fiber in batch and continuous systems were investigated. For batch system under optimized conditions (pH 2; contact time, 480 min; 30 °C; initial Cr(VI) concentration of 50 mg/L), an adsorption capacity of 17.4 mg/g was recorded. In continuous packed bed column reactors, a capacity of 39.4 mg/g was noted with a bed height of 18 cm, a flow rate of 5 mL/min, an initial Cr(VI) concentration of 50 mg/L was employed. The batch sorption data followed the Langmuir isotherm and pseudo first order kinetics. Adsorption studies using Cr(VI) spiked freshwater, ground water and domestic wastewater in a continuous packed bed column reactors demonstrated Cr(VI) removals of 29.3, 43.6, 37.3, 25 %, respectively.
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G.S. Agarwal, H.K. Bhuptawat and S. Chaudhari, Bioresour. Technol., 97, 949 (2006); doi:10.1016/j.biortech.2005.04.030.
M.L. Paul, J. Samuel, N. Chandrasekaran and A. Mukherjee, Chem. Eng. J., 187, 104 (2012); doi:10.1016/j.cej.2012.01.106.
P.E. Molokwane, K.C. Meli and E.M. Nkhalambayausi-Chirwa, Water Res., 42, 4538 (2008); doi:10.1016/j.watres.2008.07.040.
K. Sundar, A. Mukherjee, M. Sadiq and N. Chandrasekaran, J. Hazard. Mater., 187, 553 (2011); doi:10.1016/j.jhazmat.2011.01.077.
J. Samuel, M.L. Paul, M. Pulimi, M.J. Nirmala, N. Chandrasekaran and A. Mukherjee, Ind. Eng. Chem. Res., 51, 3740 (2012); doi:10.1021/ie201796s.
C. Quintelas, B. Fonseca, B. Silva, H. Figueiredo and T. Tavares, Bioresour. Technol., 100, 220 (2009); doi:10.1016/j.biortech.2008.05.010.
C. Quintelas, Z. Rocha, B. Silva, B. Fonseca, H. Figueiredo and T. Tavares, Chem. Eng. J., 149, 319 (2009); doi:10.1016/j.cej.2008.11.025.
C. Quintelas, Z. Rocha, B. Silva, B. Fonseca, H. Figueiredo and T. Tavares, Chem. Eng. J., 152, 110 (2009); doi:10.1016/j.cej.2009.03.039.
A.D. Eaton, L.S. Clesceri, E.W. Rice, A.E. Greenberg and M.A.H. Franson, Standard Methods for the Examination of Water and Wastewater, 21st edn. American Public Health Association (APHA), Washington, 2005.
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C. Namasivayam and M.V. Sureshkumar, Bioresour. Technol., 99, 2218 (2008); doi:10.1016/j.biortech.2007.05.023.
D. Nityanandi and C.V. Subbhuraam, J. Hazard. Mater., 170, 876 (2009); doi:10.1016/j.jhazmat.2009.05.049.
K. Anjana, A. Kaushik, B. Kiran and R. Nisha, J. Hazard. Mater., 148, 383 (2007); doi:10.1016/j.jhazmat.2007.02.051.
A. Selatnia, M.Z. Bakhti, A. Madani, I. Kertous and Y. Mansouri, Hydrometallurgy, 75, 11 (2004); doi:10.1016/j.hydromet.2004.06.005.
S.S. Baral, S.N. Das and P. Rath, Biochem. Eng. J., 31, 216 (2006); doi:10.1016/j.bej.2006.08.003.
S.K. Singh, A. Bansal, M.A. Jha and A. Dey, Bioresour. Technol., 104, 257 (2012); doi:10.1016/j.biortech.2011.11.044.
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K. Selvi, S. Pattabhi and K. Kadirvelu, Bioresour. Technol., 80, 87 (2001); doi:10.1016/S0960-8524(01)00068-2.
S. Babel and T.A. Kurniawan, Chemosphere, 54, 951 (2004); doi:10.1016/j.chemosphere.2003.10.001.
P. Suksabye, P. Thiravetyan and W. Nakbanpote, J. Hazard. Mater., 160, 56 (2008); doi:10.1016/j.jhazmat.2008.02.083.
Y.G. Ko, Y.J. Chun, C.H. Kim and U.S. Choi, J. Hazard. Mater., 194, 92 (2011); doi:10.1016/j.jhazmat.2011.07.088.
R. Kumar, D. Bhatia, R. Singh, S. Rani and N.R. Bishnoi, Int. Biodeter. Biodegrad., 65, 1133 (2011); doi:10.1016/j.ibiod.2011.09.003.
M. Tamez Uddin, M. Rukanuzzaman, M. Maksudur Rahman Khan and M. Akhtarul Islam, J. Environ. Manage., 90, 3443 (2009); doi:10.1016/j.jenvman.2009.05.030.
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S.S. Baral, N. Das, T.S. Ramulu, S.K. Sahoo, S.N. Das and G.R. Chaudhury, J. Hazard. Mater., 161, 1427 (2009); doi:10.1016/j.jhazmat.2008.04.127.
E. Malkoc, Y. Nuhoglu and M. Dundar, J. Hazard. Mater., 138, 142 (2006); doi:10.1016/j.jhazmat.2006.05.051.
S. Chen, Q. Yue, B. Gao, Q. Li, X. Xu and K. Fu, Bioresour. Technol., 113, 114 (2012); doi:10.1016/j.biortech.2011.11.110.
A.A. Ahmad and B.H. Hameed, J. Hazard. Mater., 175, 298 (2010); doi:10.1016/j.jhazmat.2009.10.003.
R.P. Han, Y. Wang, X. Zhao, Y.F. Wang, F.L. Xie, J.M. Cheng and M.S. Tang, Desalination, 245, 284 (2009); doi:10.1016/j.desal.2008.07.013.
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M.R. Unnithan, V.P. Vinod and T.S. Anirudhan, Ind. Eng. Chem. Res., 43, 2247 (2004); doi:10.1021/ie0302084.
J. Liu, H. Zhang and X. Liu, Adv. Mater. Res., 343-344, 172 (2011); doi:10.4028/www.scientific.net/AMR.343-344.172.