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Mechanistic and Characterization Studies for Sorptive Elimination of Emerald Green Dye from Water By Arachis hypogeal Shells and Citrullus lanatus Peels
Corresponding Author(s) : Rabia Rehman
Asian Journal of Chemistry,
Vol. 26 No. 9 (2014): Vol 26 Issue 9
Abstract
Emerald green dye adsorption by Arachis hypogeal shells and Citrullus lanatus peels has been investigated in this study. Characterization of adsorbents by measuring pH, bulk density, pHpzc, porosity, iodine number, moisture contents, ash contents, elemental contents, carboxylic (acidic functions), phenolic, lactonic and basic sites were conducted.The adsorption process was done in a batch process by varying contact time intervals, adsorbent doses, different initial pH, agitation speed and temperature. The suitability of the data was confirmed by determining isothermal parameters, which showed that sorption capacity of Citrullus lanatus peels for Emerald green dye is 2.099 mg g-1 with DG0 -2.785 KJ mol-1 and it is better adsorbent as compared to Arachis hypogeal shells, which adsorbs only 1.989 mg g-1 of dye with DG0 -1.432 KJ mol-1. Both of them can be used on larger scale water treatment for removing Emerald green dye.
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- B. Samiey and F. Ashoori, Chem. Cent. J., 6, 14 (2012); doi:10.1186/1752-153X-6-14.
- N. Daneshvar, M. Ayazloo, A.R. Khataee and M. Pourhassan, Bioresour. Technol., 98, 1176 (2007); doi:10.1016/j.biortech.2006.05.025.
- R. Rehman and T. Mahmud, Asian J. Chem., 25, 8285 (2013); doi:10.14233/ajchem.2013.14713.
- G.V. Kumar, P. Agrawal and L. Hiremath, Int. J. Chem. Tech. Res., 43, 19 (2012).
- W.J. Epolito, Y.H. Lee, L.A. Bottomley and S.G. Pavlostathis, Dyes Pigments, 67, 35 (2005); doi:10.1016/j.dyepig.2004.10.006.
- B.K. Nandi, A. Goswami and M.K. Purkait, Appl. Clay Sci., 42, 583 (2009); doi:10.1016/j.clay.2008.03.015.
- R. Rehman, J. Anwar, T. Mahmud and M. Salman, J. Chem. Soc. Pak., 34, 136 (2012).
- R. Rehman, T. Mahmud, J. Anwar, W. Zaman, M. Moeen and J. Zafar, J. Chem. Soc. Pak., 34, 1120 (2012).
- S.S. Nawar and H.S. Doma, Sci. Total Environ., 79, 271 (1989); doi:10.1016/0048-9697(89)90342-2.
- K. Santhy and P. Selvapathy, Bioresour. Technol., 97, 1329 (2006); doi:10.1016/j.biortech.2005.05.016.
- A.O. Ibhadon, G.M. Greenway, Y. Yue, P. Falaras and D. Tsoukleris, Appl. Catal. B, 84, 351 (2008); doi:10.1016/j.apcatb.2008.04.019.
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- E. Guibal and J. Roussy, React. Funct. Polym., 67, 33 (2007); doi:10.1016/j.reactfunctpolym.2006.08.008.
- K.G. Bhattacharyya and A. Sarma, Dyes Pigments, 57, 211 (2003); doi:10.1016/S0143-7208(03)00009-3.
- Y. Kismir and A.Z. Aroguz, Chem. Eng. J., 172,199 (2011); doi:10.1016/j.cej.2011.05.090.
- R. Kobiraj, N. Gupta, A.K. Kushwaha and M.C. Chattopadhyaya, Indian J. Chem. Technol., 19, 26 (2012).
- V.S. Mane and P.V.V. Babu, Desalination, 273, 321 (2011); doi:10.1016/j.desal.2011.01.049.
- M. Oplatowska, R.F. Donnelly, R.J. Majithiya, D.G. Kennedy and C.T. Elliott, Food Chem. Toxicol., 49, 1870 (2011).
- V.S. Mane, I.D. Mall and V.C. Srivastava, J. Environ. Manage., 84, 390 (2007); doi:10.1016/j.jenvman.2006.06.024.
- A. Mittal, D. Kaur and J. Mittal, J. Colloid Interf. Sci., 326, 8 (2008); doi:10.1016/j.jcis.2008.07.005.
- P.A. Janssen, B.L. Selwood, S.R. Dobson, D. Peacock and P.N. Thiessen, Pediatrics, 111, 15 (2003); doi:10.1542/peds.111.1.15.
- H. Tavallali, M. Ostovar and P. Noor, Int. J. Chem. Tech. Res., 1, 199 (2009).
- J. Song, W. Zou, Y. Bian, F. Su and R. Han, Desalination, 265, 119 (2011); doi:10.1016/j.desal.2010.07.041.
- P. Brown, I. Atly Jefcoat, D. Parrish, S. Gill and E. Graham, Adv. Environ. Res., 4, 19 (2000); doi:10.1016/S1093-0191(00)00004-6.
- K.S. Bharathi and S.T.M. Ramesh, J. Environ. Res. Dev., 7, 321 (2012).
- A.M. Rimando and P.M. Perkins-Veazie, J. Chromatogr. A, 1078, 196 (2005); doi:10.1016/j.chroma.2005.05.009.
- O.A. Ekpete and M. JNR Horsfall, Res. J. Chem. Sci., 1, 10 (2011).
- A.P. Vieira, S.A.A. Santana, C.W.B. Bezerra, H.A.S. Silva, J.A.P. Chaves, J.C.P. de Melo, E.C. da Silva Filho and C. Airoldi, J. Hazard. Mater., 166, 1272 (2009); doi:10.1016/j.jhazmat.2008.12.043.
- M.M. Nassar, M.F. Hamoda and G.H. Radwan, Water Sci. Technol., 32, 27 (1995); doi:10.1016/0273-1223(96)00114-X.
- R. Rehman, T. Mahmud and W. Zaman, Asian J. Chem., 25, 4261 (2013); doi:10.14233/ajchem.2013.13928.
References
B. Samiey and F. Ashoori, Chem. Cent. J., 6, 14 (2012); doi:10.1186/1752-153X-6-14.
N. Daneshvar, M. Ayazloo, A.R. Khataee and M. Pourhassan, Bioresour. Technol., 98, 1176 (2007); doi:10.1016/j.biortech.2006.05.025.
R. Rehman and T. Mahmud, Asian J. Chem., 25, 8285 (2013); doi:10.14233/ajchem.2013.14713.
G.V. Kumar, P. Agrawal and L. Hiremath, Int. J. Chem. Tech. Res., 43, 19 (2012).
W.J. Epolito, Y.H. Lee, L.A. Bottomley and S.G. Pavlostathis, Dyes Pigments, 67, 35 (2005); doi:10.1016/j.dyepig.2004.10.006.
B.K. Nandi, A. Goswami and M.K. Purkait, Appl. Clay Sci., 42, 583 (2009); doi:10.1016/j.clay.2008.03.015.
R. Rehman, J. Anwar, T. Mahmud and M. Salman, J. Chem. Soc. Pak., 34, 136 (2012).
R. Rehman, T. Mahmud, J. Anwar, W. Zaman, M. Moeen and J. Zafar, J. Chem. Soc. Pak., 34, 1120 (2012).
S.S. Nawar and H.S. Doma, Sci. Total Environ., 79, 271 (1989); doi:10.1016/0048-9697(89)90342-2.
K. Santhy and P. Selvapathy, Bioresour. Technol., 97, 1329 (2006); doi:10.1016/j.biortech.2005.05.016.
A.O. Ibhadon, G.M. Greenway, Y. Yue, P. Falaras and D. Tsoukleris, Appl. Catal. B, 84, 351 (2008); doi:10.1016/j.apcatb.2008.04.019.
N. Junnarkar, D.S. Murty, N.S. Bhatt and D. Madamwar, World J. Microbiol. Biotechnol., 22, 163 (2006); doi:10.1007/s11274-005-9014-3.
E. Guibal and J. Roussy, React. Funct. Polym., 67, 33 (2007); doi:10.1016/j.reactfunctpolym.2006.08.008.
K.G. Bhattacharyya and A. Sarma, Dyes Pigments, 57, 211 (2003); doi:10.1016/S0143-7208(03)00009-3.
Y. Kismir and A.Z. Aroguz, Chem. Eng. J., 172,199 (2011); doi:10.1016/j.cej.2011.05.090.
R. Kobiraj, N. Gupta, A.K. Kushwaha and M.C. Chattopadhyaya, Indian J. Chem. Technol., 19, 26 (2012).
V.S. Mane and P.V.V. Babu, Desalination, 273, 321 (2011); doi:10.1016/j.desal.2011.01.049.
M. Oplatowska, R.F. Donnelly, R.J. Majithiya, D.G. Kennedy and C.T. Elliott, Food Chem. Toxicol., 49, 1870 (2011).
V.S. Mane, I.D. Mall and V.C. Srivastava, J. Environ. Manage., 84, 390 (2007); doi:10.1016/j.jenvman.2006.06.024.
A. Mittal, D. Kaur and J. Mittal, J. Colloid Interf. Sci., 326, 8 (2008); doi:10.1016/j.jcis.2008.07.005.
P.A. Janssen, B.L. Selwood, S.R. Dobson, D. Peacock and P.N. Thiessen, Pediatrics, 111, 15 (2003); doi:10.1542/peds.111.1.15.
H. Tavallali, M. Ostovar and P. Noor, Int. J. Chem. Tech. Res., 1, 199 (2009).
J. Song, W. Zou, Y. Bian, F. Su and R. Han, Desalination, 265, 119 (2011); doi:10.1016/j.desal.2010.07.041.
P. Brown, I. Atly Jefcoat, D. Parrish, S. Gill and E. Graham, Adv. Environ. Res., 4, 19 (2000); doi:10.1016/S1093-0191(00)00004-6.
K.S. Bharathi and S.T.M. Ramesh, J. Environ. Res. Dev., 7, 321 (2012).
A.M. Rimando and P.M. Perkins-Veazie, J. Chromatogr. A, 1078, 196 (2005); doi:10.1016/j.chroma.2005.05.009.
O.A. Ekpete and M. JNR Horsfall, Res. J. Chem. Sci., 1, 10 (2011).
A.P. Vieira, S.A.A. Santana, C.W.B. Bezerra, H.A.S. Silva, J.A.P. Chaves, J.C.P. de Melo, E.C. da Silva Filho and C. Airoldi, J. Hazard. Mater., 166, 1272 (2009); doi:10.1016/j.jhazmat.2008.12.043.
M.M. Nassar, M.F. Hamoda and G.H. Radwan, Water Sci. Technol., 32, 27 (1995); doi:10.1016/0273-1223(96)00114-X.
R. Rehman, T. Mahmud and W. Zaman, Asian J. Chem., 25, 4261 (2013); doi:10.14233/ajchem.2013.13928.