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A Novel Mutually Perpendicular Bicyclo-Shape Tetranuclear Complex Constructed from 2,3-Dihydroxy butanedioic Acid with Pisces Mode
Corresponding Author(s) : B.Q. Yang
Asian Journal of Chemistry,
Vol. 26 No. 9 (2014): Vol 26 Issue 9
Abstract
A new complex [Ni4(dhbd)4·8H2O]·13H2O (1) (H4dhbd = 2,3-dihydroxy butanedioic acid) has been synthesized and its structure (C16H16O45Ni4, Mr = 1163.13) was determined by single-crystal X-ray diffraction analysis. The crystal belongs to the monoclinic system, space group P21/c with a = 13.700(5), b = 17.143(5), c = 18.599(5) Å, b = 96.786(5), V = 4338(2) Å3, Z = 4, Dc = 1.781 g/cm3, μ(MoKa) = 1.839 mm-1, F(000) = 2336, S = 1.025, the final R = 0.0524 and wR = 0.1390 for 9257 reflections with I > 2s(I). The centrosymmetric nickel complex contains a tetranuclear in which four distorted octahedral Ni(II) centers are bridged by the carboxylic oxygen atoms and the hydroxy oxygen atoms of the four 2,3-dihydroxy butanedioic acid with the Pisces mode, featuring a novel mutually perpendicular bicyclo structure. The complex units are further linked to form three-dimentional supramolecular structure via the hydrogen bonds between the coordinate water molecules and the plentiful free water molecules. The elemental analysis and optical properties for the complex have been studied.
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- T. Higashi, Program for Absorption Correction, Rigaku Corporation, Tokyo, Japan (1995).
- SHELXTL, Version 5.1, Siemens Industrial Automation, Inc. (1997).
- G.M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany (1997).
- Y. Wang, G.X. Liu, Y.C. Chen, K.B. Wang and S.-G. Meng, Inorg. Chim. Acta, 363, 2668 (2010); doi:10.1016/j.ica.2010.03.076.
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References
B. Moulton and M.J. Zaworotko, Chem. Rev., 101, 1629 (2001); doi:10.1021/cr9900432.
M.W. Hosseini, Acc. Chem. Res., 38, 313 (2005); doi:10.1021/ar0401799.
A.Y. Robin and K.M. Fromm, Coord. Chem. Rev., 250, 2127 (2006); doi:10.1016/j.ccr.2006.02.013.
G.D. Feng, L. Jiang and Z.M. Su, Z. Anorg. Allg. Chem., 637, 2211 (2011); doi:10.1002/zaac.201100270.
N.L. Rosi, M. Eddaoudi, J. Kim, M. O’Keeffe and O.M. Yaghi, Angew. Chem. Int. Ed. Engl., 41, 284 (2002); doi:10.1002/1521-3773(20020118)41:2<284::AID-ANIE284>3.0.CO;2-M.
C. Serre, F. Millange, C. Thouvenot, N. Gardant, F. Pelle and G. Ferey, J. Mater. Chem., 14, 1540 (2004); doi:10.1039/b312425h.
Y. Cui, H.L. Ngo, P.S. White and W. Lin, Chem. Commun., 994 (2003); doi:10.1039/b211916a.
F. Fu, D.S. Li, J. Zhao and W.W. Dong, Chinese J. Struct. Chem., 28, 925 (2009).
F. Luo, Y.- Che and J.- Zheng, Inorg. Chem. Commun., 9, 1045 (2006); doi:10.1016/j.inoche.2006.06.014.
T. Higashi, Program for Absorption Correction, Rigaku Corporation, Tokyo, Japan (1995).
SHELXTL, Version 5.1, Siemens Industrial Automation, Inc. (1997).
G.M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany (1997).
Y. Wang, G.X. Liu, Y.C. Chen, K.B. Wang and S.-G. Meng, Inorg. Chim. Acta, 363, 2668 (2010); doi:10.1016/j.ica.2010.03.076.
D.S. Li, Y.Y. Wang, X.J. Luan, P. Liu, C.H. Zhou, H.R. Ma and Q.Z. Shi, Eur. J. Inorg. Chem., 2005, 2678 (2005); doi:10.1002/ejic.200500088.
W. Shi, X.Y. Chen, B. Zhao, A. Yu, H.B. Song, P. Cheng, H.G. Wang, D.Z. Liao and S.P. Yan, Inorg. Chem., 45, 3949 (2006); doi:10.1021/ic051979y.