A Novel Mutually Perpendicular Bicyclo-Shape Tetranuclear Complex Constructed from 2,3-Dihydroxy butanedioic Acid with Pisces Mode

L. Jiang; B.Q. Yang; G.D. Feng

doi:10.14233/ajchem.2014.15791

Issue

Vol. 26 No. 9 (2014): Vol 26 Issue 9

Issue Published : April 28, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

A Novel Mutually Perpendicular Bicyclo-Shape Tetranuclear Complex Constructed from 2,3-Dihydroxy butanedioic Acid with Pisces Mode

https://doi.org/10.14233/ajchem.2014.15791

L. Jiang

College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, P.R. China ;Key Laboratory of Functional Coordination Compounds, Department of Chemistry and Chemical Engineering, Baoji University of Arts and Science, Baoji 721013, P.R. China

B.Q. Yang

College of Chemistry and Chemical Engineering, Shaanxi University of Science and Technology, Xi'an 710021, P.R. China

G.D. Feng

Key Laboratory of Functional Coordination Compounds, Department of Chemistry and Chemical Engineering, Baoji University of Arts and Science, Baoji 721013, P.R. China

Corresponding Author(s) : B.Q. Yang

ginger_jl@163.com; fengguodong00805@163.com

Asian Journal of Chemistry, Vol. 26 No. 9 (2014): Vol 26 Issue 9
Article Published : April 29, 2014

Abstract

A new complex [Ni₄(dhbd)₄·8H₂O]·13H₂O (1) (H₄dhbd = 2,3-dihydroxy butanedioic acid) has been synthesized and its structure (C₁₆H₁₆O₄₅Ni₄, Mr = 1163.13) was determined by single-crystal X-ray diffraction analysis. The crystal belongs to the monoclinic system, space group P_21/c with a = 13.700(5), b = 17.143(5), c = 18.599(5) Å, b = 96.786(5), V = 4338(2) Å³, Z = 4, Dc = 1.781 g/cm³, μ(MoK_a) = 1.839 mm^-1, F(000) = 2336, S = 1.025, the final R = 0.0524 and wR = 0.1390 for 9257 reflections with I > 2s(I). The centrosymmetric nickel complex contains a tetranuclear in which four distorted octahedral Ni(II) centers are bridged by the carboxylic oxygen atoms and the hydroxy oxygen atoms of the four 2,3-dihydroxy butanedioic acid with the Pisces mode, featuring a novel mutually perpendicular bicyclo structure. The complex units are further linked to form three-dimentional supramolecular structure via the hydrogen bonds between the coordinate water molecules and the plentiful free water molecules. The elemental analysis and optical properties for the complex have been studied.

Keywords

Synthesis Crystal structure Bicyclo structure Nickel(II) complex 2,3-Dihydroxybutanedioic Acid

Jiang, L., Yang, B., & Feng, G. (2014). A Novel Mutually Perpendicular Bicyclo-Shape Tetranuclear Complex Constructed from 2,3-Dihydroxy butanedioic Acid with Pisces Mode. Asian Journal of Chemistry, 26(9), 2667–2670. https://doi.org/10.14233/ajchem.2014.15791

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References

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References

B. Moulton and M.J. Zaworotko, Chem. Rev., 101, 1629 (2001); doi:10.1021/cr9900432.

M.W. Hosseini, Acc. Chem. Res., 38, 313 (2005); doi:10.1021/ar0401799.

A.Y. Robin and K.M. Fromm, Coord. Chem. Rev., 250, 2127 (2006); doi:10.1016/j.ccr.2006.02.013.

G.D. Feng, L. Jiang and Z.M. Su, Z. Anorg. Allg. Chem., 637, 2211 (2011); doi:10.1002/zaac.201100270.

N.L. Rosi, M. Eddaoudi, J. Kim, M. O’Keeffe and O.M. Yaghi, Angew. Chem. Int. Ed. Engl., 41, 284 (2002); doi:10.1002/1521-3773(20020118)41:2<284::AID-ANIE284>3.0.CO;2-M.

C. Serre, F. Millange, C. Thouvenot, N. Gardant, F. Pelle and G. Ferey, J. Mater. Chem., 14, 1540 (2004); doi:10.1039/b312425h.

Y. Cui, H.L. Ngo, P.S. White and W. Lin, Chem. Commun., 994 (2003); doi:10.1039/b211916a.

F. Fu, D.S. Li, J. Zhao and W.W. Dong, Chinese J. Struct. Chem., 28, 925 (2009).

F. Luo, Y.- Che and J.- Zheng, Inorg. Chem. Commun., 9, 1045 (2006); doi:10.1016/j.inoche.2006.06.014.

T. Higashi, Program for Absorption Correction, Rigaku Corporation, Tokyo, Japan (1995).

SHELXTL, Version 5.1, Siemens Industrial Automation, Inc. (1997).

G.M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structure, University of Göttingen, Germany (1997).

Y. Wang, G.X. Liu, Y.C. Chen, K.B. Wang and S.-G. Meng, Inorg. Chim. Acta, 363, 2668 (2010); doi:10.1016/j.ica.2010.03.076.

D.S. Li, Y.Y. Wang, X.J. Luan, P. Liu, C.H. Zhou, H.R. Ma and Q.Z. Shi, Eur. J. Inorg. Chem., 2005, 2678 (2005); doi:10.1002/ejic.200500088.

W. Shi, X.Y. Chen, B. Zhao, A. Yu, H.B. Song, P. Cheng, H.G. Wang, D.Z. Liao and S.P. Yan, Inorg. Chem., 45, 3949 (2006); doi:10.1021/ic051979y.

Issue

Vol. 26 No. 9 (2014): Vol 26 Issue 9

A Novel Mutually Perpendicular Bicyclo-Shape Tetranuclear Complex Constructed from 2,3-Dihydroxy butanedioic Acid with Pisces Mode

Corresponding Author(s) : B.Q. Yang

Abstract

Keywords

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