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Synthesis and Crystal Structure of N,N-Bis[(4-aminophenoxy)ethyl]benzene Sulfonamide
Corresponding Author(s) : Guang-Qi Jiang
Asian Journal of Chemistry,
Vol. 26 No. 10 (2014): Vol 26 Issue 10
Abstract
The reaction of diethanol amine and benzene sulfonyl chloride produced the benzene sulfonate intermediates, then it was nucleophilicly substituted by 4-nitrophenol and subsequently reduced by hydrazine hydrate in the presence of activated carbon and iron(III) chloride. A new binary aromatic amine, N,N-bis[(4-aminophenoxy)ethyl]benzene sulfonamide was prepared. The intermediates and the final product were structurally characterized by the means of IR, 1H NMR and single crystal X-ray diffraction analysis.
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- A.J. Kasparian, C. Savarin, A.M. Allgeier and S.D. Walker, J. Org. Chem., 76, 9841 (2011); doi:10.1021/jo2015664.
- M.A. Satam, R.K. Raut and N. Sekar, Dyes Pigments, 96, 92 (2013); doi:10.1016/j.dyepig.2012.07.019.
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- R.S. Downing, P.J. Kunkeler and H. van Bekkum, Catal. Today, 37, 121 (1997); doi:10.1016/S0920-5861(97)00005-9.
- P.L. Gkizis, M. Stratakis and I.N. Lykakis, Catal. Commun., 36, 48 (2013); doi:10.1016/j.catcom.2013.02.024.
- Y.Z. Wu, Chin. J. Chem. Ind. Eng., 31, 40 (2010).
- L. Wang, P. Li, Z.T. Wu, J.C. Yan, M. Wang and Y.B. Ding, Synthesis, 2001 (2003); doi:10.1055/s-2003-41021.
- B. Zhang, S. Chen and L. Chen, Chin. Liaoning Chem. Industry, 41, 460 (2012).
- K.Y. Cai, C.N. Liu, Y.M. Zhou and W. Yue, Chinese J. Appl. Chem., 26, 1080 (2009).
References
A.J. Kasparian, C. Savarin, A.M. Allgeier and S.D. Walker, J. Org. Chem., 76, 9841 (2011); doi:10.1021/jo2015664.
M.A. Satam, R.K. Raut and N. Sekar, Dyes Pigments, 96, 92 (2013); doi:10.1016/j.dyepig.2012.07.019.
T.S. Kang, S.K. Jin, J.E. Lee, S.W. Woo and J. Roh, J. Clin. Pharm. Ther., 34, 709 (2009); doi:10.1111/j.1365-2710.2009.01065.x.
R.S. Downing, P.J. Kunkeler and H. van Bekkum, Catal. Today, 37, 121 (1997); doi:10.1016/S0920-5861(97)00005-9.
P.L. Gkizis, M. Stratakis and I.N. Lykakis, Catal. Commun., 36, 48 (2013); doi:10.1016/j.catcom.2013.02.024.
Y.Z. Wu, Chin. J. Chem. Ind. Eng., 31, 40 (2010).
L. Wang, P. Li, Z.T. Wu, J.C. Yan, M. Wang and Y.B. Ding, Synthesis, 2001 (2003); doi:10.1055/s-2003-41021.
B. Zhang, S. Chen and L. Chen, Chin. Liaoning Chem. Industry, 41, 460 (2012).
K.Y. Cai, C.N. Liu, Y.M. Zhou and W. Yue, Chinese J. Appl. Chem., 26, 1080 (2009).