Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Preparation of H3PW12O40-Titania Composite Materials and Their Photocatalytic Activity Under Visible Light
Corresponding Author(s) : S.Z. Hu
Asian Journal of Chemistry,
Vol. 26 No. 10 (2014): Vol 26 Issue 10
Abstract
The H3PW12O40-titania composite materials were prepared by nonionic-surfactant templating strategy combined with hydrothermal treatment. X-ray diffraction, N2 adsorption, elemental analysis, UV-visible spectroscopy, photoluminescence and X-ray photoelectron spectroscopy were used to characterize the prepared composite materials. The results indicated that the addition of H3PW12O40 did not influence the crystallization of TiO2. Hybridization of Ti 3d orbit and W 5d orbit caused the decreased bandgap energies of H3PW12O40-titania composite materials, leading to the increased visible light absorption. The obtained catalyst exhibited outstanding photocatalytic activity and stability under visible light.
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References
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U.I. Gaya and A.H. Abdullah, J. Photochem. Photobiol. Photochem. Rev., 9, 1 (2008); doi:10.1016/j.jphotochemrev.2007.12.003.
S. Klosek and D. Raftery, J. Phys. Chem. B, 105, 2815 (2001); doi:10.1021/jp004295e.
H. Yamashita, M. Harada, J. Misaka, M. Takeuchi, K. Ikeue and M. Anpo, J. Photochem. Photobiol. Chem., 148, 257 (2002); doi:10.1016/S1010-6030(02)00051-5.
S.Z. Hu, F.Y. Li and Z.P. Fan, Bull. Korean Chem. Soc., 33, 199 (2012); doi:10.5012/bkcs.2012.33.1.199.
H.J. Sun, H.L. Liu, J. Ma, X.Y. Wang, B. Wang and L. Han, J. Hazard. Mater., 156, 552 (2008); doi:10.1016/j.jhazmat.2007.12.087.
Q. Shi, D. Yang, Z.Y. Jiang and J. Li, J. Mol. Catal. Enzym., 43, 44 (2006); doi:10.1016/j.molcatb.2006.06.005.
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A. Zaleska, J.W. Sobczak, E. Grabowska and J. Hupka, Appl. Catal. B, 78, 92 (2008); doi:10.1016/j.apcatb.2007.09.005.
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Y. Guo, C. Hu, S. Jiang, C. Guo, Y. Yang and E. Wang, Appl. Catal. B, 36, 9 (2002); doi:10.1016/S0926-3373(01)00260-0.
K. Li, Y. Guo, F. Ma, H. Li, L. Chen and Y. Guo, Catal. Commun., 11, 839 (2010); doi:10.1016/j.catcom.2010.03.004.
Y. Xie, L. Zhou and H. Huang, Appl. Catal. B, 76, 15 (2007); doi:10.1016/j.apcatb.2007.05.006.
G. Marcì, E. García-López, L. Palmisano, D. Carriazo, C. Martín and V. Rives, Appl. Catal. B, 90, 497 (2009); doi:10.1016/j.apcatb.2009.03.034.
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