Synthesis and Crystal Structure of Novel 4-6-connected Co(II) Coordination Polymers Constructed by Pyridinedicarboxylate and Imidazole-Containing Ligands

Guanglong Zou; Xuelin Wang; Tingting Li; Zhiqing Fang; Bing Xie

doi:10.14233/ajchem.2014.16986

Issue

Vol. 26 No. 10 (2014): Vol 26 Issue 10

Issue Published : May 10, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Crystal Structure of Novel 4-6-connected Co(II) Coordination Polymers Constructed by Pyridinedicarboxylate and Imidazole-Containing Ligands

https://doi.org/10.14233/ajchem.2014.16986

Guanglong Zou

School of Chemistry and Enviromental Science, Guizhou Minzu Univeristy, Guiyang 550025, P.R. China

Xuelin Wang

School of Science, Guizhou Minzu University, Guiyang 550025, P.R. China

Tingting Li

School of Chemistry and Enviromental Science, Guizhou Minzu Univeristy, Guiyang 550025, P.R. China

Zhiqing Fang

School of Chemistry and Enviromental Science, Guizhou Minzu Univeristy, Guiyang 550025, P.R. China

Bing Xie

School of Chemistry and Enviromental Science, Guizhou Minzu Univeristy, Guiyang 550025, P.R. China

Corresponding Author(s) : Guanglong Zou

scesgzmu@126.com

Asian Journal of Chemistry, Vol. 26 No. 10 (2014): Vol 26 Issue 10
Article Published : May 10, 2014

Abstract

A new coordination polymers {Co(2,3-PDC)(bib)_1.5]·3H₂O}_n (1) [2,3-PDC= 2,3-pyridine dicarboxylic acid and bib=1,4-bis(imidazol-1-yl)benzene] has been prepared by hydrothermal synthesis. Complex {Co(2,3-PDC)(bib)_1.5]·3H₂O}_n (1), is triclinic, space group P-1 with a = 9.666 (5) Å, b = 11.358 (5) Å, c = 13.671 (5) Å, a = 69.701 (5)°, b = 70.792 (5)°, g = 81.688 (5)°, V =1328.5 (10) Å³, Z = 2, Mr = 593.44, D_c = 1.484 g/cm³, F(000) = 612 and μ = 0.70 mm^-1. The final refinement gave R = 0.0533 and wR = 0.0584 for 5142 reflections with I > 2s(I). X-ray diffraction analysis reveals that complex 1 shows a (4,6)-connected three-dimensional (3D) structure with the point symbol (4⁴.6²).(4⁸.6⁷).

Keywords

Coordination polymer Co (II) Crystal structure Metal-organic framework

Zou, G., Wang, X., Li, T., Fang, Z., & Xie, B. (2014). Synthesis and Crystal Structure of Novel 4-6-connected Co(II) Coordination Polymers Constructed by Pyridinedicarboxylate and Imidazole-Containing Ligands. Asian Journal of Chemistry, 26(10), 3123–3124. https://doi.org/10.14233/ajchem.2014.16986

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References

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J.L.C. Rowsell and O.M. Yaghi, Angew. Chem. Int. Ed., 44, 4670 (2005); doi:10.1002/anie.200462786.

X.L. Wang, C. Qin, E.B. Wang, L. Xu, Z.M. Su and C.W. Hu, Angew. Chem. Int. Ed., 43, 5036 (2004); doi:10.1002/anie.200460758.

S. Kitagawa, R. Kitaura and S.I. Noro, Angew. Chem. Int. Ed., 43, 2334 (2004); doi:10.1002/anie.200300610.

M. Eddaoudi, J. Kim, N.L. Rosi, D.T. Vodak, J. Wachter, M. O'Keeffe and O.M. Yaghi, Science, 295, 469 (2002); doi:10.1126/science.1067208.

K. Sumida, S. Horike, S.S. Kaye, Z.R. Herm, W.L. Queen, C.M. Brown, F. Grandjean, G.J. Long, A. Dailly and J.R. Long, Chem. Sci., 1, 184 (2010); doi:10.1039/c0sc00179a.

S.-C. Xie, Asian J. Chem., 25, 3529 (2013); doi:10.14233/ajchem.2013.13816A.

Z.Q. Jiang, Asian J. Chem., 25, 2353 (2013); doi:10.14233/ajchem.2013.13746D.

Y.-P. Hu, C.-P. Tan, S.-F. Wang and X.-B. Meng, Asian J. Chem., 25, 1137 (2013); doi:10.14233/ajchem.2013.13743.

K. Biradha, C. Seward and M.J. Zaworotko, Angew. Chem. Int. Ed., 38, 492 (1999); doi:10.1002/(SICI)1521-3773(19990215)38:4<492::AID-ANIE492>3.0.CO;2-#.

Y. Akkaya, S. Akyuz and T. Akyuz, Asian J. Chem., 25, 9185 (2013); doi:10.14233/ajchem.2013.15119.

S.H. Cho, B.Q. Ma, S.T. Nguyen, J.T. Hupp and T.E. Albrecht-Schmitt, Chem. Commun., 2563 (2006); doi:10.1039/b600408c.

K.S. Suslick, P. Bhyrappa, J.H. Chou, M.E. Kosal, S. Nakagaki, D.W. Smithenry and S.R. Wilson, Acc. Chem. Res., 38, 283 (2005); doi:10.1021/ar040173j.

M.D. Allendorf, C.A. Bauer, R.K. Bhakta and R.J.T. Houk, Chem. Soc. Rev., 38, 1330 (2009); doi:10.1039/b802352m.

E.Y. Lee, S.Y. Jang and M.P. Suh, J. Am. Chem. Soc., 127, 6374 (2005); doi:10.1021/ja043756x.

J. Yang, G.D. Li, J.J. Cao, Q. Yue, G.H. Li and J.S. Chen, Eur. Chem. J., 13, 3248 (2007); doi:10.1002/chem.200600730.

C. Janiak and J.K. Vieth, New J. Chem., 34, 2366 (2010); doi:10.1039/c0nj00275e.

A.X.S. Bruker, SAINT Software Reference Manual, Madison, WI (1998).

G.M. Sheldrick, SHELXTL NT Version 5.1, Program for Solution and Refinement of Crystal Structures, University of Göttingen, Germany (1997).

Issue

Vol. 26 No. 10 (2014): Vol 26 Issue 10

Synthesis and Crystal Structure of Novel 4-6-connected Co(II) Coordination Polymers Constructed by Pyridinedicarboxylate and Imidazole-Containing Ligands

Corresponding Author(s) : Guanglong Zou

Abstract

Keywords

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