Isotherm and Kinetic Modeling of Pb(II) and Cu(II) Uptake by Annona muricata L. Seeds

Meilia Innes Kurniawan; Zulfi Abdullah; Ayu Rahmadani; Rahmiana Zein; Edison Munaf

doi:10.14233/ajchem.2014.16515

Issue

Vol. 26 No. 12 (2014): Vol 26 Issue 12

Issue Published : June 5, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Isotherm and Kinetic Modeling of Pb(II) and Cu(II) Uptake by Annona muricata L. Seeds

https://doi.org/10.14233/ajchem.2014.16515

Meilia Innes Kurniawan

Laboratory of Analytical Environmental Chemistry, Faculty of Mathematics and Natural Sciences, Andalas University, Padang 25163, Indonesia

Zulfi Abdullah

Laboratory of Analytical Environmental Chemistry, Faculty of Mathematics and Natural Sciences, Andalas University, Padang 25163, Indonesia

Ayu Rahmadani

Laboratory of Analytical Environmental Chemistry, Faculty of Mathematics and Natural Sciences, Andalas University, Padang 25163, Indonesia

Rahmiana Zein

Laboratory of Analytical Environmental Chemistry, Faculty of Mathematics and Natural Sciences, Andalas University, Padang 25163, Indonesia

Edison Munaf

Laboratory of Analytical Environmental Chemistry, Faculty of Mathematics and Natural Sciences, Andalas University, Padang 25163, Indonesia

Corresponding Author(s) : Edison Munaf

emunaf@fmipa.unand.ac.id

Asian Journal of Chemistry, Vol. 26 No. 12 (2014): Vol 26 Issue 12
Article Published : June 5, 2014

Abstract

Isotherm and kinetic modeling of Pb(II) and Cu(II) uptake by Annona muricata L. seeds has been investigated. Batch adsorption studies were conducted to examine their optimum condition. For the biosorption of Pb(II), the optimum pH solution, contact time and stirring speed were 3, 45 min and 150 rpm, respectively. Those values for Cu(II) ions were 4, 60 min and 100 rpm, respectively. Data obtained from these studies fitted well with pseudo second-order and Freundlich isotherm model. The maximum capacity for Pb(II) and Cu(II) ions were 5.585 and 4.1685 mg/g, respectively. The biosorption capacity decreased as the dosage of biomass increased. FTIR spectra analysis might revealed that carboxyl and hydroxyl groups were dominant in the process of metal ions uptake. Biosorption of binary solution did not influence the adsorption capacity of the leading ion (its optimum condition was used in binary solution) onto Annona muricata L. seed.

Keywords

Isotherm and kinetic modeling Annona muricata L. seeds Toxic metals FTIR

Innes Kurniawan, M., Abdullah, Z., Rahmadani, A., Zein, R., & Munaf, E. (2014). Isotherm and Kinetic Modeling of Pb(II) and Cu(II) Uptake by Annona muricata L. Seeds. Asian Journal of Chemistry, 26(12), 3588–3594. https://doi.org/10.14233/ajchem.2014.16515

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Y. Liu and Y.J. Liu, Sep. Purif. Technol., 61, 229 (2008); doi:10.1016/j.seppur.2007.10.002.

A. Demirbas, J. Hazard. Mater., 157, 220 (2008); doi:10.1016/j.jhazmat.2008.01.024.

J. Wang and C. Chen, Biotechnol. Adv., 27, 195 (2009); doi:10.1016/j.biotechadv.2008.11.002.

C.J. Tien, Process Biochem., 38, 605 (2002); doi:10.1016/S0032-9592(02)00183-8.

R. Zein, R. Suhaili, F. Earnestly, Indrawati and E. Munaf, J. Hazard. Mater., 181, 52 (2010); doi:10.1016/j.jhazmat.2010.04.076.

L.M. Andrade, J.A.C. Sanchez, D.G. Ramirez, L. Reyes, A.R. Chumacero and B.R. Trejo, Sci. Res. Essays, 6, 3089 (2011).

D.L.M. Stojanovic, A. Zarubica, M. Purenovic, D. Bojic, T. Andjelkovic and L.J. Aleksandar, Water SA, 37, 303 (2011).

T.A. Oyedepo, Sci. J. Pure Appl. Chem., 10, 1 (2011).

P.L. Homagai, H. Paudyal and K.N. Ghimire, J. Nepal Chem. Soc., 23, 102 (2008).

A.A. Suhaimi, M.A.A. Samah and S.A. Aziz, Int. J. Environmental Protection, 3, 44 (2013).

V.K. Gupta, D. Mohan and S. Sharma, Sep. Sci. Technol., 33, 1331 (1998); doi:10.1080/01496399808544986.

M.E. Argun, S. Dursun, C. Ozdemir and M. Karatas, J. Hazard. Mater., 141, 77 (2007); doi:10.1016/j.jhazmat.2006.06.095.

Q.J.M. Slaiman, C.K. Haweel and Y.R. Abdulmajeed, Iraqi J. Chem. Petrol. Eng., 11, 23 (2010).

R. Marandi, F.D. Ardejani and H.A. Afshar, Int. J. Mining Environ. Issues, 1, 9 (2010).

Y. Nuhoglu and E. Oguz, Process Biochem., 38, 1627 (2003); doi:10.1016/S0032-9592(03)00055-4.

D.S.S.R. Raju, V.N. Rao, P.R. Prasad and N.C. Babu, Int. J. Eng. Sci. Adv. Technol., 2, 1577 (2012).

R.B. Ljupkovic, J. Mitrovic, M. Radovic, M. Kostic, D. Bojic, D.L.M. Stojanovic and A.L. Bojic, Biologica Nyssaana, 2, 85 (2011).

F. Ekmekyapar, A. Aslan, Y.K. Bayhan and A. Cakici, Int. J. Environ. Res., 6, 417 (2012).

X.J. Dong, J. Environ. Biol., 27, 639 (2006).

D.S.S.R. Raju, G.A.R. Kiran and V.N. Rao, Int. J. Emerg. Trends Eng. Dev., 1, 273 (2013).

G. Cimino, A. Paserini and G. Toscano, Water Res., 34, 2955 (2000); doi:10.1016/S0043-1354(00)00048-8.

L.B. Khalil, B.S. Girgis and T.A.M. Tawfik, J. Chem. Technol. Biotechnol., 76, 1132 (2001); doi:10.1002/jctb.481.

N. Meunier, J. Laroulandie, J.F. Blais and R.D. Tyagi, Bioresour. Technol., 90, 255 (2003); doi:10.1016/S0960-8524(03)00129-9.

M.E. Argun, S. Dursun, C. Ozdemir and M. Karatas, J. Hazard. Mater., 141, 77 (2007); doi:10.1016/j.jhazmat.2006.06.095.

S. Cay, A. Uyanik and A. Ozasik, Sep. Purif. Technol., 38, 273 (2004); doi:10.1016/j.seppur.2003.12.003.

Issue

Vol. 26 No. 12 (2014): Vol 26 Issue 12

Isotherm and Kinetic Modeling of Pb(II) and Cu(II) Uptake by Annona muricata L. Seeds

Corresponding Author(s) : Edison Munaf

Abstract

Keywords

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