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Adsorption and Desorption Properties of Coalbed Methane on SBA-15
Corresponding Author(s) : Zhenghe Liu
Asian Journal of Chemistry,
Vol. 26 No. 12 (2014): Vol 26 Issue 12
Abstract
The adsorption and desorption properties of coalbed methane on SBA-15 and activated carbon (AC) with the same process were investigated. For the three adsorbents, the adsorption capacity to coalbed methane is the following sequence, activated carbon > SBA-15. The results showed that coalbed methane desorbed from the surface of SBA-15 is easily compared with the other materials. However activated carbon is easier than both of them. Both of adsorption capacity and adsorption strength of SBA-15 sample to coalbed methane are lower than the other two adsorbents, most likely due to the pore diameter of the SBA-15 sample is larger to the molecular diameter of methane. However SBA-15 sample has a larger pore size and specific surface area relative to conventional materials sample, which result in a large value of adsorption capacity of modified SBA-15 sample to coalbed methane. In addition, although the adsorption capacity of SBA-15 sample to coalbed methane is lower in contrast to activated carbon, modified SBA-15 sample is easy to regenerate and has a short time of desorption. Hence, SBA-15 sample, as an adsorbent, is a good choice for the condition of low concentration of coalbed methane.
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- L.H. Nie, S.P. Xu, Y.M. Su and S.Q. Liu, Chem. Ind. Eng. Prog., 27, 1505 (2008).
- J. Xn, W.S. Wei and X.J. Bao, Chin. J. Chem. Eng., 10, 56 (2002).
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- R.P. Marathe, S. Farooq and M.P. Srinivasan, Langmuir, 21, 4532 (2005); doi:10.1021/la046938d.
- D. Das, V. Gaur and N. Verma, Carbon, 42, 2949 (2004); doi:10.1016/j.carbon.2004.07.008.
- W.B. Li and H. Gong, Acta Phys. Chim. Sin., 26, 885 (2010); doi:10.3866/PKU.WHXB20100436.
- A. Kumar, J. Dewulf and H. Van Langenhove, Chem. Eng. J., 136, 82 (2008); doi:10.1016/j.cej.2007.06.006.
- S. Mudliar, B. Giri, K. Padoley, D. Satpute, R. Dixit, P. Bhatt, R. Pandey, A. Juwarkar and A. Vaidya, J. Environ. Manage., 91, 1039 (2010); doi:10.1016/j.jenvman.2010.01.006.
- K. Demeestere, J. Dewulf and H. Van Langenhove, Crit. Rev. Environ. Sci. Technol., 37, 489 (2007); doi:10.1080/10643380600966467.
- J.W. Lee, W.G. Shim and H. Moon, Micropor. Mesopor. Mater., 73, 109 (2004); doi:10.1016/j.micromeso.2004.04.020.
- W. Makowski and P. Kustrowski, Micropor. Mesopor. Mater., 102, 283 (2007); doi:10.1016/j.micromeso.2007.01.009.
- I. Glaznev, I. Ponomarenko, S. Kirik and Y. Aristov, Int. J. Refrig., 34, 1244 (2011); doi:10.1016/j.ijrefrig.2011.02.007.
- W. Rudziński, J. Narkiewicz-Michałek, P. Szabelski and A.S.T. Chiang, Langmuir, 13, 1095 (1997); doi:10.1021/la960254r.
- S. Brosillon, M.H. Manero and J.N. Foussard, Environ. Sci. Technol., 35, 3571 (2001); doi:10.1021/es010017x.
- S.J. Bhadra and S. Farooq, Ind. Eng. Chem. Res., 50, 14030 (2011); doi:10.1021/ie201237x.
- B. Majumdar, S.J. Bhadra, R.P. Marathe and S. Farooq, Ind. Eng. Chem. Res., 50, 3021 (2011); doi:10.1021/ie1014124.
- R. Serna-Guerrero and A. Sayari, Environ. Sci. Technol., 41, 4761 (2007); doi:10.1021/es0627996.
References
L.H. Nie, S.P. Xu, Y.M. Su and S.Q. Liu, Chem. Ind. Eng. Prog., 27, 1505 (2008).
J. Xn, W.S. Wei and X.J. Bao, Chin. J. Chem. Eng., 10, 56 (2002).
J.R. Odum, T.P.W. Jungkamp, R.J. Griffin, H.J.L. Forstner, R.C. Flagan and J.H. Seinfeld, Environ. Sci. Technol., 31, 1890 (1997); doi:10.1021/es960535l.
R.P. Marathe, S. Farooq and M.P. Srinivasan, Langmuir, 21, 4532 (2005); doi:10.1021/la046938d.
D. Das, V. Gaur and N. Verma, Carbon, 42, 2949 (2004); doi:10.1016/j.carbon.2004.07.008.
W.B. Li and H. Gong, Acta Phys. Chim. Sin., 26, 885 (2010); doi:10.3866/PKU.WHXB20100436.
A. Kumar, J. Dewulf and H. Van Langenhove, Chem. Eng. J., 136, 82 (2008); doi:10.1016/j.cej.2007.06.006.
S. Mudliar, B. Giri, K. Padoley, D. Satpute, R. Dixit, P. Bhatt, R. Pandey, A. Juwarkar and A. Vaidya, J. Environ. Manage., 91, 1039 (2010); doi:10.1016/j.jenvman.2010.01.006.
K. Demeestere, J. Dewulf and H. Van Langenhove, Crit. Rev. Environ. Sci. Technol., 37, 489 (2007); doi:10.1080/10643380600966467.
J.W. Lee, W.G. Shim and H. Moon, Micropor. Mesopor. Mater., 73, 109 (2004); doi:10.1016/j.micromeso.2004.04.020.
W. Makowski and P. Kustrowski, Micropor. Mesopor. Mater., 102, 283 (2007); doi:10.1016/j.micromeso.2007.01.009.
I. Glaznev, I. Ponomarenko, S. Kirik and Y. Aristov, Int. J. Refrig., 34, 1244 (2011); doi:10.1016/j.ijrefrig.2011.02.007.
W. Rudziński, J. Narkiewicz-Michałek, P. Szabelski and A.S.T. Chiang, Langmuir, 13, 1095 (1997); doi:10.1021/la960254r.
S. Brosillon, M.H. Manero and J.N. Foussard, Environ. Sci. Technol., 35, 3571 (2001); doi:10.1021/es010017x.
S.J. Bhadra and S. Farooq, Ind. Eng. Chem. Res., 50, 14030 (2011); doi:10.1021/ie201237x.
B. Majumdar, S.J. Bhadra, R.P. Marathe and S. Farooq, Ind. Eng. Chem. Res., 50, 3021 (2011); doi:10.1021/ie1014124.
R. Serna-Guerrero and A. Sayari, Environ. Sci. Technol., 41, 4761 (2007); doi:10.1021/es0627996.