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Vol. 26 No. 12 (2014): Vol 26 Issue 12

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Synthesis, Characterization, Catalytic Applications and Optical Sensing Properties of Palladium Complexes Containing Tetradentate Schiff Bases

https://doi.org/10.14233/ajchem.2014.16505
P. Köse Yaman
The Graduate School of Natural and Applied Sciences, Chemistry, Dokuz Eylul University, Buca 35160, Izmir, Turkey
E. Subasi
Department of Chemistry, Faculty of Science, Dokuz Eylul University, Buca-Tinaztepe 35160, Izmir, Turkey
H. Temel
Department of Chemistry, Faculty of Education, Dicle University, 21280 Diyarbakir, Turkey
O. Öter
Department of Chemistry, Faculty of Science, Dokuz Eylul University, Buca-Tinaztepe 35160, Izmir, Turkey
E. Çelik
Center for Fabrication and Application of Electronic Materials (EMUM), University of Dokuz Eylul, 35160 Tinaztepe, Izmir, Turkey

Corresponding Author(s) : P. Köse Yaman

pelin.kose@deu.edu.tr

Asian Journal of Chemistry, Vol. 26 No. 12 (2014): Vol 26 Issue 12

Abstract

In this study, the synthesis, spectroscopic and catalytic properties of PdLn (n = 1-6) complexes with tetradentate -ONNO- and -SNNS- type Schiff base ligands LnH2 (n = 1-6) were investigated. The PdLn (n = 1-6) complexes were synthesized by the thermal reactions of the Schiff bases and Pd(OAc)2 in acetonitrile and characterized by elemental analysis, FT-IR, 1H NMR, UV-visible and TGA/DTG. The spectroscopic studies suggest that all of the ligands are coordinated to the central metal as a tetradentate ligand coordinating via the central azomethine nitrogens (C=N) and phenolic oxygen/sulfur atoms. On the palladium-catalyzed Suzuki cross-coupling reactions employing PdLn (n = 1-6) complexes toward a various substituted arylbromides and boronic acids were pursued. The conversions were obtained and yields with different arylbromides were calculated and discussed. All the complexes were thermally stable and were not sensitive to air or the moisture. The complexes were easily prepared from low cost precursors that could be used as versatile and catalysts for different C-C coupling reactions (Suzuki-Miyaura reactions). Moreover steady state fluorescence emission and excitation spectra were measured. These studies have been shown that PdL2 and PdL3 dyes exhibited high fluorescence intensity and selective and efficient response to cobalt ions over other metal ions in buffered solutions.

Keywords

Palladium(II) Schiff bases Suzuki-Miyaura reaction -ONNO- and -SNNS- type Schiff bases
Köse Yaman, P., Subasi, E., Temel, H., Öter, O., & Çelik, E. (2014). Synthesis, Characterization, Catalytic Applications and Optical Sensing Properties of Palladium Complexes Containing Tetradentate Schiff Bases. Asian Journal of Chemistry, 26(12), 3581–3587. https://doi.org/10.14233/ajchem.2014.16505
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