Adsorption of Isonicotinamide on Loughlinite (Natural Na-Sepiolite): An FT-IR Spectroscopic Study

Sevim Akyuz; Tanil Akyuz

doi:10.14233/ajchem.2014.16060

Issue

Vol. 26 No. 14 (2014): Vol 26 Issue 14

Issue Published : July 5, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Adsorption of Isonicotinamide on Loughlinite (Natural Na-Sepiolite): An FT-IR Spectroscopic Study

https://doi.org/10.14233/ajchem.2014.16060

Sevim Akyuz

Istanbul Kultur University, Science and Letters Faculty, Physics Department, Atakoy Campus, 34156 Bakirkoy, Istanbul, Turkey

Tanil Akyuz

Istanbul Kultur University, Science and Letters Faculty, Physics Department, Atakoy Campus, 34156 Bakirkoy, Istanbul, Turkey

Corresponding Author(s) : Sevim Akyuz

s.akyuz@iku.edu.tr

Asian Journal of Chemistry, Vol. 26 No. 14 (2014): Vol 26 Issue 14
Article Published : July 5, 2014

Abstract

In this study adsorption of isonicotinamide on loughlinite (Na-sepiolite) has been investigated by FT-IR spectroscopy. The adsorption of isonicotinamide showed a considerable alteration on both Si-OH stretching and deformation peaks of loughlinite structure. Spectroscopic results indicate that adsorbed isonicotinamide molecules onto loughlinite are coordinated to surface silanol groups and/or Lewis acidic centers by H-bonding interaction through pyridine ring nitrogen lone pairs. The amino nitrogen is found to be relatively in active to adsorbing sites.

Keywords

Adsorption Clays IR spectroscopy Isonicotinamide Loughlinite Sepiolite

Akyuz, S., & Akyuz, T. (2014). Adsorption of Isonicotinamide on Loughlinite (Natural Na-Sepiolite): An FT-IR Spectroscopic Study. Asian Journal of Chemistry, 26(14), 4197–4200. https://doi.org/10.14233/ajchem.2014.16060

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References

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S. Akyuz and T. Akyuz, Vib. Spectrosc., 42, 387 (2006); doi:10.1016/j.vibspec.2006.05.032.
S. Akyuz and T. Akyuz, Asian J. Chem., 20, 3767 (2008).
S. Akyuz and T. Akyuz, Asian J. Chem., 22, 546 (2010).
T. Akyuz and S. Akyuz, Asian J. Chem., 23, 3211 (2011).
M. Ogawa, T. Hashizume, K. Kuroda and C. Kato, Inorg. Chem., 30, 584 (1991); doi:10.1021/ic00003a050.
N. Khaorapapong, K. Kuroda, T. Hashizume and M. Ogawa, Appl. Clay Sci., 19, 69 (2001); doi:10.1016/S0169-1317(01)00055-2.
E. Akalin and S. Akyuz, J. Mol. Struct., 482-483, 175 (1999); doi:10.1016/S0022-2860(98)00780-7.
E. Akalin and S. Akyuz, J. Mol. Struct., 565-564, 579 (2001); doi:10.1016/S0022-2860(00)00802-4.
T.J. Dines, L.D. MacGregor and C.H. Rochester, Spectrochim. Acta A, 59, 3205 (2003); doi:10.1016/S1386-1425(03)00139-2.
A. Borba, A. Gómez-Zavaglia and R. Fausto, J. Phys. Chem., 112, 45 (2008); doi:10.1021/jp0765547.
S. Yurdakul and A. Atac, Spectrosc. Lett., 37, 33 (2004); doi:10.1081/SL-120028421.
E. Akalin, A. Yilmaz and S. Akyuz, J. Mol. Struct., 744-747, 881 (2005); doi:10.1016/j.molstruc.2004.11.077.
E. Akalin, S. Akyuz and T. Akyuz, Asian J. Chem., 22, 4111 (2010).
S. Akyuz and T. Akyuz, J. Mol. Struct., 744-747, 47 (2005); doi:10.1016/j.molstruc.2004.10.024.

References

R.A. Olsen, L. Liu, N. Ghaderi, A. Johns, M.E. Hatcher and L.J. Mueller, J. Am. Chem. Soc., 125, 10125 (2003); doi:10.1021/ja028751j.

R.K. Murray, D.K. Granner, P.A. Mayes and V.W. Rodwell, Harper's Biochemistry, Prentice Hall International Inc., London, edn 22, p. 332 (1990).

S. Yurdakul, A. Ataç, E. Sahin and S. Ide, Vib. Spectrosc., 31, 41 (2003); doi:10.1016/S0924-2031(02)00066-8.

J.L. Castro, J.F. Arenas, M.R. Lopez-Ramirez, J. Soto and J.C. Otero, J. Colloid Interf. Sci., 396, 95 (2013); doi:10.1016/j.jcis.2013.01.050.

J.J. Fahey, M. Ross and J.M. Axelrod, Am. Mineral., 45, 270 (1960).

S. Kadir, H. Bas and Z. Karakas, Can. Mineral., 40, 1091 (2002); doi:10.2113/gscanmin.40.4.1091.

K. Brauner and A. Preisinger, Tschermaks Mineral. Petrogr. Mitt., 6, 120 (1956); doi:10.1007/BF01128033.

J.M. Serratosa, In Proceedings of International Clay Conference, 1978, edited by M.M. Mortland and V.C. Farmer, Elsevier, Amsterdam, p. 99 (1979).

S. Akyuz and T. Akyuz, Vib. Spectrosc., 42, 387 (2006); doi:10.1016/j.vibspec.2006.05.032.

S. Akyuz and T. Akyuz, Asian J. Chem., 20, 3767 (2008).

S. Akyuz and T. Akyuz, Asian J. Chem., 22, 546 (2010).

T. Akyuz and S. Akyuz, Asian J. Chem., 23, 3211 (2011).

M. Ogawa, T. Hashizume, K. Kuroda and C. Kato, Inorg. Chem., 30, 584 (1991); doi:10.1021/ic00003a050.

N. Khaorapapong, K. Kuroda, T. Hashizume and M. Ogawa, Appl. Clay Sci., 19, 69 (2001); doi:10.1016/S0169-1317(01)00055-2.

E. Akalin and S. Akyuz, J. Mol. Struct., 482-483, 175 (1999); doi:10.1016/S0022-2860(98)00780-7.

E. Akalin and S. Akyuz, J. Mol. Struct., 565-564, 579 (2001); doi:10.1016/S0022-2860(00)00802-4.

T.J. Dines, L.D. MacGregor and C.H. Rochester, Spectrochim. Acta A, 59, 3205 (2003); doi:10.1016/S1386-1425(03)00139-2.

A. Borba, A. Gómez-Zavaglia and R. Fausto, J. Phys. Chem., 112, 45 (2008); doi:10.1021/jp0765547.

S. Yurdakul and A. Atac, Spectrosc. Lett., 37, 33 (2004); doi:10.1081/SL-120028421.

E. Akalin, A. Yilmaz and S. Akyuz, J. Mol. Struct., 744-747, 881 (2005); doi:10.1016/j.molstruc.2004.11.077.

E. Akalin, S. Akyuz and T. Akyuz, Asian J. Chem., 22, 4111 (2010).

S. Akyuz and T. Akyuz, J. Mol. Struct., 744-747, 47 (2005); doi:10.1016/j.molstruc.2004.10.024.

Issue

Vol. 26 No. 14 (2014): Vol 26 Issue 14

Adsorption of Isonicotinamide on Loughlinite (Natural Na-Sepiolite): An FT-IR Spectroscopic Study

Corresponding Author(s) : Sevim Akyuz

Abstract

Keywords

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