J- and H-Aggregation of 5,10,15,20-Tetrakis-(4-sulfonatophenyl)porphyrin within Stimuli Responsive Complex Micelles via Electrostatic Interaction

Qingyuan Yu; Chenglin Wu; Fang Wang

doi:10.14233/ajchem.2014.16094

Issue

Vol. 26 No. 14 (2014): Vol 26 Issue 14

Issue Published : July 5, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

J- and H-Aggregation of 5,10,15,20-Tetrakis-(4-sulfonatophenyl)porphyrin within Stimuli Responsive Complex Micelles via Electrostatic Interaction

https://doi.org/10.14233/ajchem.2014.16094

Qingyuan Yu

First Middle School of Taizhou City, Taizhou 317000, Zhejiang Province, P.R. China

Chenglin Wu

School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 317000, Zhejiang Province, P.R. China

Fang Wang

School of Pharmaceutical and Chemical Engineering, Taizhou University, Taizhou 317000, Zhejiang Province, P.R. China

Corresponding Author(s) : Chenglin Wu

clwu@tzc.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 14 (2014): Vol 26 Issue 14
Article Published : July 5, 2014

Abstract

In aqueous solution, complex micelles were prepared by micellization of 5,10,15,20-tetrakis-(4-sulfonatophenyl)porphyrin (TPPS) and poly(2-(dimethylamino)ethyl methacrylate)-b-poly(N-isopropylacrylamide) (PDMAEMA-b-PNIPAM) at pH < 7 based on electrostatic interaction. The resultant complex micelles had a core-shell structure with complex TPPS/PDMAEMA as a core and PNIPAM as a shell. The anionic TPPS in the micellar core formed J-aggregates (pH 1.5) and H-aggregates (pH 3 - pH 7) due to electrostatic interaction with positive charged PDMAEMA. When the temperature was above the lower critical solution temperature (LCST) of PNIPAM, the thermo-responsive block collapsed on the complex micellar core, while the aggregation form of TPPS remained unchanged.

Keywords

Core-shell J-Aggregates H-Aggregates 5,10,15,20-tetrakis-(4-Sulfonatophenyl)porphyrin

Yu, Q., Wu, C., & Wang, F. (2014). J- and H-Aggregation of 5,10,15,20-Tetrakis-(4-sulfonatophenyl)porphyrin within Stimuli Responsive Complex Micelles via Electrostatic Interaction. Asian Journal of Chemistry, 26(14), 4269–4272. https://doi.org/10.14233/ajchem.2014.16094

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References

C.K. Ober, S.Z.D. Cheng, P.T. Hammond, M. Muthukumar, E. Reichmanis, K.L. Wooley and T.P. Lodge, Macromolecules, 42, 465 (2009); doi:10.1021/ma802463z.
F. Bai, Z. Sun, H. Wu, R.E. Haddad, E.N. Coker, J.Y. Huang, M.A. Rodriguez and H. Fan, Nano Lett., 11, 5196 (2011); doi:10.1021/nl203598n.
N.C. Maiti, S. Mazumdar and N. Periasamy, J. Phys. Chem. B, 102, 1528 (1998); doi:10.1021/jp9723372.
S.G. Jiang and M.H. Liu, J. Phys. Chem. B, 108, 2880 (2004); doi:10.1021/jp036886l.
A.S.R. Koti and N. Periasamy, Chem. Mater., 15, 369 (2003); doi:10.1021/cm025664h.
J.F. Gohy, Adv. Polym. Sci., 190, 65 (2005); doi:10.1007/12_048.
J. Rao, Z. Luo, Z. Ge, H. Liu and S. Liu, Biomacromolecules, 8, 3871 (2007); doi:10.1021/bm700830b.
L. Zhao, R. Ma, J. Li, Y. Li, Y. An and L. Shi, Biomacromolecules, 9, 2601 (2008); doi:10.1021/bm8004808.
L. Zhao, R. Ma, J. Li, Y. Li, Y. An and L. Shi, Biomacromolecules, 10, 3343 (2009); doi:10.1021/bm9010408.
C. Wu, A. Ying, S. Ren and J. Xu, Asian J. Chem., 25, 3806 (2013); doi:10.14233/ajchem.2013.13792.
E.B. Fleischer, J.M. Palmer, T.S. Srivastava and A. Chatterjee, J. Am. Chem. Soc., 93, 3162 (1971); doi:10.1021/ja00742a012.
G. De Luca, A. Romeo and L.M. Scolaro, J. Phys. Chem. B, 110, 7309 (2006); doi:10.1021/jp0530348.
N.C. Maiti, S. Mazumdar and N. Periasamy, J. Porphy. Phthalocyanines, 2, 369 (1998); doi:10.1002/(SICI)1099-1409(199807/10)2:4/5<369::AID-JPP92>3.0.CO;2-3.
A.S.R. Koti, J. Taneja and N. Periasamy, Chem. Phys. Lett., 375, 171 (2003); doi:10.1016/S0009-2614(03)00866-2.
M.A. Castriciano, A. Romeo, V. Villari, N. Angelini, N. Micali and L.M. Scolaro, J. Phys. Chem. B, 109, 12086 (2005); doi:10.1021/jp0508960.

References

C.K. Ober, S.Z.D. Cheng, P.T. Hammond, M. Muthukumar, E. Reichmanis, K.L. Wooley and T.P. Lodge, Macromolecules, 42, 465 (2009); doi:10.1021/ma802463z.

F. Bai, Z. Sun, H. Wu, R.E. Haddad, E.N. Coker, J.Y. Huang, M.A. Rodriguez and H. Fan, Nano Lett., 11, 5196 (2011); doi:10.1021/nl203598n.

N.C. Maiti, S. Mazumdar and N. Periasamy, J. Phys. Chem. B, 102, 1528 (1998); doi:10.1021/jp9723372.

S.G. Jiang and M.H. Liu, J. Phys. Chem. B, 108, 2880 (2004); doi:10.1021/jp036886l.

A.S.R. Koti and N. Periasamy, Chem. Mater., 15, 369 (2003); doi:10.1021/cm025664h.

J.F. Gohy, Adv. Polym. Sci., 190, 65 (2005); doi:10.1007/12_048.

J. Rao, Z. Luo, Z. Ge, H. Liu and S. Liu, Biomacromolecules, 8, 3871 (2007); doi:10.1021/bm700830b.

L. Zhao, R. Ma, J. Li, Y. Li, Y. An and L. Shi, Biomacromolecules, 9, 2601 (2008); doi:10.1021/bm8004808.

L. Zhao, R. Ma, J. Li, Y. Li, Y. An and L. Shi, Biomacromolecules, 10, 3343 (2009); doi:10.1021/bm9010408.

C. Wu, A. Ying, S. Ren and J. Xu, Asian J. Chem., 25, 3806 (2013); doi:10.14233/ajchem.2013.13792.

E.B. Fleischer, J.M. Palmer, T.S. Srivastava and A. Chatterjee, J. Am. Chem. Soc., 93, 3162 (1971); doi:10.1021/ja00742a012.

G. De Luca, A. Romeo and L.M. Scolaro, J. Phys. Chem. B, 110, 7309 (2006); doi:10.1021/jp0530348.

N.C. Maiti, S. Mazumdar and N. Periasamy, J. Porphy. Phthalocyanines, 2, 369 (1998); doi:10.1002/(SICI)1099-1409(199807/10)2:4/5<369::AID-JPP92>3.0.CO;2-3.

A.S.R. Koti, J. Taneja and N. Periasamy, Chem. Phys. Lett., 375, 171 (2003); doi:10.1016/S0009-2614(03)00866-2.

M.A. Castriciano, A. Romeo, V. Villari, N. Angelini, N. Micali and L.M. Scolaro, J. Phys. Chem. B, 109, 12086 (2005); doi:10.1021/jp0508960.

Issue

Vol. 26 No. 14 (2014): Vol 26 Issue 14

J- and H-Aggregation of 5,10,15,20-Tetrakis-(4-sulfonatophenyl)porphyrin within Stimuli Responsive Complex Micelles via Electrostatic Interaction

Corresponding Author(s) : Chenglin Wu

Abstract

Keywords

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