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Synthesis and Properties of Lauric Acid-2-hydroxy-3-propane Sulfonic Acid Sodium Salt
Corresponding Author(s) : Yulan Hao
Asian Journal of Chemistry,
Vol. 26 No. 14 (2014): Vol 26 Issue 14
Abstract
The lauric acid-2-hydroxy-3-propane sulfonic acid sodium salt was synthesized by using sodium bisulfite, epichlorohydrin, sodium phosphate and lauric acid. The influence factors on reaction temperature, reaction time, the amount of catalyst and reactant molar ratio to the yield were investigated. The favorable conditions of synthesizing were determined:epichlorohydrin was added into the solution of sodium bisulfite of 85 °C, stirring for 2 h and left for 1.5 h. 3-Chloro-2-hydroxy-propane sulfonic acid sodium was synthesized. 3-Chloro-2-hydroxy-propane sulfonic acid sodium was mixed into the solution of sodium phosphate at 55 °C and 4 h reaction time. The 2,3-oxiranemethane sulfonic acid sodium salt was formed. 2,3-Oxiranemethane sulfonic acid sodium salt solution was dropped into the solution of lauric acid at 90 °C, the dropping time 0.5 h and left for 2.5 h. Lauric acid-2-hydroxy-3-propane sulfonic acid sodium salt was obtained. The yield was 85.2 % and was characterized by FTIR.
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References
J.X. Xiao and Z.G. Zhao, Principle and Application of Surfactants, Chemical Industry Press, Beijing (2003).
Y.C. Zheng, D. Han and P.H. Yang, Fine Chem., 22, 578 (2005).
P.S. PiispanenU.R. Mikael KjellinB. Hedman. P.S. Piispanen, U.R.M. Kjellin, B. Hedman and T. Norin, J. Surfact. Deterg., 6, 125 (2003); doi:10.1007/s11743-003-0255-4.
H. Ge, L.-X. Sun and J. Wang, China Surfact. Deterg. Cosmet., 34, 176 (2004).
R.M. Zhang and S.Y. Lim, Adv. Fine Petrochem., 7, 1 (2006).
J.J. Hinkel, J E. Brown, B.R. Gadiyar and E. Beyer, New Environmentally Friendly Surfactant Enhances Well Cleanup, Paper SPE 82214, Presented at the SPE Formation Damage Conference, Hague, Netherlands, May 13-14, 2003.
R.M. Zhang and X.F. Ma, Hebei Chem. Eng. Ind., 30, 10 (2007).
Z.G. Chen, Y. Qian and Q. Gao, Chinese J. Colloid Polym., 21, 33 (2003).
H.L. Zuo, X.Q. Wu and L.J. Cui, Chinese J. Colloid Polym., 24, 33 (2006).