Preparation and Characterization of Magnetic Co0.5Mn0.5Fe2O4-Chitosan Nanoparticles as Surfactants in Oilfield

X.F. Zheng; Q. Lian

doi:10.14233/ajchem.2014.17466

Issue

Vol. 26 No. 14 (2014): Vol 26 Issue 14

Issue Published : July 5, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Preparation and Characterization of Magnetic Co0.5Mn0.5Fe2O4-Chitosan Nanoparticles as Surfactants in Oilfield

https://doi.org/10.14233/ajchem.2014.17466

X.F. Zheng

College of Chemical Engineering, Hebei Normal University of Science and Technology, Qinhuangdao 066600, P.R. China

Q. Lian

College of Chemical Engineering, Hebei Normal University of Science and Technology, Qinhuangdao 066600, P.R. China

Corresponding Author(s) : Q. Lian

xuefang-zheng@163.com

Asian Journal of Chemistry, Vol. 26 No. 14 (2014): Vol 26 Issue 14
Article Published : July 6, 2014

Abstract

The novel magnetic Co_0.5Mn_0.5Fe₂O₄-chitosan nanoparticles has the advantage of excellent biodegradation and a high level of controllability. The Co_0.5Mn_0.5Fe₂O₄-chitosan nanoparticles was prepared successfully. The size of the Co_0.5Mn_0.5Fe₂O₄-chitosan nanoparticles were all below 100 nm. The saturated magnetization of the Co_0.5Mn_0.5Fe₂O₄-chitosan nanoparticles could reach 80 emu/g and showed the characteristics of super-paramagnetism at the same time. The images of TEM and SEM electron microscopy showed that the cubic-shape magnetic Co_0.5Mn_0.5Fe₂O₄ particles were encapsulated by the spherical chitosan nanoparticles. The evaluation on the interfacial properties of the product showed that the interfacial tension between crude oil and water could be reduce to ultra-low values as low as 10^-3 mN/m when the magnetic Co_0.5Mn_0.5Fe₂O₄-chitosan nanoparticle was used in several blocks in Shengli oilfield without other additives. Meanwhile, the magnetic Co_0.5Mn_0.5Fe₂O₄-chitosan nanoparticles possessed good salt-resisting capacity.

Keywords

Magnetic nanoparticles Surfactants Superparamagnetism Interfacial tension

Zheng, X., & Lian, Q. (2014). Preparation and Characterization of Magnetic Co0.5Mn0.5Fe2O4-Chitosan Nanoparticles as Surfactants in Oilfield. Asian Journal of Chemistry, 26(14), 4499–4503. https://doi.org/10.14233/ajchem.2014.17466

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S. Mukherjee, P. Das and R. Sen, Trends Biotechnol., 24, 509 (2006); doi:10.1016/j.tibtech.2006.09.005.

Y. Wu, J. Guo, W.L. Yang, C.C. Wang and S.K. Fu, Polymer, 47, 5287 (2006); doi:10.1016/j.polymer.2006.05.017.

H.W. Gu, K.M. Xu, C.J. Xu and B. Xu, Chem. Commun., 941 (2006); doi:10.1039/B514130C.

P. Wunderbaldinger, L. Josephson and R. Weissleder, Bioconjug. Chem., 13, 264 (2002); doi:10.1021/bc015563u.

W. Wang, L. Deng, Z.H. Peng and X. Xiao, Enzyme Microb. Technol., 40, 255 (2007); doi:10.1016/j.enzmictec.2006.04.020.

E. Carrero, N.V. Queipo, S. Pintos and L.E. Zerpa, J. Petrol. Sci. Eng., 58, 30 (2007); doi:10.1016/j.petrol.2006.11.007.

M. Nitschke, S.G.V.A.O. Costa and J. Contiero, Biotechnol. Prog., 21, 1593 (2005); doi:10.1021/bp050239p.

J.D. Van Hamme, A. Singh and O.P. Ward, Biotechnol. Adv., 24, 604 (2006); doi:10.1016/j.biotechadv.2006.08.001.

R.S. Makkar, S.S. Cameotra and I.M. Banat, AMB Express, 1, 5 (2011); doi:10.1186/2191-0855-1-5.

H.-P. Meyer, Org. Process Res. Dev., 15, 180 (2011); doi:10.1021/op100206p.

S.L. Fox and G.A. Bala, Bioresour. Technol., 75, 235 (2000); doi:10.1016/S0960-8524(00)00059-6.

L.R. Rodrigues, J.A. Teixeira and R. Oliveira, Biochem. Eng. J., 32, 135 (2006); doi:10.1016/j.bej.2006.09.012.

J. Roger, J.N. Pons, R. Massart, A. Halbreich and J. Bacri, Eur. Phys. J. Appl. Phys., 5, 321 (1999); doi:10.1051/epjap:1999144.

I.M. Banat, R.S. Makkar and S.S. Cameotra, Appl. Microbiol. Biotechnol., 53, 495 (2000); doi:10.1007/s002530051648.

A. Singh, J.D. Van Hamme and O.P. Ward, Biotechnol. Adv., 25, 99 (2007); doi:10.1016/j.biotechadv.2006.10.004.

J.D. Desai and I.M. Banat, Microbiol. Mol. Biol. Rev., 61, 47 (1997).

W.S.W. Ngah, S. Ab Ghani and A. Kamari, Bioresour. Technol., 96, 443 (2005); doi:10.1016/j.biortech.2004.05.022.

A.J. Varma, S.V. Deshpande and J.F. Kennedy, Carbohydr. Polym., 55, 77 (2004); doi:10.1016/j.carbpol.2003.08.005.

Y.C. Chang and D.H. Chen, J. Colloid Interf. Sci., 283, 446 (2005); doi:10.1016/j.jcis.2004.09.010.

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R.B. Hernández, A.P. Franco, O.R. Yola, A. López-Delgado, J. Felcman, M.A.L. Recio and A.L.R. Merce, J. Mol. Struct., 877, 89 (2008); doi:10.1016/j.molstruc.2007.07.024.

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Issue

Vol. 26 No. 14 (2014): Vol 26 Issue 14

Preparation and Characterization of Magnetic Co0.5Mn0.5Fe2O4-Chitosan Nanoparticles as Surfactants in Oilfield

Corresponding Author(s) : Q. Lian

Abstract

Keywords

Full Article

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