Preparation and Thermal Behavior of Novel Sulfur-Nitrogen Flame Retardant Containing Triazine Ring for Cotton Fabrics

Zhi-Yi Zhang; Gui-Zhe Zhao; Ya-Qing Liu

doi:10.14233/ajchem.2014.16758

Issue

Vol. 26 No. 14 (2014): Vol 26 Issue 14

Issue Published : July 5, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Preparation and Thermal Behavior of Novel Sulfur-Nitrogen Flame Retardant Containing Triazine Ring for Cotton Fabrics

https://doi.org/10.14233/ajchem.2014.16758

Zhi-Yi Zhang

Research Center for Engineering Technology of Polymeric Composites of Shanxi Province, College of Materials Science and Engineering, North University of China, Taiyuan 030051, P.R. China

Gui-Zhe Zhao

Research Center for Engineering Technology of Polymeric Composites of Shanxi Province, College of Materials Science and Engineering, North University of China, Taiyuan 030051, P.R. China

Ya-Qing Liu

Research Center for Engineering Technology of Polymeric Composites of Shanxi Province, College of Materials Science and Engineering, North University of China, Taiyuan 030051, P.R. China

Corresponding Author(s) : Ya-Qing Liu

zhiyzhang@sohu.com

Asian Journal of Chemistry, Vol. 26 No. 14 (2014): Vol 26 Issue 14
Article Published : July 6, 2014

Abstract

A novel sulfur-nitrogen flame retardant containing triazine ring (SN) has been synthesized and structurally characterized by elemental analysis, FT-IR and ¹H NMR spectroscopies. Meanwhile, the effects of reaction solvent, acid-binding agent, reaction temperature and molar ratio of starting materials on the yield of SN were investigated. Experiments showed that when the molar ratio of intermediate M to diethanol amine is 1 to 1 in the presence of sodium carbonate as acid-binding agent in water at 40 °C, the yield of the obtained SN reaches 85 %. In addition, to evaluate the potential flame-retardant ability of the target flame retardant (SN), the thermal behaviors of SN, pure cotton, and cotton treated with SN were studied by thermogravimetry analysis. This result demonstrated that SN was a good charring agent and obviously improved the char-forming ability and the thermal stability of cotton fabrics.

Keywords

Sulfur-nitrogen Flame retardant Preparation Cotton fabrics Thermal behaviour

Zhang, Z.-Y., Zhao, G.-Z., & Liu, Y.-Q. (2014). Preparation and Thermal Behavior of Novel Sulfur-Nitrogen Flame Retardant Containing Triazine Ring for Cotton Fabrics. Asian Journal of Chemistry, 26(14), 4419–4422. https://doi.org/10.14233/ajchem.2014.16758

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References

S. Zhang and R. Horrocks, Prog. Polym. Sci., 28, 1517 (2003); doi:10.1016/j.progpolymsci.2003.09.001.

A.R. Horrocks, B.K. Kandola, P.J. Davies, S. Zhang and S.A. Padbury, Polym. Degrad. Stab., 88, 3 (2005); doi:10.1016/j.polymdegradstab.2003.10.024.

W.D. Wu and C.Q. Yang, Polym. Degrad. Stab., 85, 623 (2004); doi:10.1016/j.polymdegradstab.2004.02.002.

S.C. Chang, B. Condon, E. Graves, M. Uchimiya, C. Fortier, M. Easson and P. Wakelyn, Fiber. Polym., 12, 334 (2011); doi:10.1007/s12221-011-0334-7.

J.D. Zuo, S.M. Liu and Q. Sheng, Molecules, 15, 7593 (2010); doi:10.3390/molecules15117593.

S.S. Mahapatra and N. Karak, Polym. Degrad. Stab., 92, 947 (2007); doi:10.1016/j.polymdegradstab.2007.03.012.

X. Wang, Y. Hu, L. Song, W.Y. Xing, H.D. Lu, P. Lv and G.X. Jie, Polym. Adv. Technol., 22, 2480 (2011); doi:10.1002/pat.1788.

K.H. Lee, D.H. Shin and Y.H. Seo, Korean J. Chem. Eng., 23, 224 (2006); doi:10.1007/BF02705720.

X.J. Lai, X.R. Zeng, H.Q. Li, F. Liao, C. Yin and H. Zhang, Polym. Compos., 33, 35 (2012); doi:10.1002/pc.21250.

C.S. Zhao, F.L. Huang, W.C. Xiong and Y.-Z. Wang, Polym. Degrad. Stab., 93, 1188 (2008); doi:10.1016/j.polymdegradstab.2008.03.010.

S.V. Levchik and E.D. Weil, Polym. Int., 54, 981 (2005); doi:10.1002/pi.1806.

S.F. Zhao, Z.Y. Hu, H.L. Zhu and X. Li, Chin. J. Shandong Chem., 39, 3 (2010).

C.M. Feng, Y. Zhang, S.W. Liu, Z. Chi and J. Xu, J. Appl. Polym. Sci., 123, 3208 (2012); doi:10.1002/app.34993.

J.F. Dai and B. Li, J. Appl. Polym. Sci., 116, 2157 (2010).

P.H. Zhao, M. Zhang, D.H. Wu and Y.Q. Liu, Korean J. Chem. Eng., 30, 1687 (2013); doi:10.1007/s11814-013-0112-x.

C.H. Ke, J. Li, K.Y. Fang, Q.-L. Zhu, J. Zhu, Q. Yan and Y.-Z. Wang, Polym. Degrad. Stab., 95, 763 (2010); doi:10.1016/j.polymdegradstab.2010.02.011.

Issue

Vol. 26 No. 14 (2014): Vol 26 Issue 14

Preparation and Thermal Behavior of Novel Sulfur-Nitrogen Flame Retardant Containing Triazine Ring for Cotton Fabrics

Corresponding Author(s) : Ya-Qing Liu

Abstract

Keywords

Full Article

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