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Vol. 26 No. 14 (2014): Vol 26 Issue 14

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Determination of p-Phenylenediamine Using Electrochemically Reduced Graphene Oxide

https://doi.org/10.14233/ajchem.2014.16643
Chunyan Wang
Fundamental Science on Radioactive Geology and Exploration Technology Laboratory, Department of Materials Science and Engineering, East China Institute of Technology, Fuzhou 344000, P.R. China
Yanfei Lan
Fundamental Science on Radioactive Geology and Exploration Technology Laboratory, Department of Materials Science and Engineering, East China Institute of Technology, Fuzhou 344000, P.R. China
Binqian Liao
Fundamental Science on Radioactive Geology and Exploration Technology Laboratory, Department of Materials Science and Engineering, East China Institute of Technology, Fuzhou 344000, P.R. China
Dan Li
Fundamental Science on Radioactive Geology and Exploration Technology Laboratory, Department of Materials Science and Engineering, East China Institute of Technology, Fuzhou 344000, P.R. China
Meiwu Zhu
Fundamental Science on Radioactive Geology and Exploration Technology Laboratory, Department of Materials Science and Engineering, East China Institute of Technology, Fuzhou 344000, P.R. China

Corresponding Author(s) : Chunyan Wang

chunyanwang@ecit.cn

Asian Journal of Chemistry, Vol. 26 No. 14 (2014): Vol 26 Issue 14

Abstract

In this communication, we report a green and effective approach to construct a sensitive detection platform based on electrochemically reduced graphene oxide modified electrode (EG@GCE). The surface morphology and structure of electrochemical reduction of graphene oxide were investigated by utilizing transmission electron microscope, FT-IR spectra, UV-visible spectra and X-ray diffraction. This EG@GCE exhibits sensitive current responses toward the electrooxidation of p-phenylenediamine (PDA) due to the excellent conductivity and large electroactive surface area of electrochemical reduction of graphene oxide and the strong p-p stacking interactions between p-phenylenediamine and the electrochemical reduction of graphene oxide surface. Moreover, a low detection limit of 1.08 μM (S/N = 3) with the linear range of 5 to 200 μM is obtained. This new finding demonstrates that the electrochemical reduction of graphene oxide is a promising candidate of advanced electrode materials for electrochemical determination aromatic amines in environmental analysis.

Keywords

Determination p-Phenylenediamine Electrochemically reduced graphene oxide
Wang, C., Lan, Y., Liao, B., Li, D., & Zhu, M. (2014). Determination of p-Phenylenediamine Using Electrochemically Reduced Graphene Oxide. Asian Journal of Chemistry, 26(14), 4381–4385. https://doi.org/10.14233/ajchem.2014.16643
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