Copyright (c) 2019 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Monitoring of Organochlorine Pesticides Residues in Five Fruits using Gas Liquid Chromatography Equipped with Electron Capture Detector (GLC-ECD)
Corresponding Author(s) : Devendra Kumar
Asian Journal of Chemistry,
Vol. 31 No. 10 (2019): Vol 31 Issue 10
Abstract
India is the largest producer of fruits as they are important part of their economy. But they are badly affected by insect-pest attack during harvesting. Farmers use a large amount of pesticides to protect them but due to their longer persistence they found in fruits in small quantities. This paper described an analytical methodology for the monitoring of 20 organochlorine pesticides in 5 fruits viz. pineapple (Ananas comosus), apple (Malus pumila), plum (Prunus domestica), papaya (Carica papaya) and mango (Mangifera indica) by using gas liquid chromatography equipped with electron capture detector (GLC-ECD). During the monitoring work it has been found that each fruit was contaminated with pesticides. Pineapple was found contaminated with β-BHC, δ-BHC, heptachlor epoxide, dieldrin, endrin and methoxychlor; apple was found contaminated g-BHC, δ-BHC, heptachlor epoxide, dieldrin, endrin, endosulfan II and methoxychlor; plum and papaya were found contaminated with g-BHC, β-BHC, δ-BHC, heptachlor epoxide, 4,4′-DDE, endrin, endosulfan sulfate and methoxychlor; mango was found contaminated with β-BHC, δ-BHC, 4,4′-DDE, endrin, endosulfan sulfate and methoxychlor. However, the detected concentration of pesticides was below the MRL values but their long term use can cause serious health problems.
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- https://doi.org/10.1046/j.1365-2621.2001.00513.x.
- Ministry of Agriculture & Farmer Welfare, Horticulture Statistics at a
- Glance, Government of India (2017).
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References
C. Kaur and H.C. Kapoor, Int. J. Food Sci. Technol., 36, 703 (2001);
https://doi.org/10.1046/j.1365-2621.2001.00513.x.
Ministry of Agriculture & Farmer Welfare, Horticulture Statistics at a
Glance, Government of India (2017).
P.I. Devi, J. Thomas and R.K. Raju, Agric. Econ. Res. Rev., 30, 163 (2017).
R.M. Burkul, S.V. Ranade and B.L. Pangarkar, Int. J. Emerg. Trend
Eng. Basic Sci., 2, 88 (2015).
I. Mahmood, S.R. Imadi, K. Shazadi, A. Gul and K.R. Hakeem, Effects
of Pesticides on Environment, In: Plant, Soil and Microbes: Vol. 1 Implications in Crop Science, Springer International Publishing: Switzerland,
p. 253 (2016).
S. Chandra, N.A. Mahindrakar, M. Kumar and P.L. Shinde, Int. J. Adv.
Res., 2, 1075 (2014).
http://www.pan-uk.org/health-effects-of-pesticides/
(visited on 15/02/2019).
S.M. Bradberry, S.A. Cage, A.T. Proudfoot and J.A. Vale, Toxicol. Rev.,
, 93 (2005);
https://doi.org/10.2165/00139709-200524020-00003.
C.L. Beseler and L. Stallones, J. Agric. Saf. Health, 15, 327 (2009);
https://doi.org/10.13031/2013.28887.
R. Sapbamrer and S. Nata, Environ. Health Prev. Med., 19, 12 (2014);
https://doi.org/10.1007/s12199-013-0349-3.
A.A. Adewunmi and S.O. Fapohunda, Eur. J. Biol. Res., 8, 70 (2018);
https://doi.org/10.5281/zenodo.1237542.
N. Tarannum, M. Singh and R. Hawaldar, Pesticides as an Occupational
Hazard Facts and Figures, In: Handbook of Research on the Adverse
Effects of Pesticide Pollution in Aquatic Ecosystems, IGI Global, p.
(2019).
M.C. Keifer and J. Firestone, J. Agromed., 12, 17 (2007);
https://doi.org/10.1300/J096v12n01_03.
A.K. Srivastava and C. Kesavachandran, Health Effects of Pesticides,
CRC Press (2019).
J.E. Jäger, Residues of Pesticides, In: Chemical Hazards in Foods of
Animal Origin, Academic Publishers: Wageningen, p. 567 (2019).
D.P. Mukherjee, B. Kumar, S. Kumar, M. Mishra, R. Gaur, D. Prakash,
S.K. Singh and C.S. Sharma, Arch. Appl. Sci. Res., 3, 85 (2011).
R.K. Kole, H. Banerjee and A. Bhattacharyya, Bull. Environ. Contam.
Toxicol., 67, 554 (2001);
https://doi.org/10.1007/s001280159.
L. Guzzella, C. Roscioli, L. Viganò, M. Saha, S.K. Sarkar and A.
Bhattacharya, Environ. Int., 31, 523 (2005);
https://doi.org/10.1016/j.envint.2004.10.014.
L. Saunders, P. Kadhel, N. Costet, F. Rouget, C. Monfort, J.P. Thome,
L. Guldner, S. Cordier and L. Multigner, Environ. Int., 68, 171 (2014);
https://doi.org/10.1016/j.envint.2014.03.024.
K.-S. Kim, Y.-M. Lee, S.G. Kim, I.-K. Lee, H.-J. Lee, J.-H. Kim, J. Kim,
H.-B. Moon, D.R. Jacobs Jr. and D.-H. Lee, Chemosphere, 94, 151 (2014);
https://doi.org/10.1016/j.chemosphere.2013.09.066.
K.P. Singh, A. Malik, D. Mohan and S. Sinha, Bull. Environ. Contam.
Toxicol., 74, 162 (2005);
https://doi.org/10.1007/s00128-004-0563-1.
T. Vial, B. Nicolas and J. Descotes, J. Toxicol. Environ. Health, 48, 215
(1996);
https://doi.org/10.1080/009841096161294.
S.H. Safe, Environ. Health Perspect., 103, 346 (1995);
https://doi.org/10.1289/ehp.95103346.
C. Beseler, L. Stallones, J.A. Hoppin, M.C. Alavanja, A. Blair, T. Keefe
and F. Kamel, J. Occup. Environ. Med., 48, 1005 (2006);
https://doi.org/10.1097/01.jom.0000235938.70212.dd.
E. Sohail, A. Waseem, W.L. Chae, J.L. Jong and H. Imitiaz, J. Clin. Exp.
Oncol., 26, 98 (2004).
D. Kumar and A. Kashyap, J. Chem. Pharm. Res., 6, 751 (2014).
D. Kumar and P. Kulshrestha, J. Chem. Pharm. Res., 8, 539 (2016).