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Vol. 26 No. 15 (2014): Vol 26 Issue 15

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Synthesis, Characterization and Photophysical Properties of Graphene-Phthalocyanine Hybrid

https://doi.org/10.14233/ajchem.2014.16241
Fan Zhang
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China ;College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, P.R. China
Ruilin Man
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China
Zhiyuan Peng
College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, P.R. China ;College of Chemistry and Chemical Engineering, Jishou University, Jishou 416000, P.R. China
Zhibo Liu
Key Laboratory of Weak Light Non-linear Photonics, Ministry of Education and Teda Applied Physics School, Nankai University, Tianjin 300457, P.R. China

Corresponding Author(s) : Fan Zhang

zhangfan8346@sina.com

Asian Journal of Chemistry, Vol. 26 No. 15 (2014): Vol 26 Issue 15

Abstract

The functionalization of reduced graphene oxide by phenyl carboxylic diazonium salt and the subsequent attachment of a symmetrically substituted Zn-phthalocyanine via amide reaction were described. The graphene derivative was characterized by Raman spectra, Ultraviolet/visible spectra, Fourier transform infrared spectra, thermogravimetric analysis, scanning electron microscope, transmission electron microscopy, atomic force microscopy, fluorescence emission spectra and Z-scan experiments. The nanocomposite exhibited excellent thermal performance, a strong quenching and stronger nonlinear optical performance than that of each individual and the mixture in nanosecond regime. The thermogravimetric analysis tests showed the high grafting efficiency of phthalocyanine to graphene. And the efficient fluorescence quenching and optical limiting properties of the hybrid demonstrated the possible photoinduced electron transfer or energy transfer mechanism between graphene and phthalocyanine.

Keywords

Phthalocyanine Graphene Z-scan Functionalization
Zhang, F., Man, R., Peng, Z., & Liu, Z. (2014). Synthesis, Characterization and Photophysical Properties of Graphene-Phthalocyanine Hybrid. Asian Journal of Chemistry, 26(15), 4819–4826. https://doi.org/10.14233/ajchem.2014.16241
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